A novel charge-transfer polymer for separating hydrocarbon fractions of crude oils     

Keith C.C. Bancroft  Susan B. Kendall  Michael M. Rhead  Gerard Hentic 《Marine pollution bulletin》1979,10(8):238-239

Hydrocarbon fractions in crude oil were separated by a new charge-transfer polymer in place of silver ions in Argentation TLC. The charge-transfer plates are cheaper than their silver nitrate equivalents, do not discolour, and store well. The polymer/silica gel mix can be re-used.  相似文献   

The azimuthal variation of teleseismic P-wave residuals for stations in southern California     

Susan A. Raikes 《Earth and Planetary Science Letters》1976,29(2):367-372

A study of teleseismic P-residuals for 13 stations in southern California reveals that these vary systematically with the azimuth of the event; the residuals generally tend to be negative in the NW and SE quadrants. This effect is greatest in the north of the region: a maximum peak-to-peak variation of 1.3 sec with residuals as low as ?0.9 sec was observed at Isabella. The delays become less negative further south in the region, and at the southernmost station, Glamis, delays of up to +0.75 sec were observed to the west. The latter may be associated with velocity decreases in the active geothermal areas of the Imperial Valley. A simple model, consisting of a region some 175 km wide and 100 km thick at a depth of approximately 100 km in which a velocity increase of up to 0.45 km/sec occurs, is proposed to account for the observed variations. This region trends NW-SE approximately parallel to the North America-Pacific plate boundary. The proposed velocity changes are consistent with a pinching out of the low-velocity (partial melting) zone under the area, such as has been proposed to explain the low heat flow in the Sierra Nevada, and may be related to the presence of an ancient (～ 30 m.y.) subduction zone under southern California.  相似文献   

Fatty acids and Pb-210 geochronology of a sediment core from Buzzards Bay,Massachusetts     

John W Farrington  Susan M Henrichs  Robert Anderson 《Geochimica et cosmochimica acta》1977,41(2):289-296

Four sections of a Pb-210 dated core of 62 cm length from Buzzards Bay, Massachusetts, were analyzed for fatty acids. A comparison of fatty acids extracted by Soxhlet extraction (unbound fatty acids) with fatty acids extracted by subsequent saponification extraction of the same sample (bound fatty acids) showed the former did not undergo diagenetic loss any faster than the latter. However, compositional differences between bound and unbound fatty acids were apparent in the top section of 1–2 cm and were less apparent in the 54–58 cm section. At least 14% of the bound fatty acids are esterified to non-solvent extractable material. The net conversion of fatty acids to other compounds is 32 μ/g dry weight sediment over the first 30 yr after deposition.  相似文献   

Climatological aspects of the tropical convective boundary layer     

E. B. Kraus  Howard P. Hanson 《Boundary-Layer Meteorology》1974,6(1-2):219-233

The characteristics of a boundary layer depend both on conditions at the surface and in the interior of the medium. In the undisturbed tropics, the latter are largely determined by subsidence and by infrared radiational cooling. One-dimensional models are used to establish relationships between the inversion height, subsidence, upper-air humidity and sea-surface temperature. In particular, it is shown that a universally colder tropical ocean would probably be covered by more extensive clouds.Contribution No. 1700 Rosenstiel School of Marine and Atmospheric Science, University of Miami.  相似文献   

Seismic reflection coefficients from mantle fault zones   总被引：3，自引：0，他引：3  

Mike Warner &  Susan McGeary 《Geophysical Journal International》1987,89(1):223-230

Summary. Several bright reflections from structures within the mantle can be seen on BIRPS' deep seismic reflection profiles. We have calculated apparent reflection coefficients for the brightest of these events and obtain values around 0.1. It is not possible to produce such large reflections by either compositional layering or seismic anisotropy if olivine and pyroxene are the only significant minerals in the mantle. These large reflections can be produced by a mafic layer or a partially hydrated layer within normal peridotite. The brightest reflections seem to be best explained as major faults or shear zones within the mantle.  相似文献   

Assessing possible changes in flood frequency due to climate change in mid‐sized watersheds in New York State,USA     

Stephen B. Shaw  Susan J. Riha 《水文研究》2011,25(16):2542-2550

The frequency of flooding is often presumed to increase with climate change because of projected increases in rainfall intensities. In this paper, using 50‐plus years of historical discharge and meteorological data from three watersheds in different physiographic regions of New York State, USA, we find that annual maximum stream discharges are associated with 20% or less of the annual maximum rainfall events. Instead of rainfall events, approximately 20% of annual maximum stream discharges are associated with annual maximum snowmelt events while 60% of annual maximum discharges are associated with moderate rainfall amounts and very wet soil conditions. To explore the potential for changes in future flood risk, we employed a compound frequency distribution that assumes annual maximum discharges can be modelled by combining the cumulative distribution functions of discharges resulting from annual maximum rainfall, annual maximum snowmelt, and occurrences of moderate rain on wet soils. Basing on a compound frequency distribution comprised of univariate general extreme value (GEV) and gamma distributions, we found that a hypothetical 20% increase in the magnitude of rainfall‐related stream discharge results in little change in 96th percentile annual maximum discharge. For the 99th percentile discharge, two waterbodies in our study had a 10% or less increase in annual maximum discharge when annual maximum rainfall‐related discharges increased 20% while the third waterbody had a 16% increase in annual maximum discharges. Additionally, in some cases, annual maximum discharges could be offset by a reduction in the discharge resulting from annual maximum snowmelt events. While only intended as a heuristic tool to explore the interaction among different flood‐causing mechanisms, use of a compound flood frequency distribution suggests a case can be made that not all waterbodies in humid, cold regions will see extensive changes in flooding due to increased rainfall intensities. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Correspondence analysis of water quality data: Implications for fauna deaths at Stillwater Lakes, Nevada     

Susan G. Oleson  James R. Carr 《Mathematical Geology》1990,22(6):665-698

Over the last 2 years, more than seven million fish and 16,000 birds have died from drought-induced disease and suspected poisoning at Stillwater Lakes, Nevada. Correspondence analysis of water samples taken in June and September 1986, from lakes and reservoirs near Stillwater Lakes and four background lakes/reservoirs (not associated with fauna disease and death), is attempted to investigate the correlation among sites associated with fauna deaths. This analysis identifies high correlation between some Stillwater Lakes sites and boron. A correlation between boron and arsenic is also identified. Leaching and transport of toxins to the Stillwater Lakes system is one hypothesis to explain the wildlife deaths. Other hypotheses include the direct introduction of toxins by groundwater associated with geothermal activity. A natural cause for the wildlife deaths is also suggested, a cause not associated with the introduction of toxins.  相似文献   

Numerical simulation of the circulation within the Perth Submarine Canyon,Western Australia     

Susan J. Rennie  Charitha B. Pattiaratchi  Robert D. McCauley 《Continental Shelf Research》2009,29(16):2020-2036

Surface and sub-surface currents along the ocean boundary of Western Australia were simulated using Regional Ocean Modelling System (ROMS) to examine the circulation within the Perth Canyon. Two major current systems influenced the circulation within the canyon: (1) The Leeuwin current interacted weakly with the canyon as the majority of the canyon was below the depth of the Leeuwin current and (2) Leeuwin undercurrent interacted strongly with the canyon, forming eddies within the canyon at depths of 400–800 m. The results indicated that within the canyon, the current patterns changed continuously although there were some repeated patterns. Recurrent eddies produced regions where upwelling or downwelling dominated during the model runs. Deep upwelling was stronger within the canyon than elsewhere on the shelf, but vertical transport in the upper ocean was strong everywhere when wind forcing was applied. Upwelling alone appeared to be insufficient to transport nutrients to the euphotic zone because the canyon rims were deep. Increased upwelling, combined with entrapment within eddies and strong upwelling-favourable winds, which could assist mixing, may account for the high productivity attributed to the canyon. The Leeuwin current is otherwise a strong barrier to the upwelling of nutrients.  相似文献   

Tomography: A window on the role of sulfur in the structure of micrometeorites     

Susan TAYLOR  Keith W. JONES  Gregory F. HERZOG  Claire E. HORNIG 《Meteoritics & planetary science》2011,46(10):1498-1509

Abstract– To determine the role played by sulfides in the formation of vesicles and FeNi metal beads, we mapped the locations and tabulated the numbers of sulfides, metal beads, and vesicles in 1583 sectioned micrometeorites (MMs) using conventional microscopy and in 190 whole MMs using synchrotron computed microtomography (SCMT). Both the section and the SCMT images show that sulfides melt, coalesce, and migrate to the MMs surface. The decomposition of sulfides may occur during all these stages. Given the sulfide morphologies and compositions that we see in section, we think the breakdown of Ni sulfides produces the FeNi beads. The SCMT images show that metal beads are common in melted MMs, >50% have them. Vesicles in porphyritic and scoriaceous MMs are also probably formed as sulfides decompose. Not only do sulfides abut the vesicles but also the temperatures at which sulfides decompose overlap those at which MM surfaces first melt and temporarily seal, suggesting that S gases could produce most of these vesicles. As the vesicle shapes and patterns of distribution differ among MM classes, tomography can be used to nondestructively screen for specific types of MMs. Tomography is a powerful tool for visualizing the three‐dimensional distribution of metal beads, sulfides, mean densities, and vesicles in MMs.  相似文献   

An in-depth look at the lunar crater Copernicus: Exposed mineralogy by high-resolution near-infrared spectroscopy     

Roberto Bugiolacchi  Urs Mall  Susan McKenna-Lawlor  Kjell Brønstad  Finn Søraas  Rolf B. Pedersen 《Icarus》2011,213(1):43-63

Newly acquired, sequentially spaced, high-resolution near-infrared spectra across the central section of crater Copernicus’ interior have been analyzed using a range of complementary techniques and indexes.We have developed a new interpretative method based on a multiple stage normalization process that appears to both confirm and expand on previous mineralogical estimations and mapping. In broad terms, the interpreted distribution of the principle mafic species suggests an overall composition of surface materials dominated by calcium-poor pyroxenes and minor olivine but with notable exceptions: the southern rim displays strong ca-rich pyroxene absorption features and five other locations, the uppermost northern crater wall, opposite rim sections facing the crater floor, and the central peak Pk1 and at the foot of Pk3, show instead strong olivine signatures.We also propose impact glass an alternative interpretation to the source of the weak but widespread olivine-like spectral signature found in low-reflectance samples, since it probably represents a major regolith constituent and component in large craters such as Copernicus.The high quality and performance of the SIR-2 data allows for the detection of diagnostic key mineral species even when investigating spectral samples with very subdued absorption features, confirming the intrinsic high-quality value of the returned data.  相似文献