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821.
We explore the contribution of fractures (joints) in controlling the rate of weathering advance for a low‐porosity rock by using methods of homogenization to create averaged weathering equations. The rate of advance of the weathering front can be expressed as the same rate observed in non‐fractured media (or in an individual block) divided by the volume fraction of non‐fractured blocks in the fractured parent material. In the model, the parent has fractures that are filled with a more porous material that contains only inert or completely weathered material. The low‐porosity rock weathers by reaction‐transport processes. As observed in field systems, the model shows that the weathering advance rate is greater for the fractured as compared to the analogous non‐fractured system because the volume fraction of blocks is < 1. The increase in advance rate is attributed both to the increase in weathered material that accompanies higher fracture density, and to the increase in exposure of surface of low‐porosity rock to reaction‐transport. For constant fracture aperture, the weathering advance rate increases when the fracture spacing decreases. Equations describing weathering advance rate are summarized in the ‘List of selected equations’. If erosion is imposed at a constant rate, the weathering systems with fracture‐bounded bedrock blocks attain a steady state. In the erosional transport‐limited regime, bedrock blocks no longer emerge at the air‐regolith boundary because they weather away. In the weathering‐limited (or kinetic) regime, blocks of various size become exhumed at the surface and the average size of these exposed blocks increases with the erosion rate. For convex hillslopes, the block size exposed at the surface increases downslope. This model can explain observations of exhumed rocks weathering in the Luquillo mountains of Puerto Rico. Published 2017. This article is a U.S. Government work and is in the public domain in the USA  相似文献   
822.
Molluscan shell debris is an under-exploited means of detecting, sourcing, and age-dating dredged sediments in open-shelf settings. Backscatter features on the Southern California shelf are suggestive of dredged sediment hauled from San Diego Bay but deposited significantly inshore of the EPA-designated ocean disposal site. We find that 36% of all identifiable bivalve shells > 2 mm (44% of shells > 4 mm) in sediment samples from this 'short dump' area are from species known to live exclusively in the Bay; such shells are absent at reference sites of comparable water depth, indicating that their presence in the short-dump area signals non-compliant disposal rather than natural offshore transport or sea level rise. These sediments lack the shells of species that invaded California bays in the 1970s, suggesting that disposal preceded federal regulations. This inexpensive, low-tech method, with its protocol for rejecting alternative hypotheses, will be easy to adapt in other settings.  相似文献   
823.
As part of a study on microbial redox alteration of humic substances we investigated the potential effect of this metabolism on the fate of heavy metals and hydrocarbons as a result of conformational alteration of the humic molecular structure due to microbial reduction. Our studies indicate that the microbial reduction of humic acids (HA) results in significant morphological and geochemical alterations. X‐ray microscopy analysis indicate that the conformational structure of the humic colloids is altered as a result of the redox change. In the reduced state, the HA appeared as small dense particles, on reoxidation, large loose aggregates were formed. In addition, spectrofluorometric studies indicated that the binding capacity of the HA for naphthalene was decreased by 10% when the HA was reduced. Similarly, the reduced HA yielded higher surface tension values at all concentrations tested which is indicative of a more hydrophilic and less hydrophobic solute. On reoxidation, the surface tension values reverted back to values similar to those obtained for the untreated oxidized HA. These data indicate that the hydrophobicity of the HA is altered on biological reduction of the HA and that this alteration is reversible. In contrast the reduced HA demonstrated a 15% higher affinity for heavy metals such as divalent cobalt than the oxidized HA. In addition to increasing the binding capacity of HA for heavy metals, the reduction of the HA also decreased the bioavailability and toxicity of bound heavy metals such as chromium. When incubated in the presence of Cr(III) and HA, cells of Escherichia coli grew much more rapidly in the presence of the reduced HA suggesting that the higher metal binding capacity of the reduced humic substances resulted in a removal of the Cr(III) from solution and hence reduced its bioavailability and toxicity. These studies demonstrate that HA redox state and reduction of humic acids by microorganisms can have a significant effect on the molecular morphology and binding constants of HA for heavy metals and hydrocarbons and also directly affects the bioavailability of these compounds in the environment.  相似文献   
824.
825.
Single receiver phase ambiguity resolution with GPS data   总被引:26,自引:12,他引:14  
Global positioning system (GPS) data processing algorithms typically improve positioning solution accuracy by fixing double-differenced phase bias ambiguities to integer values. These “double-difference ambiguity resolution” methods usually invoke linear combinations of GPS carrier phase bias estimates from pairs of transmitters and pairs of receivers, and traditionally require simultaneous measurements from at least two receivers. However, many GPS users point position a single local receiver, based on publicly available solutions for GPS orbits and clocks. These users cannot form double differences. We present an ambiguity resolution algorithm that improves solution accuracy for single receiver point-positioning users. The algorithm processes dual- frequency GPS data from a single receiver together with wide-lane and phase bias estimates from the global network of GPS receivers that were used to generate the orbit and clock solutions for the GPS satellites. We constrain (rather than fix) linear combinations of local phase biases to improve compatibility with global phase bias estimates. For this precise point positioning, no other receiver data are required. When tested, our algorithm significantly improved repeatability of daily estimates of ground receiver positions, most notably in the east component by approximately 30% with respect to the nominal case wherein the carrier biases are estimated as real values. In this “static” test for terrestrial receiver positions, we achieved daily repeatability of 1.9, 2.1 and 6.0 mm in the east, north and vertical (ENV) components, respectively. For kinematic solutions, ENV repeatability is 7.7, 8.4, and 11.7 mm, respectively, representing improvements of 22, 8, and 14% with respect to the nominal. Results from precise orbit determination of the twin GRACE satellites demonstrated that the inter-satellite baseline accuracy improved by a factor of three, from 6 to 2 mm up to a long-term bias. Jason-2/Ocean Surface Topography Mission precise orbit determination tests results implied radial orbit accuracy significantly below the 10 mm level. Stability of time transfer, in low-Earth orbit, improved from 40 to 7 ps. We produced these results by applying this algorithm within the Jet Propulsion Laboratory’s (JPL’s) GIPSY/OASIS software package and using JPL’s orbit and clock products for the GPS constellation. These products now include a record of the wide-lane and phase bias estimates from the underlying global network of GPS stations. This implies that all GIPSY–OASIS positioning users can now benefit from this capability to perform single-receiver ambiguity resolution.  相似文献   
826.
Accurate estimation of streambed vertical hydraulic conductivity (Kv) is of great importance in the analysis of water quantity exchange and solute transfer between a stream and its sediments. The paper analyzed the inaccuracy of hydraulic conductivity values of sediments derived from grain-size distribution (Kg), which were determined from eight empirical grain-size methods to represent streambed Kv. In this study, the values of Kv for a streambed were derived using falling-head standpipe permeameter tests conducted at eight study sites in the Elkhorn River, Nebraska, and the tested streambed columns were then collected for grain-size analysis by sieving. These empirical methods were used to calculate the Kg values of the streambed from grain-size distribution data of sediments. Unlike many other studies, this study verifies Kg from grain-size distribution with Kv from permeameter tests on the basis of the same samples of streambed sediments. The Kg values derived from the eight empirical methods were larger than the Kv from permeameter tests; there are five methods that give Kg values of about 3–6 times larger than these Kv. The Kg values from the Kozeny formula followed by the Hazen formula give the largest overestimation error if they are used to represent the Kv of the streambed. The USBR and Shepherd formulas generated Kg values close to Kv, but these Kg values are still larger in general than the Kv values. Moreover, the new values of coefficient C for the empirical formulas were revised so that they can be used to calculate the approximate Kv of a streambed. Among the eight methods, the ratios of the original C values to the average new C range from 1.3 to 5.9. It can be hypothesized that smaller C values must be used in the estimation of Kv for general soil samples if these empirical formulas are used to calculate Kv.  相似文献   
827.
828.
对表层海洋动力学及其调控机制的认识对准确认识海洋自然变化过程及其未来对气候变化的响应具有重要意义。志愿观测船作为自动观测系统的载体和样品采集平台的优势使其在提升人类对于表层海洋的观测能力方面具有极大优势。本文系统性地回顾了志愿观测船的概念、发展历史、现状和未来发展趋势。基于志愿观测船的诸多海洋观测项目的成功显示了,随着快速发展的传感器技术,志愿观测船能够以经济有效的方式显著地提升表层海洋现场观测的时间和空间分辨率。未来的海洋观测系统应该综合利用包括志愿观测船在内的多种海洋观测平台的优势。  相似文献   
829.
Abstract

We used heart rate change as a tool to study how positive and negative wildlife conservation messaging impacts a viewer, and which types of animal images stimulate greatest reaction. We used scenes from five wildlife conservation videos available from environmental organization websites and YouTube, with positive and negative messaging. We found both very positive and very negative messaging in videos may be similarly effective in engaging viewers. A trend in greater changes in heart rate when insects, mammals, and birds appear on the screen suggests generally high human interest in these taxa, potentially due to avoidance and attraction responses. The number of scenes (N?=?54) in which various taxa appear reflects bias toward mammals (65%) and birds (17%) to capture viewers’ attention. Arousal is a primary step in engaging an audience to attend to a message. Physiological research offers innovative new techniques to evaluate public responses to communications about biodiversity conservation.  相似文献   
830.
Large quantities of methane (C1), ethane (C2), and propane (C3) emanate from shallow marine seeps near Coal Oil Point (COP), California. Concentrations of these gases were analyzed in the surface water down-current of the seep field over a 15-month period. The variable proportions of C1, C2, and C3 analyzed in gas bubbles emitted from 16 distinct seeps in the COP field encompass much of the variability found in the surface waters down-current. However, waters with disproportionate levels of C1 suggest the presence of additional C1 sources. Based on three spatial surveys, covering areas up to 280 km2, C2 and C3 air-sea fluxes were estimated to be in the order of 3.7 and 1.4 μmol day?1 m?2, respectively. Only 0.6% of C2 and 0.5% of C3 in the dissolved plume originating from the COP seep field are transferred to the atmosphere in the study area, with the fate of the remainder uncertain.  相似文献   
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