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861.
862.
863.
This paper describes a dual-column laboratory setup consisting of a glass column and a stainless-steel column filled with aquifer material. The setup was used to replicate a ground water recirculation well that serves as an in situ reactor and a combined injection/withdrawal well. The treatment solution consisted of a buffered titanium (III) citrate/vitamin B12 mixture. The first column, representing the well, was made of glass, allowing for visual inspection of the mixing. The stainless-steel column was instrumented with redox (Eh) probes to monitor the changes in redox conditions. The redox measurement showed that, although the sand contained large quantities of iron oxides, the oxidation rate was relatively slow and the titanium solution would remain reduced for some time in the aquifer, continuing to react with the contaminants. This laboratory setup was used to optimize the reagent concentrations and rate of delivery for field implementation. It was found that 4 mM titanium citrate and 3 mg/L vitamin B12 were sufficient to degrade 1,1,2,2-tetrachloroethane and carbon tetrachloride within one day, but not trichloroethylene, which required five days with 10 mM titanium citrate and 5 mg/L vitamin B12.  相似文献   
864.
Early career geography faculty in colleges and universities in the United States are positioned at the leading edge of a challenging period of change in higher education. Demands brought on by new technologies, new administrative and research pressures, and an increasingly competitive campus climate, may make it difficult to balance teaching, research, and service while also trying to maintain a personal life. This article argues that many geographers could benefit from the support of mentoring. Using ideas generated by participants in the Association of American Geographers' recent project, the Geography Faculty Development Alliance, I provide both pragmatic and personal suggestions for establishing these all‐important mentoring relationships to help cope with the pressures facing early career faculty.  相似文献   
865.
Rats were raised on a variety of isotopically controlled diets comprising 20% C3, C4 or marine protein and C3 and/or C4 non-protein or energy (i.e. sucrose, starch and oil) macronutrients. Compound specific stable carbon isotope (δ13C) analysis was performed on the cholesterol isolated from the diet (n=7 ) and bone (n=15 ) of these animals and the values compared with bulk δ13C measurements of bone collagen and apatite. The dietary signals reflected by these three bone biochemical components were investigated using linear regression analysis. δ13C values of bone cholesterol were shown to reflect whole diet δ13C values, collagen to reflect mainly dietary protein values and apatite to reflect whole diet values. Further correlations between dietary protein-to-energy spacings (Δ13Cprot-engy = δ13Cprotein - δ13Cenergy) and whole diet-to-bone component fractionations (Δ13Cbcomp-wdiet = δ13Cbone component - δ13Cwhole diet) indicates that for hypothetical diets where protein δ13C values are equal to energy values, fractionations between whole diet and bone biochemical fractions are -3.3‰ for cholesterol, +5.4‰ for collagen and +9.5‰ for apatite. Moreover, the narrow range of variation observed in apatite-to-cholesterol spacings (Δ13Capat-bchol) suggests that cholesterol δ13C values can potentially also be used as an independent test for the isotopic integrity of apatite δ13C values. These insights into bone cholesterol, collagen and apatite dietary signals, diet-to-bone fractionations and bone component-to-bone component spacings provide the basis for more accurate interpretations of the dietary behaviour of archaeological populations and food webs when the δ13C analysis of bone is employed.  相似文献   
866.
Fe released into solution is isotopically lighter (enriched in the lighter isotope) than hornblende starting material when dissolution occurs in the presence of the siderophore desferrioxamine mesylate (DFAM). In contrast, Fe released from goethite dissolving in the presence of DFAM is isotopically unchanged. Furthermore, Δ56Fesolution-hornblende for Fe released to solution in the presence of ligands varies with the affinity of the ligand for Fe. The extent of isotopic fractionation of Fe released from hornblende also increases when experiments are agitated continuously. The Fe isotope fractionation observed during hornblende dissolution with organic ligands is attributed predominantly to retention of 56Fe in an altered surface layer, while the lack of isotopic fractionation during goethite dissolution in DFAM is consistent with the lack of an altered layer. When a siderophore-producing soil bacterium is added to the system (without added organic ligands), Fe released to solution from both hornblende and goethite differs isotopically from Fe in the bulk mineral: Δ56Fesolution-starting material = −0.56 ± 0.19 (hornblende) and −1.44 ± 0.16 (goethite). Increased isotopic fractionation is attributed in this case to the fact that as bacterial respiration depletes the system in oxygen and aqueous Fe is reduced, equilibration between aqueous ferrous and ferric iron creates a pool of isotopically heavy ferric iron that is assimilated by bacterial cells. Adsorption of isotopically heavy ferrous iron (Fe(II) enriched in the heavier isotope) or precipitation of isotopically heavy Fe minerals may also contribute to observed fractionations.To test whether these Fe isotope signatures are recorded in natural systems, we also investigated extractions of samples of soils from which the bacteria were isolated. These extractions show variability in the isotopic signatures of exchangeable Fe and Fe oxyhydroxide fractions from one soil sample to another, but exchangeable Fe is observed to be lighter than Fe in soil Fe oxyhydroxides and hornblende. This observation is consistent with isotopically light Fe-organic complexes in soil pore water derived from the Fe-silicate starting materials in the presence of growing microorganisms, as documented in experiments reported here. The contributions from phenomena including organic ligand-promoted nonstoichiometric dissolution of Fe silicates, uptake of ferric iron by organisms, adsorption of isotopically heavy ferrous iron, and precipitation of iron minerals should create complex isotopic signatures in soils. Better understanding of these processes and the timescales over which they contribute to fractionation is needed.  相似文献   
867.
The Helan Shan and Zhuozi Shan of the NW Ordos basin, China, contain thick (up to 4 km) sequences of nonmarine Triassic strata. These rocks represent a major intraplate sedimentary basin, the paleogeography, tectonic setting and provenance of which are poorly understood and controversial. Studies of the sedimentary geology of the basin, supported by new palinspastic reconstruction of younger deformation, demonstrate that the basin filled from three sides by fluvial, lacustrine-deltaic and alluvial fan depositional systems. The basin forms a westward-thickening wedge that reaches its maximum thickness along the western margin of the Helan Shan and thins to a relatively constant 600–800 m east of the Zhuozi Shan. The stratigraphy of the basin is strongly asymmetric; alluvial fan strata are restricted to the extreme western margin of the basin and interfinger with axial fluvial deposits low in the section and deep lacustrine facies high in the section. Much of the eastern part of the basin is dominated by west-flowing meandering river and deltaic systems. Large structures of Triassic age have not been identified in the Helan Shan or Zhuozi Shan, but small Triassic normal faults have been documented in the western and central Helan Shan. These characteristics most strongly support an extensional origin for the Triassic basin in NW Ordos. The basin is interpreted to have been a north-trending half graben, bound along its western margin by an east-dipping normal fault, presently concealed beneath Quaternary cover west of the Helan Shan. The eastern margin, now found in the Zhuozi Shan, has simple ramp-margin geometry. Driving mechanisms for this extension are not obvious due to limited documentation of Triassic structure throughout the region, but probably relate to far-field stresses from the Qinling or Jinsha active margins interacting with the stable Ordos block.  相似文献   
868.
Changes in environmental conditions can be accompanied by shifts in the distribution and abundances of organisms. When physical factors become unsuitable for growth ofZostera marina (eelgrass), which is a dominant seagrass species in North America, other more ruderal seagrass species, includingRuppia maritima (widgeongrass), often increase in abundance or replace the dominant species. We report the proliferation of widgeongrass into eelgrass beds in Mission Bay and San Diego Bay in San Diego, California, during the 1997 to 1998 El Niño Southern Oscillation (ENSO). Widgeongrass persisted in these eelgrass beds at least one year after a return to non-ENSO conditions and an increase in eelgrass density. We suggest that a warming of the water in two bays in San Diego by 1.5–2.5°C could result, in a permanent shift in the local seagrass vegetation from eelgrass to widgeongrass. This shift, could, have substantial ecosystem-level ramifications.  相似文献   
869.
Effective risk communication is central to good environmental risk management. While studies have shown that newspapers are the primary source of information to the public regarding environmental issues, little is known about how environmental news is used as a risk‐communication tool. This article explores the role of local information systems in risk communication, using newspaper content analysis as well as in‐depth interviews with journalists and community residents to develop a case study of an environmental assessment process for a nonhazardous industrial‐waste landfill. Results indicate that risk messages were chosen and shaped by journalists on the basis of their own exigencies. In addition, while newspapers were a major source of risk information, their impact was mitigated by resident distrust and access to other information sources, most notably their own personal information networks. These results have implications for environmental policy, as decision makers often use—either passively or actively—print media as a risk‐communication tool.  相似文献   
870.
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