Untersuchungen zum Abbau von Pharmaka in kommunalen Kläranlagen mit HPLC-Electrospray-Massenspektrometrie     

E. Mhle  C. Kempter  A. Kern  J. W. Metzger 《洁净——土壤、空气、水》1999,27(6):430-436

Examination of the Degradation of Drugs in Municipal Sewage Plants Using Liquid Chromatography-Electrospray Mass Spectrometry Numerous drugs can be identified in the secondary effluent of municipal sewage plants. In order to obtain information about the degree of elimination (adsorption, aerobic degradation) of these compounds, a batch reactor containing different drugs in environmentally relevant concentrations and a suspension of activated sludge was coupled to a HPLC-MS-MS system. During a testing period of three days concentration-time-curves were recorded. For most of the examined drugs (acetamidoantipyrine, crotamiton, diclofenac, primidone, propyphenazone) solely a strong decrease of the initial concentration within the first 15 minutes was observed, which was interpreted primarily as adsorption to the activated sludge. For acetaminophenol and pentoxifyllin an additional slower decrease in concentration within several hours was observed. This slower elimination was interpreted to be caused mainly by primary degradation. It could be shown that dihydrocodeine is oxidized to hydrocodone in the batch reactor. The conjugate acetaminophen glucuronide was cleaved.  相似文献   

A spatially explicit methodology for a priori estimation of field survey effort in environmental observation networks     

Carlos Guerra  Marc J. Metzger  João Honrado  Joaquim Alonso 《International journal of geographical information science》2013,27(10):2077-2098

When establishing environmental monitoring programmes, it crucial to make reliable cost estimates, especially where a field survey is involved. This paper presents a methodology for creating a spatial measure of a field survey effort (SE). A set of relevant variables affecting a SE (e.g. areas with rough terrain, or distant from the main road network) was classified using fuzzy sets and then combined to produce spatially explicit effort indicators, which were integrated to a single measure using an analytic hierarchy process (AHP). To evaluate this approach and identify the limits for its application, three spatially nested case studies were used to test the spatial expression of SE and the scalable capacity of the method itself. The presented methodology could cope with variations in the scale and data resolution, retrieving a coherent estimate of SE across the different case studies. The presented methodology is therefore useful for (i) testing the network designs for sampling bias related to SE, (ii) comparing alternative sampling designs, (iii) assessing the sampling costs and (iv) supporting the human and logistical resource management.  相似文献   

Use of LIDAR in landslide investigations: a review   总被引：13，自引：0，他引：13  

Michel Jaboyedoff  Thierry Oppikofer  Antonio Abellán  Marc-Henri Derron  Alex Loye  Richard Metzger  Andrea Pedrazzini 《Natural Hazards》2012,61(1):5-28

This paper presents a short history of the appraisal of laser scanner technologies in geosciences used for imaging relief by high-resolution digital elevation models (HRDEMs) or 3D models. A general overview of light detection and ranging (LIDAR) techniques applied to landslides is given, followed by a review of different applications of LIDAR for landslide, rockfall and debris-flow. These applications are classified as: (1) Detection and characterization of mass movements; (2) Hazard assessment and susceptibility mapping; (3) Modelling; (4) Monitoring. This review emphasizes how LIDAR-derived HRDEMs can be used to investigate any type of landslides. It is clear that such HRDEMs are not yet a common tool for landslides investigations, but this technique has opened new domains of applications that still have to be developed.  相似文献   

Live (stained) benthic foraminifera from the Rhône prodelta (Gulf of Lion,NW Mediterranean): Environmental controls on a river-dominated shelf     

A. Goineau  C. Fontanier  F.J. Jorissen  B. Lansard  R. Buscail  A. Mouret  P. Kerhervé  S. Zaragosi  E. Ernoult  C. Artéro  P. Anschutz  E. Metzger  C. Rabouille 《Journal of Sea Research》2011,65(1):58-75

In this paper, we investigate the ecology of live (rose Bengal stained) benthic foraminifera collected at 20 stations ranging from 15 to 100 m depth in the Rhône prodelta (Gulf of Lions, NW Mediterranean). These sites were sampled in September 2006, five months after the Rhône River annual flood. Statistical analyses based on foraminiferal communities (> 150 μm) divide our study area into six main biofacies directly related to environmental conditions. Miliolid species are abundant in the relict prodeltaic lobe which is characterised by sand with low organic matter content. Close to the river mouth, the limited oxygen penetration in the sediment combined with important hydro-sedimentary processes constitute stressful conditions for foraminiferal faunas dominated by opportunistic species (e.g. Leptohalysis scottii). With increasing distance from the river mouth, foraminiferal faunas (e.g. Nonionella turgida, Eggerella scabra) adapted to thrive in sediments enriched in Rhône-derived organic matter under more stable hydro-sedimentary conditions appear. In the distal part of the Rhône River influence, benthic species (e.g. Valvulineria bradyana, Textularia agglutinans) living in fine sediment enriched in both continental and marine organic compounds emerge. At the deepest stations located in the south-eastern part of our study area, benthic foraminiferal faunas (e.g. Bulimina aculeata, Melonis barleeanus, Bigenerina nodosaria) are highly diverse, underlining stable environmental conditions characterised by marine-derived organic matter supplies and relatively deep oxygen penetration depth in the sediment. We also compare foraminiferal faunas sampled in September 2006 with communities sampled in June 2005, one month after the Rhône River annual flood (Mojtahid et al., 2009). This comparison suggests that opportunistic species (e.g. B. aculeata, Cassidulina carinata, V. bradyana) have responded to organic matter inputs related to marine primary production in June 2005.  相似文献   

The credibility of volunteered geographic information   总被引：10，自引：0，他引：10  

Andrew J. Flanagin  Miriam J. Metzger 《GeoJournal》2008,72(3-4):137-148

The proliferation of information sources as a result of networked computers and other interconnected devices has prompted significant changes in the amount, availability, and nature of geographic information. Among the more significant changes is the increasing amount of readily available volunteered geographic information. Although volunteered information has fundamentally enhanced geographic data, it has also prompted concerns with regard to its quality, reliability, and overall value. This essay situates these concerns as issues of information and source credibility by (a) examining the information environment fostering collective information contribution, (b) exploring the environment of information abundance, examining credibility and related notions within this environment, and leveraging extant research findings to understand user-generated geographic information, (c) articulating strategies to discern the credibility of volunteered geographic information (VGI), including relevant tools useful in this endeavor, and (d) outlining specific research questions germane to VGI and credibility.  相似文献   

Mesoscale SST–wind stress coupling in the Peru–Chile current system: Which mechanisms drive its seasonal variability?     

Vera Oerder  François Colas  Vincent Echevin  Sebastien Masson  Christophe Hourdin  Swen Jullien  Gurvan Madec  Florian Lemarié 《Climate Dynamics》2016,47(7-8):2309-2330

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Seasonal variations of the ocean surface circulation in the vicinity of Palau   总被引：1，自引：0，他引：1  

Scott F. Heron  E. Joseph Metzger  William J. Skirving 《Journal of Oceanography》2006,62(4):413-426

The surface circulation in the western equatorial Pacific Ocean is investigated with the aim of describing intra-annual variations near Palau (134°30′ E, 7°30′ N). In situ data and model output from the Ocean Surface Currents Analysis—Real-time, TRIangle Trans-Ocean buoy Network, Naval Research Laboratory Layered Ocean Model and the Joint Archive for Shipboard ADCP are examined and compared. Known major currents and eddies of the western equatorial Pacific are observed and discussed, and previously undocumented features are identified and named (Palau Eddy, Caroline Eddy, Micronesian Eddy). The circulation at Palau follows a seasonal variation aligned with that of the Asian monsoon (December–April; July–October) and is driven by the major circulation features. From December to April, currents around Palau are generally directed northward with speeds of approximately 20 cm/s, influenced by the North Equatorial Counter-Current and the Mindanao Eddy. The current direction turns slightly clockwise through this boreal winter period, due to the northern migration of the Mindanao Eddy. During April–May, the current west of Palau is reduced to 15 cm/s as the Mindanao Eddy weakens. East of Palau, a cyclonic eddy (Palau Eddy) forms producing southward flow of around 25 cm/s. The flow during the period July to September is disordered with no influence from major circulation features. The current is generally northward west of Palau and southward to the east, each with speeds on the order of 5 cm/s. During October, as the Palau Eddy reforms, the southward current to the east of Palau increases to 15 cm/s. During November, the circulation transitions to the north-directed winter regime.  相似文献   

Microsomal estrogen metabolism in channel catfish     

Butala H  Metzger C  Rimoldi J  Willett KL 《Marine environmental research》2004,58(2-5):489-494

Our goal was to study the involvement of cytochrome P450 genes in estrogen metabolism and the extent to which the potentially carcinogenic 4-hydroxyestradiol metabolite is formed by channel catfish (Ictalurus punctatus; CC). Estradiol metabolism and ethoxyresorufin-O-deethylase (EROD) activity were assessed in several tissues from fish collected from three variably contaminated sites in the Mississippi River Delta, from laboratory control fish, and from fish exposed to 20 mg/kg benzo(a)pyrene (BaP) i.p. for 4 days. Liver EROD activity was induced by BaP, but Delta fish EROD activities were not statistically higher than activities in control fish. Gill microsomal EROD activity was also induced by BaP, but activities were 8- to 77-fold lower than those from liver. The predominant estrogen metabolites formed by CC liver, gill and gonad microsomes were 2-hydroxyestradiol and estrone as detected by GC/MS. Liver and gill 2-hydroxyestradiol formation was induced in BaP-dosed fish. The trends in hydroxyestradiol formation in field collected fish were more variable. In all fish liver microsomes there was more 2- compared to 4-hydroxyestradiol formed. However, BaP-treatment increased the 4:2 hydroxyestradiol ratio from 0.04 in control fish to 0.2 in BaP-exposed fish, suggesting that BaP induces the formation of the potentially genotoxic estrogen metabolite. No detectable 4-hydroxyestradiol was produced by gill and gonad microsomes. These results will ultimately help in determining which fish P450 genes are susceptible to environmental contamination and may be involved in estrogen genotoxicity.  相似文献   

Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)   总被引：4，自引：0，他引：4  

Franoise Elbaz-Poulichet  Jean Luc Seidel  Didier Jzquel  Edouard Metzger  Franois Prvot  Caroline Simonucci  Grard Sarazin  Eric Viollier  Henri Etcheber  Jean-Marie Jouanneau  Olivier Weber  Olivier Radakovitch 《Marine Chemistry》2005,95(3-4):271-281

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.  相似文献   

Nickel-rich outflows from accretion discs formed by the accretion-induced collapse of white dwarfs     

B. D. Metzger  A. L. Piro  E. Quataert 《Monthly notices of the Royal Astronomical Society》2009,396(3):1659-1664

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