Impacts of freshwater on the seasonal variations of surface salinity and circulation in the Caspian Sea     

A. Birol Kara  Alan J. Wallcraft  E. Joseph Metzger  Murat Gunduz 《Continental Shelf Research》2010,30(10-11):1211-1225

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Thermal decomposition processes in algaenan of Botryococcus braunii race L. Part 1: Experimental data and structural evolution     

Elodie Salmon  Françoise Behar  François Lorant  Patrick G. Hatcher  Pierre Metzger  Paul-Marie Marquaire 《Organic Geochemistry》2009,40(3):400-415

The thermal reactivity of organic matter in source rocks is usually kinetically represented by a set of parallel and independent first order reactions. The approach assumes that only defunctionalisation reactions take place upon thermal decomposition, regardless of the chemical nature of kerogen. We have developed a new method for evaluating maturation pathways for an important kerogen-forming geopolymer, algaenan from the alga Botryococcus braunii (B. braunii), involving molecular dynamic reactive modelling based on quantum mechanics to reproduce maturation. To achieve this, a structural model is first constructed on the basis of models from the literature and analytical characterization of our samples using modern 1D and 2D nuclear magnetic resonance spectroscopy (NMR), Fourier transform infrared spectroscopy (FTIR) and elemental analysis (EA). Then, thermal decomposition of the algaenan is performed at low conversion in order to describe the initial transformations analytically. In an additional step, the observed chemical changes are quantitatively and qualitatively compared to simulated maturation from the molecular models. From this simulated maturation detailed reaction schemes are extracted for primary cracking mechanisms.  相似文献   

Asymptotic transport parameters in a heterogeneous porous medium: Comparison of two ensemble-averaging procedures     

D. Metzger  H. Kinzelbach  I. Neuweiler  W. Kinzelbach 《Stochastic Environmental Research and Risk Assessment (SERRA)》1999,13(6):396-415

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In situ measurements of particle load and transport in dust devils     

S.M. Metzger  M.C. Towner 《Icarus》2011,214(2):766-772

In situ (mobile) sampling of 33 natural dust devil vortices reveals very high total suspended particle (TSP) mean values of 296 mg m⁻³ and fine dust loadings (PM10) mean values ranging from 15.1 to 43.8 mg m⁻³ (milligrams per cubic meter). Concurrent three-dimensional wind profiles show mean tangential rotation of 12.3 m s⁻¹ and vertical uplift of 2.7 m s⁻¹ driving mean vertical TSP flux of 1689 mg m⁻³ s⁻¹ and fine particle flux of ∼1.0 to ∼50 mg m⁻³ s⁻¹. Peak PM10 dust loading and flux within the dust column are three times greater than mean values, suggesting previous estimates of dust devil flux might be too high. We find that deflation rates caused by dust devil erosion are ∼2.5-50 μm per year in dust devil active zones on Earth. Similar values are expected for Mars, and may be more significant there where competing erosional mechanisms are less likely.  相似文献   

Use of voltammetric solid-state (micro)electrodes for studying biogeochemical processes: Laboratory measurements to real time measurements with an in situ electrochemical analyzer (ISEA)     

George W. Luther III  Brian T. Glazer  Shufen Ma  Robert E. Trouwborst  Tommy S. Moore  Edouard Metzger  Chareonkwan Kraiya  Tim J. Waite  Gregory Druschel  Bjrn Sundby  Martial Taillefert  Donald B. Nuzzio  Timothy M. Shank  Brent L. Lewis  Paul J. Brendel 《Marine Chemistry》2008,108(3-4):221-235

Solid-state voltammetric (micro)electrodes have been used in a variety of environments to study biogeochemical processes. Here we show the wealth of information that has been obtained in the study of sediments, microbial mats, cultures and the water column including hydrothermal vents. Voltammetric analyzers have been developed to function with operator guidance and in unattended mode for temporal studies with an in situ electrochemical analyzer (ISEA). The electrodes can detect the presence (or absence) of a host of redox species and trace metals simultaneously. The multi-species capacity of the voltammetric electrode can be used to examine complex heterogeneous environments such as the root zone of salt marsh sediments. The data obtained with these systems clearly show that O₂ and Mn²⁺ profiles in marine sedimentary porewaters and in microbial biofilms on metal surfaces rarely overlap indicating that O₂ is not a direct oxidant for Mn²⁺. This lack of overlap was suggested originally by Joris Gieskes' group. In waters emanating from hydrothermal vents, Fe²⁺, H₂S and soluble molecular FeS clusters (FeS_aq) are detected indicating that the reactants for the pyrite formation reaction are H₂S and soluble molecular FeS clusters. Using the ISEA with electrodes at fixed positions, data collected continuously over three days near a Riftia pachyptila tubeworm field generally show that O₂ and H₂S anti-correlate and that H₂S and temperature generally correlate. Unlike sedimentary environments, the data clearly show that Riftia live in areas where both O₂ and H₂S co-exist so that its endosymbiont bacteria can perform chemosynthesis. However, physical mixing of diffuse flow vent waters with oceanic bottom waters above or to the side of the tubeworm field can dampen these correlations or even reverse them. Voltammetry is a powerful technique because it provides chemical speciation data (e.g.; oxidation state and different elemental compounds/ions) as well as quantitative data. Because (micro)organisms occupy environmental niches due to the system's chemistry, it is necessary to know chemical speciation. Voltammetric methods allow us to study how chemistry drives biology and how biology can affect chemistry for its own benefit.  相似文献   

Live (stained) benthic foraminifera in the Whittard Canyon, Celtic margin (NE Atlantic)   总被引：1，自引：0，他引：1  

P. Duros  C. Fontanier  E. Metzger  A. PuscedduF. Cesbron  H.C. de StigterS. Bianchelli  R. DanovaroF.J. Jorissen 《Deep Sea Research Part I: Oceanographic Research Papers》2011,58(2):128-146

Living (Rose Bengal stained) benthic foraminifera were investigated at 18 deep-sea stations sampled in the Whittard Canyon area (NE Atlantic). The stations were positioned along 4 bathymetric transects ranging from 300 to 3000 m depth: two along the main canyon axes (Western and Eastern branches) and two along adjacent open slopes (Western and Eastern slopes). The aim of this study was to assess changes of foraminiferal standing stock, composition and microhabitat in relation to the physico-chemical conditions prevailing at and below the sediment-water interface in various canyon and open-slope environments. Minimal oxygen penetration depths and maximal diffusive oxygen uptakes were recorded at upper canyon stations, suggesting a high mineralisation rate. This is confirmed by the high phytopigment concentrations measured in the sediment of the upper canyon axes. Foraminiferal abundance was positively correlated with diffusive oxygen uptake and phytopigment concentration in the sediment. This suggests a control of organic matter fluxes on the foraminiferal communities. Foraminiferal abundance was generally higher along the canyon axis compared to open-slope sites at comparable water depths. The species composition varied with water depth along all four transects, but was also different between canyon branches and adjacent slopes. The silty/sandy intercalations at many of the deeper canyon stations may have been rapidly deposited by fairly recent gravity flows. At station 51WB (3002 m), the faunal characteristics (strong dominance, shallow infaunal microhabitats) suggest that the foraminiferal community is in an early state of ecosystem colonisation after these recent sedimentation events, which would have supplied the important amounts of phytopigments.  相似文献   

Techniques for assessing spatial heterogeneity of carbonate δ13C values: Implications for craton‐wide isotope gradients     

J. Garrecht Metzger  David A. Fike 《Sedimentology》2013,60(6):1405-1431

The sedimentary record of carbonate carbon isotopes (δ¹³C_carb) provides one of the best methods for correlating marine strata and understanding the long‐term evolution of the global carbon cycle. This work focuses on the Late Ordovician Guttenberg isotopic carbon excursion, a ca 2·5‰ positive δ¹³C_carb excursion that is found in strata globally. Substantial variability in the apparent magnitude and stratigraphic morphology of the Guttenberg excursion at different localities has hampered high‐resolution correlations and led to divergent reconstructions of ocean chemistry and the biogeochemical carbon cycle. This work investigates the magnitude, spatial scale and sources of isotopic variability of the Guttenberg excursion in two sections from Missouri, USA. Centimetre‐scale isotope transects revealed variations in δ¹³C_carb and δ¹⁸O_carb greater than 2‰ across individual beds. Linear δ¹³C_carb to δ¹⁸O_carb mixing lines, together with petrographic and elemental abundance data, demonstrate that much of the isotopic scatter in single beds is due to mixing of isotopically distinct components. These patterns facilitated objective sample screening to determine the ‘least‐altered’ data. A δ¹⁸O_carb filter based on empirical δ¹⁸O_carb values of well‐preserved carbonate mudstones allowed further sample discrimination. The resulting ‘least‐altered’ δ¹³C_carb profile improves the understanding of regional as well as continental‐scale stratigraphic relations in this interval. Correlations with other Laurentian sections strongly suggest that: (i) small‐scale variability in Guttenberg excursion δ¹³C_carb values may result in part from local diagenetic overprinting; (ii) peak‐Guttenberg excursion δ¹³C_carb values of the Midcontinent are not distinct from their Taconic equivalents; and (iii) no primary continental‐scale spatial gradient in δ¹³C_carb (for example, arising from chemically distinct ‘aquafacies’) is required during Guttenberg excursion‐time. This study demonstrates the importance of detailed petrographic and geochemical screening of samples to be used for δ¹³C_carb chemostratigraphy and for enhancing understanding of epeiric ocean chemistry.  相似文献   

Estimates of surface drifter trajectories in the equatorial Atlantic: a multi-model ensemble approach   总被引：3，自引：3，他引：0  

Robert Bruce Scott  Nicolas Ferry  Marie Drévillon  Charlie N. Barron  Nicolas C. Jourdain  Jean-Michel Lellouche  Edward Joseph Metzger  Marie-Hélène Rio  Ole Martin Smedstad 《Ocean Dynamics》2012,62(7):1091-1109

We compared the estimates of surface drifter trajectories from 1 to 7?days in the equatorial Atlantic over an 18-month period with five eddying ocean general circulation model (OGCM) reanalyses and one observational product. The cumulative distribution of trajectory error was estimated using over 7,000?days of drifter trajectories. The observational product had smaller errors than any of the individual OGCM reanalyses. Three strategies for improving trajectory estimates using the ensemble of five operational ocean analysis and forecasting products were explored: two methods using a multi-model ensemble estimate and also spatial low-pass filtering. The results were insensitive to the method used to create the ensemble estimates, and by most measures, the results were better than the observational product. Comparison of relative skill of the various OGCM reanalyses suggested promising avenues for exploration for further improvements: forcing with higher frequency wind stress and quality control of input data. One of the lowest horizontal resolution OGCMs, with 1/4° longitude horizontal resolution, made the best trajectory estimates. The individual OGCMs were dominated by errors at spatial scales smaller than about 100 to 200?km, i.e., less than the local deformation radius. But buried in those errors were valuable signals that could be retrieved by combining all the OGCM velocity fields to produce a multi-model ensemble-based estimate. This estimate had skill down to spatial scales about 75?km. Results from this study are consistent with previous work showing that ensemble-mean forecast skill is superior to individual forecasts.  相似文献   

Short-duration gamma-ray bursts with extended emission from protomagnetar spin-down     

B. D. Metzger  E. Quataert  T. A. Thompson 《Monthly notices of the Royal Astronomical Society》2008,385(3):1455-1460

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In situ disdrometer calibration using multiple DSD moments     

John E. Lane  Takis Kasparis  Philip T. Metzger  W. Linwood Jones 《Acta Geophysica》2014,62(6):1450-1477

In situ calibration is a proposed strategy for continuous as well as initial calibration of an impact disdrometer. In previous work, a collocated tipping bucket had been utilized to provide a rainfall rate based ～11/3 moment reference to an impact disdrometer’s signal processing system for implementation of adaptive calibration. Using rainfall rate only, transformation of impulse amplitude to a drop volume based on a simple power law was used to define an error surface in the model’s parameter space. By incorporating optical extinction second moment measurements with rainfall rate data, an improved in situ disdrometer calibration algorithm results due to utilization of multiple (two or more) independent moments of the drop size distribution in the error function definition. The resulting improvement in calibration performance can be quantified by detailed examination of the parameter space error surface using simulation as well as real data.  相似文献