Modeling of packed absorption tower for volatile organic compounds emission control     

M. S. Rahbar  T. Kaghazchi 《International Journal of Environmental Science and Technology》2005,2(3):207-215

Development of chemical industry and high vapor pressure of volatile organic compounds (VOCs) have been caused that these materials recently be considered as a source of air pollution. These are different methods for separation of VOC from air that absorption by suitable and selective solvent is an efficient method. In this research, mathematical modeling of a packed absorption tower for separation of VOCs from air has been presented. Then, acetone vapors separation in this tower and with Intalox saddle packing has been investigated. Concentration of acetone in inlet air stream was 1.5 mol % which has reduced to 150 ppm (0.015 mol %) in effluent air stream. The results show that the packed absorption tower with this type of packing can separate 99% of acetone vapors. Comparison of the results obtained by Intalox saddle packing with the results obtained by another type of packing (with trade mark of Kerapak patented by Sulzer Company) shows that the tower gives the same efficiency for acetone separation. Thus, the efficiency of absorption process, mainly, depends on solvent type, composition of VOC in feed air, desired composition of VOC in outlet air (or percentage of VOC separation) and pressure drop.  相似文献   

Seasonal records of climatic change in annually laminated tufas: short review and future prospects   总被引：3，自引：0，他引：3  

J. E. Andrews  A. T. Brasier 《第四纪科学杂志》2005,20(5):411-421

Many Recent and fossil freshwater tufa stromatolites contain millimetre‐scale, alternating laminae of dense micrite and more porous or sparry crystalline calcites. These alternating laminae have been interpreted to represent seasonally controlled differences in the biotic activity of microbes, and/or seasonally controlled changes in the rate of calcification. Either way, couplets of these microbially mediated alternating calcified laminae are generally agreed to represent annual seasonality. Combined stable isotope (δ¹⁸O and δ¹³C) and trace element (Mg, Sr, Ba) geochemistry from Recent tufa stromatolites show that seasonal climatic information is available from these calcites. Variability in δ¹⁸O (and in one case Mg concentration) has been shown to be controlled primarily by stream temperature change, usually driven by solar insolation. In arid climates, seasonal evaporation can also cause δ¹⁸O enrichment by at least 1‰. Variability in δ¹³C results potentially from: (1) seasonal change in plant uptake of ¹²C‐enriched CO₂; (2) seasonal change in degassing of ¹²C‐enriched CO₂ in the aquifer system; and (3) precipitation of calcite along the aquifer or river flow path, a process that increases δ¹³C of dissolved inorganic carbon (DIC) in the remaining water. Mechanisms 2 and 3 are linked because calcite precipitates in aquifers where degassing occurs, e.g. air pockets. The latter mechanism for δ¹³C enrichment has also been shown to cause sympathetic variation between trace element/Ca ratios and δ¹³C because trace elements with partition coefficients much greater than 1 (e.g. Sr, Ba) remain preferentially in solution. Since degassing in air pockets will be enhanced during decreased recharge when water saturation of the aquifer is lowest, sympathetic variation in trace element/Ca ratios and δ¹³C is a possible index of recharge and therefore precipitation intensity. High‐resolution geochemical data from well‐dated tufa stromatolites have great potential for Quaternary palaeoclimate reconstructions, possibly allowing recovery of annual seasonal climatic information including water temperature variation and change in rainfall intensity. However, careful consideration of diagenetic effects, particularly aggrading neomorphism, needs to be the next step. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Analysis of pressuremeter geometry effects in clay using critical state models   总被引：1，自引：0，他引：1  

H. S. Yu  M. T. Charles  C. D. Khong 《国际地质力学数值与分析法杂志》2005,29(8):845-859

The conventional interpretation methods of pressuremeter testing effectively approximate pressuremeter membranes as infinitely long. As a result, the effects of the two‐dimensional geometry of pressuremeters are ignored, leading to an overestimation of soil shear strength by pressuremeter testing, as demonstrated in several previous studies. This paper presents results of a numerical study of two‐dimensional geometry effects on self‐boring pressuremeter tests in undrained clay. The results are obtained using critical state soil models with an effective stress formulation. This is in contrast to most (if not all) existing studies on pressuremeter geometry effects, which were based on perfectly plastic soil models (e.g. Yu (Cavity expansion theory and its application to the analysis of pressuremeters. DPhil Thesis, The University of Oxford, 1990), Yeung and Carter (Proc. 3rd Int. Symp. on Pressuremeters, 1990), and Houlsby and Carter (Géotechnique, 1993; 43 (4):567–576)). The present study suggests that the overestimation of soil strength due to the neglect of finite pressuremeter length is significantly affected by the soil model used in the calculations. It is found that for clays with a high overconsolidation ratio (OCR) the strength overestimation predicted using critical state soil models could be considerably smaller than that predicted using perfectly plastic soil models. The main conclusion of this numerical study is that care must be exercised before directly applying any numerically determined pressuremeter geometry correction factors in practice. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Test of a distributed modelling approach to predict flood flows in the karst Suoimuoi catchment in Vietnam     

Y. B. Liu  O. Batelaan  F. De. Smedt  N. T. Huong  V. T. Tam 《Environmental Geology》2005,48(7):931-940

The major obstacles for modelling flood processes in karst areas are a lack of understanding and model representations of the distinctive features and processes associated with runoff generation and often a paucity of field data. In this study, a distributed flood-modelling approach, WetSpa, is modified and applied to simulate the hydrological features and processes in the karst Suoimuoi catchment in northwest Vietnam. With input of topography, land use and soil types in a GIS format, the model is calibrated based on 15 months of hourly meteorological and hydrological data, and is used to simulate both fast surface and conduit flows, and groundwater discharges from karst and non-karst aquifers. Considerable variability in the simulation accuracy is found among storm events and within the catchment. The simulation results show that the model is able to represent reasonably well the stormflows generated by rainfall events in the study catchment.  相似文献   

GIS-based detachment susceptibility analyses of a cut slope in limestone, Ankara—Turkey   总被引：3，自引：0，他引：3  

B. Oztekin  T. Topal 《Environmental Geology》2005,49(1):124-132

Due to the rapidly growing population of the city of Ankara (Turkey) and increased traffic congestion, it has become necessary to widen the Ankara-Eskişehir (E-90) highway connecting the newly built areas west of the city to the city center. During widening, several cut slopes were formed along the highway route. As a result, some instability problems (small-sized rock falls/sliding, sloughing, raveling) produced detachment zones along a cut slope in highly jointed, folded and sheared limestone, causing local degradation of the cut slope. Identification of the areas that are likely to detach from the cut slope in the future is considered to be very important for the application of remedial measures. For this purpose, the relationships between the existing detachment zones and various parameters (e.g., point load strength index, weathering, block size, daylighting, shear zone) were investigated using GIS-based statistical detachment susceptibility analyses in order to predict the further aerial extension of the detachment zones with time. During the overlay analyses, statistical index and weighting factor methods were used. The outcomes of the analyses were compared and evaluated with the field observations to check the reliability of the methods and to assess the detachment zones that may develop in the future. The detachment susceptibility map without the block-size layer gives the best result and indicates some risky zones where detachments are likely to occur in the future. Recommendations on remedial measures of the cut slope should consider these risky zones.  相似文献   

Native and artificial radiation-induced defects in montmorillonite. An EPR study     

S. Sorieul  T. Allard  G. Morin  B. Boizot  G. Calas 《Physics and Chemistry of Minerals》2005,32(1):1-7

A natural montmorillonite containing radiation-induced defects was studied with Electron Paramagnetic Resonance (EPR) spectroscopy (X- and Q-band). A first dominant native defect, namely native defect 1, is identified. It gives rise to an orthorhombic spectrum with g_x= 2.004 ± 0.005 g_y= 2.010 ± 0.003, g_z= 2.065 ± 0.002. Simulation of the EPR spectrum at X- and Q-band reveals a second native defect with isotropic spectrum at g= 2.019 ± 0.005. Both are electron holes trapped on oxygen atoms of the structure. The native defect 1 is located on an oxygen-silicon bond or a non-bonding orbital parallel to the c* axis. These defects are annealed at 500°C and the half-life determined for native defect 1 is circa 3,000 years. Irradiations with beta rays produced two additional hole centers of lower stability and distinct EPR parameters. Artificial irradiations show that montmorillonite can be used as a dosimeter in a large dose range.  相似文献   

Prediction of creep characteristic of rock under varying environment   总被引：2，自引：0，他引：2  

T. N. Singh  A. K. Verma 《Environmental Geology》2005,48(4-5):559-568

The strain developed due to creep is mainly proportional to the logarithm of the time under load, and is mostly proportional to the stress and temperature. At higher temperature the creep rate falls slowly with respect to time, and the creep strain is proportional to a fractional power of time, with the exponent increasing as the temperature increases and reaching a value approximately one-third at temperatures of about 0.5°C. At these temperatures, the creep increases with stress according to a power greater than unity and possibly exponentially. It increases with temperature as (−U/kT), where U is an activation energy and k is Boltzman’s constant. There are different methods to determine the creep strain and the energy of Jog (B) including experimental methods, multivariate regression analysis, and by numerical simulation. These methods are less cumbersome and time consuming. In the present investigation, artificial neural network technique has been used for prediction of the creep strain and energy of Jog (B). Two different networks have been tested and validated. Both the networks have four input neurons and one hidden layer with five neurons, and one output neuron. The data for different rocks at temperatures up to 750°C under conditions of compressive or tortional stress are taken from the literatures. The training and testing data sets used were 163 and 14, respectively. To deal with the problem of overfitting of data, Bayesian regulation has been used and network is trained with suitable training epochs. The coefficients of correlation among the predicted and observed values are found high and they improve the confidence of the users. The mean absolute percentage error obtained are also very low.  相似文献   

GPS monitoring of vertical ground motion in northern Ardenne–Eifel: five campaigns (1999–2003) of the HARD project     

A. Demoulin  J. Campbell  A. De. Wulf  A. Muls  R. Arnould  B. Görres  D. Fischer  T. Kötter  M. Brondeel  D. Van. Damme  J. M. Jacqmotte 《International Journal of Earth Sciences》2005,94(4):515-524

We present the HARD project of GPS monitoring of vertical ground motion in NE Ardenne and Eifel (western Europe). Its main purposes are to get a better insight into the present-day rates of vertical ground motion in intraplate settings and to identify the various causes of these motions. Since 1999, we have carried out yearly campaigns of simultaneous GPS measurements at 12 sites situated so as to sample the different tectonic subunits of the study area and especially to record potential displacements across the seismogenic Hockai fault zone. Five campaigns (1999–2003) have been processed currently. Key issues of the data processing with the Gamit software are discussed and first results are presented. Though temporally consistent in many cases, the obtained vertical motion rates are spatially highly variable. They are also much too high (several mm/year) to support a tectonic interpretation, and a long-term influence of groundwater level variations is proposed to account for the observed motions. This influence should be distinguished from seasonal variations and from inter-survey variations linked to the varying degree of soil and subsoil drying off during the successive spring surveys.  相似文献   

Constraints from Thorium/Lanthanum on Sediment Recycling at Subduction Zones and the Evolution of the Continents   总被引：20，自引：3，他引：20  

PLANK  T. 《Journal of Petrology》2005,46(5):921-944

Arc magmas and the continental crust share many chemical features,but a major question remains as to whether these features arecreated by subduction or are recycled from subducting sediment.This question is explored here using Th/La, which is low inoceanic basalts (<0·2), elevated in the continents(>0·25) and varies in arc basalts and marine sediments(0·09–0·34). Volcanic arcs form linear mixingarrays between mantle and sediment in plots of Th/La vs Sm/La.The mantle end-member for different arcs varies between highlydepleted and enriched compositions. The sedimentary end-memberis typically the same as local trench sediment. Thus, arc magmasinherit their Th/La from subducting sediment and high Th/Lais not newly created during subduction (or by intraplate, adakiteor Archaean magmatism). Instead, there is a large fractionationin Th/La within the continental crust, caused by the preferentialpartitioning of La over Th in mafic and accessory minerals.These observations suggest a mechanism of ‘fractionation& foundering’, whereby continents differentiate intoa granitic upper crust and restite-cumulate lower crust, whichperiodically founders into the mantle. The bulk continentalcrust can reach its current elevated Th/La if arc crust differentiatesand loses 25–60% of its mafic residues to foundering. KEY WORDS: arc magmatism; continental crust; delamination; thorium; sediment subduction  相似文献   

Groundwater control of mangrove surface elevation: Shrink and swell varies with soil depth     

Kevin R. T. Whelan  Thomas J. Smith  Donald R. Cahoon  James C. Lynch  Gordon H. Anderson 《Estuaries and Coasts》2005,28(6):833-843

We measured monthly soil surface elevation change and determined its relationship to groundwater changes at a mangrove forest site along Shark River, Everglades National Park, Florida. We combined the use of an original design, surface elevation table with new rod-surface elevation tables to separately track changes in the mid zone (0–4 m), the shallow root zone (0–0.35 m), and the full sediment profile (0–6 m) in response to site hydrology (daily river stage and daily groundwater piezometric pressure). We calculated expansion and contraction for each of the four constituent soil zones (surface [accretion and erosion; above 0 m], shallow zone [0–0.35 m], middle zone [0.35–4 m], and bottom zone [4–6]) that comprise the entire soil column. Changes in groundwater pressure correlated strongly, with changes in soil elevation for the entire profile (Adjusted R² = 0.90); this relationship was not proportional to the depth of the soil profile sampled. The change in thickness of the bottom soil zone accounted for the majority (R² = 0.63) of the entire soil profile expansion and contraction. The influence of hydrology on specific soil zones and absolute elevation change must be considered when evaluating the effect of disturbances, sea level rise, and water management decisions on coastal wetland systems.  相似文献