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1.
Rabindra N Roy Lakshimi N Roy Kathleen M Vogel C Porter-Moore Tara Pearson Catherine E Good Frank J Millero Douglas M Campbell 《Marine Chemistry》1993,44(2-4)
The pK1* and pK2* for the dissociation of carbonic acid in seawater have been determined from 0 to 45°C and S = 5 to 45. The values of pK1* have been determined from emf measurements for the cell: where X is the mole fraction of CO2 in the gas. The values of pK2* have been determined from emf measurements on the cell: The results have been fitted to the equations: where T is the temperature in K, S is the salinity, and the standard deviations of the fits are σ = 0.0048 in lnK1* and σ = 0.0070 in lnK2*.Our new results are in good agreement at S = 35 (±0.002 in pK1*and ±0.005 in pK2*) from 0 to 45°C with the earlier results of Goyet and Poisson (1989). Since our measurements are more precise than the earlier measurements due to the use of the Pt, H2|AgCl, Ag electrode system, we feel that our equations should be used to calculate the components of the carbonate system in seawater. 相似文献
Pt](1 − X)H2 + XCO2|NaHCO3, CO2 in synthetic seawater|AgC1; Ag
Pt, H2(g, 1 atm)|Na2CO3, NaHCO3 in synthethic seawater|AgC1; Ag
lnK*1 = 2.83655 − 2307.1266/T − 1.5529413 lnT + (−0.20760841 − 4.0484/T)S0.5 + 0.08468345S − 0.00654208S1
InK*2 = −9.226508 − 3351.6106/T− 0.2005743 lnT + (−0.106901773 − 23.9722/T)S0.5 + 0.1130822S − 0.00846934S1.5
2.
Two different goals in fitting straight lines to data are to estimate a true linear relation (physical law) and to predict values of the dependent variable with the smallest possible error. Regarding the first goal, a Monte Carlo study indicated that the structural-analysis (SA) method of fitting straight lines to data is superior to the ordinary least-squares (OLS) method for estimating true straight-line relations. Number of data points, slope and intercept of the true relation, and variances of the errors associated with the independent (X) and dependent (Y) variables influence the degree of agreement. For example, differences between the two line-fitting methods decrease as error in X becomes small relative to error in Y. Regarding the second goal—predicting the dependent variable—OLS is better than SA. Again, the difference diminishes as X takes on less error relative to Y. With respect to estimation of slope and intercept and prediction of Y, agreement between Monte Carlo results and large-sample theory was very good for sample sizes of 100, and fair to good for sample sizes of 20. The procedures and error measures are illustrated with two geologic examples. 相似文献
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Qualitative GIS is a relatively new methodological approach for analyzing and visualizing qualitative data within a geographic context. Qualitative data can take many forms, including interviews, documents, photographs, and audio and video clips. Content analysis for example, is an effective qualitative method for analyzing text‐based data. We argue that basic concepts, (i.e. how to store data, data requirements, visualization techniques, and modes of analysis) within qualitative GIS have not been adequately defined, rendering difficult the replication of work performed and hindering the development of incremental knowledge in the field. Database management systems provide a means for storing, managing, and analyzing qualitative GIS data. A standardized and well‐designed open source database system provides a mechanism for qualitative GIS projects, ensuring consistency and project replication. Qualitative GIS data stored in a database allows for additional visualization options, such as geographic word clouds. To demonstrate the concepts we performed content analysis on Master Transportation Plans from Calgary and Montreal using SpatiaLite, an open source database system. We developed Structured Query Language (SQL) queries to generate and populate groups and theme tables within the SpatiaLite database. We present our database design and queries in the hopes that they will help others conducting qualitative GIS research. 相似文献
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If utilized, the energy dissipative capability of seismically loaded shallow foundations due to inelastic behavior can result in more economic design, provided the consequences, such as excessive deformations are accounted for. In this article, a Beam‐on‐Nonlinear‐Winkler‐Foundation (BNWF) model is used to assess the performance of shearwall‐foundation systems with different attributes, when subjected to ground motions of varied hazard levels. The numerical study indicates that the force and drift demands to the shearwall reduce significantly, when nonlinear foundation behavior is realized, while permanent settlement is well below the permissible limit. These results support the concept of shallow foundation capacity mobilization in future design. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
7.
Jeffrey E. Moore Bryan P. Wallace Rebecca L. Lewison Ramúnas Žydelis Tara M. Cox Larry B. Crowder 《Marine Policy》2009
This paper reviews the available information (observer programs, estimates, statutes, regulations) for bycatch of marine mammals, sea turtles, and seabirds in fisheries of the United States. Goals of the review were to evaluate the state of knowledge of bycatch and the role of existing protective legislation in shaping bycatch management for different taxa. Pressing issues are identified, as well as knowledge gaps and policy limitations that hinder multi-species bycatch reduction. The USA has made important progress toward reducing bycatch in its fisheries, but the efficacy of its management has been limited somewhat by a focus on taxon- and fishery-specific regulation and the lack of consistent mandate across taxa for taking a cumulative perspective on bycatch. Applying consistent criteria across taxa for setting bycatch limits (e.g., extending the approach used for marine mammals to sea turtles and seabirds) would be the first step in a multi-species approach to bycatch reduction. A population-based multi-species multi-gear approach to bycatch would help identify priority areas where resources are needed most and can be used most effectively. 相似文献
8.
In this paper the ability of analytical solutions for four-component three-phase flow to predict displacement efficiency in
water alternating gas (WAG) injection processes is studied. First analytical solutions for Riemann problems with injection
compositions that are the average water and gas mixture for various WAG injection schemes are presented. These solutions are
compared to numerical calculations with variable slug sizes and used to explore the effect of slug size, injecting water vs
gas first, and the average injection composition on displacement efficiency in compositional WAG schemes. The example model
is partially miscible WAG injection of water and CO2 into an oil reservoir containing C10 and CH4 with and without a mobile aqueous phase present initially. The trailing end of the water and gas profiles are sensitive to
whether water or gas is injected first, but the magnitude of the oil bank and the breakthrough time of the injected fluids
are accurately predicted by the analytical solutions, even for displacements where large water and gas slugs are injected.
Fluctuations in the saturation and composition profiles resulting from the alternating injection sequence in the WAG simulations
appear as super-imposed on top of the sequence of rarefaction and shock waves predicted by analytical solutions. As the number
of slugs increases, the effect of alternating boundary conditions diminishes and the displacements predicted by numerical
calculations converge to the analytical solutions. 相似文献
9.
Tara A. Kniskern Jonathan A. Warrick Katherine L. Farnsworth Robert A. Wheatcroft Miguel A. Goñi 《Continental Shelf Research》2011,31(7-8):789-805
The majority of water and sediment discharge from the small, mountainous watersheds of the US West Coast occurs during and immediately following winter storms. The physical conditions (waves, currents, and winds) within and acting upon the proximal coastal ocean during these winter storms strongly influence dispersal patterns. We examined this river–ocean temporal coherence for four coastal river–shelf systems of the US West Coast (Umpqua, Eel, Salinas, and Santa Clara) to evaluate whether specific ocean conditions occur during floods that may influence coastal dispersal of sediment. Eleven years of corresponding river discharge, wind, and wave data were obtained for each river–shelf system from USGS and NOAA historical records, and each record was evaluated for seasonal and event-based patterns. Because near-bed shear stresses due to waves influence sediment resuspension and transport, we used spectral wave data to compute and evaluate wave-generated bottom-orbital velocities. The highest values of wave energy and discharge for all four systems were consistently observed between October 15 and March 15, and there were strong latitudinal patterns observed in these data with lower discharge and wave energies in the southernmost systems. During floods we observed patterns of river–ocean coherence that differed from the overall seasonal patterns. For example, downwelling winds generally prevailed during floods in the northern two systems (Umpqua and Eel), whereas winds in the southern systems (Salinas and Santa Clara) were generally downwelling before peak discharge and upwelling after peak discharge. Winds not associated with floods were generally upwelling on all four river–shelf systems. Although there are seasonal variations in river–ocean coherence, waves generally led floods in the three northern systems, while they lagged floods in the Santa Clara. Combined, these observations suggest that there are consistent river–ocean coherence patterns along the US West Coast during winter storms and that these patterns vary substantially with latitude. These results should assist with future evaluations of flood plume formation and sediment fate along this coast. 相似文献
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