Assessing Pesticide Contamination to Ground Water: A Rapid Approach   总被引：1，自引：0，他引：1  

Majid Ehteshami  Richard C. Peralta  Hubert Eisele  Howard Deer  Terry Tindall 《Ground water》1991,29(6):862-868

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The structure, mass and interactions of the hydrothermal plumes at 26°N on the Mid-Atlantic Ridge     

Terry A. Nelsen  Evan B. Forde 《Earth and Planetary Science Letters》1991,106(1-4)

Water-column surveys by combined nephelometer/CTD (NCTD) tows contributed to the 1985 discovery of the first black smokers on the Mid-Atlantic Ridge. Subsequent regional water-column mapping has helped define the extent, mass and interactions of the suspended particulate matter phase (SPM) of the hydrothermal plumes emanating from the known and other nearby sources. The results of 29 NCTD cast/tows, covering 25–30 km² of ridge segment, indicate the presence of as many as two additional sources based on SPM concentration gradients and plume-top doming over source areas. Plume doming, documented here for the first time from field observations, conforms strikingly with laboratory experiments and can serve as a marker for source field location. A comparison of the plumes' SPM with potential temperature and salinity distributions indicates close correlation in water-column anomaly patterns for each, confirming modification of the regional potential temperature and salinity structure by hydrothermal plumes, which is expressed by wide separation and sloping of isotherms and isohalines.  相似文献   

The role of salt in fold-and-thrust belts     

Dan M. Davis  Terry Engelder 《Tectonophysics》1985,119(1-4)

The style of deformation in thin-skinned fold-and-thrust belts is critically dependent upon the resistance to sliding along the detachment between the mass of deforming sediments and the underlying rocks. Evaporites can provide an extremely weak horizon within which a basal detachment can form and along which only a relatively small shear traction can be supported. Fold-and-thrust belts that form atop a salt layer, such as the Appalachian Plateau, the Franklin Mountains in northwestern Canada, and the Jura of the Alps, among others, share several readily observable characteristics. As predicted by a simple mechanical model for fold-and-thrust belts, a detachment in salt permits a thrust belt to have an extremely narrow cross-sectional taper. In addition, predicted orientations of the principal stress axes over a salt décollement are consistent with the commonly observed lack of a consistently dominant vergence direction of structures within the thrust belt. Other common attributes of salt-basal thin-skinned deformation include the presence of several widely but regularly spaced folds and abrupt changes in deformational style at the edge of the salt basin.  相似文献   

He diffusion in olivine   总被引：1，自引：0，他引：1  

S.R. Hart 《Earth and Planetary Science Letters》1984,70(2):297-302

Helium diffusion in olivine (dunite xenolith) has been measured in the temperature range 1180–1460°C; a linear Arrhenius function was obtained with an activation energy of 120₋₂₇⁺³² kcal/mole, and a pre-exponential factor (D₀) = 2.2 × 10⁸ cm²/s.

Diffusion mechanisms are not a viable means of degassing He from the mantle. Olivine phenocrysts can be expected to retain previously trapped He, during cooling in extrusive basalts, provided the flow units are thinner than 50 m; xenoliths will retain mantle He signatures only if magma transport times are less than 50 years, or if the He fugacity in the magma is high enough to prevent xenolith degassing. The lower oceanic crust is probably substantially degassed of He. Trapped He will be qualitatively retained in quenched submarine basalt glass only if the cooling rate is faster than 5 × 10¹⁴°C/m.y.; glass at several centimeters depth in a basalt flow (near the spherulite zone) will have cooling rates lower than this, so He loss may be significant in many basalt glass samples.  相似文献   

The stability and behavior of a frictional system with a two state variable constitutive law     

Michael L. Blanpied  Terry E. Tullis 《Pure and Applied Geophysics》1986,124(3):415-444

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Ocean crust vein mineral deposition: Rb/Sr ages, U-Th-Pb geochemistry, and duration of circulation at DSDP sites 261, 462 and 516     

S. R. Hart 《Geochimica et cosmochimica acta》1986,50(12):2751-2761

Cation exchange experiments (ammonium acetate and cation resin) on celadonite-smectite vein minerals from three DSDP holes demonstrate selective removal of common Sr relative to Rb and radiogenic Sr. This technique increases the Rb/Sr ratio by factors of 2.3 to 22 without significantly altering the age of the minerals, allowing easier and more precise dating of such vein minerals. The ages determined by this technique (site 261—121.4 ±1.6 m.y.; site 462A—105.1 ±2.8 m.y.; site 516F—69.9 ±2.4 m.y.) are 34, 54 and 18 m.y. younger, respectively, than the age of crust formation at the site; in the case of site 462A, the young age is clearly related to off-ridge emplacement of a massive sill/flow complex. At the other sites, either the hydrothermal circulation systems persisted longer than for normal crust (10–15 m.y.), or were reactivated by off-ridge igneous activity.

Celadonites show U and Pb contents and Pb isotopic compositions little changed from their basalt precursors, while Th contents are significantly lower. Celadonites thus have unusually high alkali/U,Th ratios and low Th/U ratios. If this celadonite alteration signature is significantly imprinted on oceanic crust as a whole, it will lead to very distinctive Pb isotope signatures for any hot spot magmas which contain a component of aged subducted recycled oceanic crust.

Initial Sr isotope ratios of ocean crust vein minerals (smectite, celadonite, zeolite, calcite) are intermediate between primary basalt values and contemporary sea water values and indicate formation under seawaterdominated systems with effective water/rock ratios of 20–200.  相似文献   

Chemical structure and evolution of the mantle and continents determined by inversion of Nd and Sr isotopic data,I. Theoretical methods     

C.J. Allègre  S.R. Hart  J.-F. Minster 《Earth and Planetary Science Letters》1983

While the chemical structure of the earth's mantle is probably rather complex, multi-box models have been used as a first approximation to evaluate this structure. Most commonly, a three-box model is used, involving the continental crust, the upper mantle and the lower mantle. The depleted upper mantle and the continental crust are assumed to represe1nt complementary reservoirs, related by crust formation processes occurring during geologic history.Here we investigate the Rb/Sr and Sm/Nd isotopic systematics of several three-box models, using mass balance equations and the definition of the mean age of the reservoirs. The geochemical uniqueness of the models, chosen from a large family of possible models, is evaluated from elementary graph theory, and these models are then solved using a total inversion approach. This paper (Part I) describes the methodology of the procedure; the companion paper (Part II) discusses the application of this approach to multi-box mantle models.  相似文献   

Possible contribution of leakage currents from the Atlantic Ocean to the magnetic-field variations observed in Devon     

A.M. Hart  P.J. Krause  W.G.V. Rosser 《Physics of the Earth and Planetary Interiors》1983,32(2):107-113

It is suggested that leakage currents flow across Devon, north of Exeter, from large-scale electric-current systems induced in the Atlantic Ocean by the geomagnetic variations incident on the Atlantic Ocean from the ionosphere. This model can account for the variation with period of the contribution of induced current flow to the differences in the magnetic H variations of period > 30 s observed at Exeter and Sidmouth.  相似文献   

Selective concentration of cesium in analcime during hydrothermal alteration,Yellowstone National Park,Wyoming     

Terry E.C Keith  J.M Thompson  Robert E Mays 《Geochimica et cosmochimica acta》1983,47(4):795-804

Chemical and mineralogical studies of fresh and hydrothermally altered rhyolitic material in Upper and Lower Geyser Basins, Yellowstone National Park, show that all the altered rocks are enriched in Cs and that Cs is selectively concentrated in analcime. The Cs content of unaltered rhyolite lava flows, including those from which the altered sediments are derived, ranges from 2.5 to 7.6 ppm. The Cs content of analcime-bearing altered sedimentary rocks is as high as 3000 ppm, and in clinoptilolite-bearing altered sedimentary rocks Cs content is as high as 180 ppm. Altered rhyolite lava flows which were initially vitrophyres, now contain up to 250 ppm Cs, and those which were crystallized prior to hydrothermal alteration contain up to 14 ppm. Mineral concentrates of analcime contain as much as 4700 ppm Cs. The Cs must have been incorporated into the analcime structure during crystallization, rather than by later cation substitution, because analcime does not readily exchange Cs. The $\text{Cs}\text{Cl}$ of the fluids circulating through the hydrothermal system varies, suggesting that Cs is not always a conservative ion and that Cs is lost from upflowing thermal waters due to water-rock interaction resulting in crystallization of Cs-bearing analcime.The source of Cs for Cs enrichment of the altered rocks is from leaching of rhyolitic rocks underlying the geyser basins, and from the top of the silicic magma chamber that underlies the area.Analcime is an important natural Cs sink, and the high Cs concentrations reported here may prove to be an important indicator of the environment of analcime crystallization.  相似文献   

Alteration of basaltic glass: Mechanisms and significance for the oceanic crust-seawater budget   总被引：1，自引：0，他引：1  

Hubert Staudigel  Stanley R. Hart 《Geochimica et cosmochimica acta》1983,47(3):337-350

Alteration of basaltic glass to palagonite is characterized by a nearly isomolar exchange of SiO₂, Al₂O₃, MnO, MgO, CaO, Na₂O, P₂O₅, Zn, Cu, Ni, Cr, Hf, Sc, Co and REE for H₂O and K₂O, whilst TiO₂ and FeO are passively accumulated during removal of the remaining cations. The network forming cations Al and Si are removed from the glass in proportion to the gain in Ti and Fe, whilst the other cations do not show a significant relationship to the amount of Ti and Fe accumulation. Sr isotopic data show that during palagonite formation approximately 85% of the basaltic Sr is lost to the hydrous solutions and 40% of seawater Sr is added to the glass, yielding an average loss of the same order of magnitude as of the network forming cations. Losses and gains of oxides yield an average increase of +105% TiO₂.K, Rb, and Cs show high increases, but $\text{K}\text{Rb}$ and $\text{K}\text{Cs}$ ratios indicate two different alteration processes: (1) formation of palagonite involves a drastic decrease in these ratios, indicating structural similarities between palagonite and smectite; (2) surface alteration of glass is characterized by an increase in $\text{K}\text{Rb}$ and $\text{K}\text{Cs}$ ratios, probably best interpreted as sorption of alkalies in ratios approximating those of seawater.The total fluxes involved in alteration of glass in the upper portion of the oceanic crust are estimated from the modal abundance of palagonite in the oceanic crust and the abundance of the vein materials smectite and carbonate. Smectite and carbonates act as a sink for a significant portion of the elements liberated up during alteration of basaltic glass except for Na and Al, which are probably taken up by zeolites and/or albite, possibly hidden in the macroscopic estimate of carbonate. Formation of the observed quantity of secondary phases requires additional sources for Si, Fe. Ca and K. K is provided in excess from the inflowing seawater at reasonable water/rock ratios. The remaining excess Ca, Si and Fe required may be derived by alteration of interstitial glass and breakdown of anorthite rich plagioclase and titano-magnetite, and/or by supply of deeper seated metamorphic reactions.  相似文献