In Titan's atmosphere consisting of N2 and CH4, large amounts of atomic hydrogen are produced by photochemical reactions during the formation of complex organics. This atomic hydrogen may undergo heterogeneous reactions with organic aerosol in the stratosphere and mesosphere of Titan. In order to investigate both the mechanisms and kinetics of the heterogeneous reactions, atomic deuterium is irradiated onto Titan tholin formed from N2 and CH4 gas mixtures at various surface-temperatures of the tholin ranging from 160 to 310 K. The combined analyses of the gas species and the exposed tholin indicate that the interaction mechanisms of atomic deuterium with the tholin are composed of three reactions; (a) abstraction of hydrogen from tholin resulting in gaseous HD formation (HD recombination), (b) addition of D atom into tholin (hydrogenation), and (c) removal of carbon and/or nitrogen (chemical erosion). The reaction probabilities of HD recombination and hydrogenation are obtained as ηabst=1.9(±0.6)×10−3×exp(−300/T) and ηhydro=2.08(±0.64)×exp(−1000/T), respectively. The chemical erosion process is very inefficient under the conditions of temperature range of Titan's stratosphere and mesosphere. Under Titan conditions, the rates of hydrogenation > HD recombination ? chemical erosion. Our measured HD recombination rate is about 10 times (with an uncertainty of a factor of 3-5) the prediction of previous theoretical model. These results imply that organic aerosol can remove atomic hydrogen efficiently from Titan's atmosphere through the heterogeneous reactions and that the presence of aerosol may affect the subsequent organic chemistry. 相似文献
Some instability problems were found on natural or engineered slopes mostly lying on Subang claystones. The instability problems included excessive erosion, slumps and rock falls. The field performance surveys of the problems suggested that the claystones physically weather rapidly so that the rock properties they exhibit during excavation often change to properties with a more characteristic of soil. Such a phenomenon is generally known as a slaking process. In order to gain better understanding about the slaking of Subang claystones, a series of experimental laboratory studies were carried out involving a modified slaking index test. Claystone samples used in this study were obtained from their exposures along the Northern West Java area of Indonesia. Petrographic analysis was correspondingly performed to identify mineral and texture/fabric, and in turn, to determine the inherent factors of the rocks which might affect the slaking process. The stssudy results indicated that the claystones were characterized by high to very high slaking properties having a maximum slaking index (Is) of 57.4% and a mean Is of 43.8%. Major dispersion slaking on sample surfaces and high cracking in response to excessive swelling were recognized as main slaking modes within the claystones. All samples lose progressively less material through the five wet–dry cycles of a slaking index test, indicating a decelerated slaking rate. It was evident that the main inherent factors controlling the slaking process were expandable clay mineral smectite, non-clay mineral pyrite and soluble mineral calcite. Moreover, a quite important of inherent bonding material and stress release energy in the slaking characteristics of the claystones was revealed by a closure phase of an initial hairline crack during unloading. 相似文献
Kolmogorov's model of the distribution of bed thicknesses is assessed by numerical simulations of a sedimentation process, assumed to be a random time-series of alternating depositional and erosional episodes conformable with a stationary Markov process in a state of equilibrium. The study supports the validity of the main point of the model. The random time-series process generates a succession of beds with 'positive' (preserved) and 'negative' (eroded) thicknesses, the frequency distribution of which, f(x), spans the range of positive to negative x -values. The beds with negative thicknesses are absent in the stratigraphic record, whereby the measured bed thicknesses show a frequency distribution, f*( x | x > 0), that is left-side truncated, cut off at the zero thickness value. The numerical simulations further indicate that f( x ) is a 'composite' geometrical distribution, whose actual form changes progressively with p d, the probability of sediment deposition relative to erosion. The distribution f( x ) invariably has a maximum at x ≤0, such that the truncated distribution f*( x ) for p d≥0.5 is a simple geometrical distribution regardless of p d value. The f*( x ) distribution will appear to be a negative exponential distribution when based on the bed-thickness data measured in a conventional metric scale. Data sets from four different turbidite successions in the Cenozoic of Japan, each comprising a few thousand beds, show this type of distribution. However, the sandstone-capping shales in one of the turbidite successions show a truncated Gaussian distribution, attributed to a significant component of non-turbiditic mud. No universal form of bed-thickness distribution can be assumed for the Kolmogorov model. The form of bed-thickness distribution may vary with the type of the depositional process and the character of the sedimentary environment. 相似文献
ABSTRACT There is continued interest in how the rate of relative sea‐level rise [A ( > 0)] and the rate of sediment supply [S] function during the growth and evolution of deltaic shorelines. The theory of shoreline autoretreat, recently corroborated in flume experiments, claims that (1) A( > 0) and S can never be in equilibrium, and (2) shoreline or shelf‐edge progradation inevitably turns to retrogradation, when relative sea level is rising even modestly and even if A/S = const (> 0). Autoretreat arises because the area of the clinoform surface of the delta (or shelf edge) per kilometer of shoreline must increase as the relative sea level rises, and the delta (or shelf edge) progrades into deeper water. A finite sediment supply rate is thus liable to become inadequate to sustain progradation. The problem increases further as a rising sea level also greatly increases the delta‐plain volume that needs to be filled, further limiting the progradation of the system. The fundamental trajectory of shoreline migration is thus one characterized by a concave‐landward shape, even under the steady forcing of the basin. The magnitudes of A (> 0) and S, or A/S do not determine whether the landward turnaround of the shoreline is realized or not, but affect merely the length and height of the fundamental trajectory curve. Thus, any attempt to detect and interpret temporal changes in A and S from the observed stratigraphic record of shoreline trajectory needs first to take full account of the inbuilt autoretreat mechanism. We develop here a simple, semi‐quantitative method of reconstructing the basin conditions (A and S) from the stratigraphic record of prograding deltaic shorelines (or prograding shelf‐margin clinoforms) on the basis of the theory of shoreline autoretreat. The deterministic nature of the autoretreat theory is advantageous in managing this latter issue, because any expected or unexpected change emerges as some discrepancy from a trajectory that was predicted for the initial conditions. The autoretreat theory also provides a convenient graphical method of dealing with the uncertainty of the field data, and with evaluating the accuracy of any reconstruction. Our methodology has been developed to deal with the behaviour of deltaic shorelines, but is basically applicable to any clinoform system, the development of which is affected by relative sea level. The suggested method is applied to an Early Eocene (Ypresian) regressive shoreline succession in the Central Tertiary Basin on Spitsbergen. The studied regressive wedge developed as a delta‐driven, progradational shelf‐margin system under a regime of overall (i.e. long‐term) rise of relative sea level, but also suffered short‐term sea‐level falls associated with valley incisions on the coastal plain and shelf. On the assumption that S was constant or was steadily decreasing, the analysis of field data obtained from three sites within the basin suggests that the initial water depth in the basin was around 0.45 km, and that the overall relative sea‐level rise (c. 0.80 km) happened largely during an early time period and was followed by a longer period of much lower rate of rise. This pattern of relative sea‐level rise is consistent with the Palaeogene tectonic subsidence trend of the basin which was determined independently through a geohistory analysis. The uncertainty of the field data does not negate our reconstruction. The combined effects of autoretreat and A/S changes on a deltaic shoreline trajectory are confirmed through the development of an autoretreat‐based methodology. Conventional sequence stratigraphic models that assume a possible equilibrium condition between A and S are both conceptually misleading and insufficient to analyse basin conditions quantitatively. Sequence stratigraphic analyses of shorelines need to incorporate the autoretreat concept. 相似文献
An unspiked K–Ar dating method using a mass-fractionation correction procedure was applied to a Quaternary independent group
of monogenetic volcanoes, Ojikajima Volcano Group, located in northwestern Kyushu in Southwest Japan, in order to clarify
in detail secular variations in eruptive volume, locations of eruptive vents, and magma compositions in a single monogenetic
volcano group. The major results were as follows: (a) K–Ar ages of monogenetic volcanoes distribute from 1.08 to 0.30 Ma,
with voluminous peaks at approximately 1.0 and 0.6 Ma. (b) The volcanic activity commenced in the central part of the field,
expanded to the whole field at approximately 0.6 Ma, and then shrank to the central area. (3) Concentrations of incompatible
elements, such as Ba, K, and Nb, increase with decreasing age, whereas P, Y, and Zr concentrations remain constant. These
concentrations suggest gradual decrease in the degree of partial melting from an identical mantle source with residual garnet.
Received: 15 December 1997 / Accepted: 23 May 1998 相似文献
A column concentration-high resolution inductively coupled plasma mass spectrometry (ICP-MS) determination was applied to measure the total dissolved concentrations of Fe, Co, Ni, Cu and Zn in seawater collected from the subarctic North Pacific (~45°N) and the Bering Sea in July–September 1997. Total adsorbable Mn was determined on board by column electrolysis preconcentration and chemiluminescence detection. The vertical profiles for Fe, Ni and Zn were nutrient-like. The deep water concentration of Fe was ~0.5 nM in the northeast Pacific (18°-140°W) and increased to ~1 nM in the northwest Pacific (161°E) and ~2 nM in the Bering Sea (57°N, 180°E). The deep water concentrations for Ni and Zn in the Bering Sea were also 1.3–2 times higher than in the North Pacific. The profiles for Co and Cu were examined in the subarctic North Pacific, and results obtained were consistent with previous reports. There was a significant correlation between the concentrations of Co and Mn except for surface mixed layer. The profiles for total adsorbable Mn were similar to the reported profiles for total dissolvable Mn. The deep water concentration of Mn in the Bering Sea was also 4 times higher than in the North Pacific. Iron and zinc were depleted in surface water of the subarctic North Pacific. The relationship between these trace elements and nutrients suggests that these elements could be a limiting factor of phytoplankton productivity. In the Bering Sea, surface water contained ~0.3 nM of Fe. The Zn concentration, which was less than the detection limit in surface water, increased at shallower depths (~30 m) compared with the subarctic North Pacific. These results imply a higher flux of Fe and Zn to surface water in the Bering Sea. This in turn may cause the ecosystem in the Bering Sea characterized by a dominance of diatoms and high regenerated production. 相似文献
The orthorhombic MgSiO3 perovskite has been synthesized with the aid of a double-stage split-sphere-type high-pressure apparatus at about 280 kbar and 1000°C. The unit cell dimensions are: a = 4.7754(3)Å, b = 4.9292(4)Å and c = 6.8969(5)Å with the probable space group Pbnm. Calculated density is 4.108 g cm?3. Crystal structure determination has been carried out by means of both the geometrical simulation (DLS) technique and the ordinary powder X-ray analysis. The results indicate that the MgSiO3 perovskite is closer to the ideal perovskite than ScAlO3 perovskite. 相似文献
High-pressure phase relations in ZnSiO3 and Zn2SiO4 were investigated at about 1000°C and in the pressure range of 100–500 kbar, using a double-staged split-sphere type of high-pressure apparatus.Clinopyroxene-type ZnSiO3 transforms directly into a polymorph with the ilmenite structure at 120 kbar. The hexagonal unit cell dimensions of the ZnSiO3 ilmenite are determined to be under ambient conditions.The following reactions are also recognized at about 1000°C: and: The stabilities of silicate ilmenites, especially the absence of ilmenite of transition metal silicate composition, is discussed. It is pointed out that data on phase relations in zinc silicates may be informative for the consideration on those in magnesium silicates under very high pressures. It is suggested that the silicate ilmenite may be a major constituent in the lower mantle. 相似文献
The problem of response of sliding structures subjected to harmonic support motions is considered. The periodic motions, consisting of the three different modes, stick-stick, stick-slip and slip-slip, are a significant part of the responses to harmonic excitations. Assuming the periodicity of the motion, the condition of the initiation of the slip-slip motion is derived. Then analytical expressions for the occurrence of the periodic motions are obtained without integrating the equations of motion. The accuracy of the analytical expressions is confirmed by comparison with numerical results herein obtained. It is observed that the numerical results are sensitive to the starting and ending times of slip motions. 相似文献
