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81.
The large thickness of Upper Carboniferous strata found in the Netherlands suggests that the area was subject to long-term subsidence. However, the mechanisms responsible for subsidence are not quantified and are poorly known. In the area north of the London Brabant Massif, onshore United Kingdom, subsidence during the Namurian–Westphalian B has been explained by Dinantian rifting, followed by thermal subsidence. In contrast, south and east of the Netherlands, along the southern margin of the Northwest European Carboniferous Basin, flexural subsidence caused the development of a foreland basin. It has been proposed that foreland flexure due to Variscan orogenic loading was also responsible for Late Carboniferous subsidence in the Netherlands. In the first part of this paper, we present a series of modelling results in which the geometry and location of the Variscan foreland basin was calculated on the basis of kinematic reconstructions of the Variscan thrust system. Although several uncertainties exist, it is concluded that most subsidence calculated from well data in the Netherlands cannot be explained by flexural subsidence alone. Therefore, we investigated whether a Dinantian rifting event could adequately explain the observed subsidence by inverse modelling. The results show that if only a Dinantian rifting event is assumed, such as is found in the United Kingdom, a very high palaeowater depth at the end of the Dinantian is required to accommodate the Namurian–Westphalian B sedimentary sequence. To better explain the observed subsidence curves, we propose (1) an additional stretching event during the Namurian and (2) a model incorporating an extra dynamic component, which might well explain the very high wavelength of the observed subsidence compared with the wavelength of the predicted flexural foreland basin.  相似文献   
82.
83.
This paper presents an overview of the modification of clay minerals by propping apart the clay layers with an inorganic complex. This expanded material is converted into a permanent two-dimensional structure, known as pillared clay or shortly PILC, by thermal treatment. The resulting material exhibits a two-dimensional porous structure with acidic properties comparable to that of zeolites. Synthetic as well as natural smectites serve as precursors for the synthesis of Al, Zr, Ti, Fe, Cr, Ga, V, Si and other pillared clays as well as mixed Fe/Al, Ga/Al, Si/Al, Zr/Al and other mixed metal pillared clays. Biofuels form an interesting renewable energy source, where these porous, catalytically active materials can play an important role in the conversion of vegetable oils, such as canola oil, into biodiesel. Transesterification of vegetable oil is currently the method of choice for conversion to biofuel. The second part of this review focuses on the catalysts and cracking reaction conditions used for the production of biofuel. A distinction has been made in three different vegetable oils as starting materials: canola oil, palm oil and sunflower oil.  相似文献   
84.
Laboratory experimental results show that adsorption can be an important mechanism in taking up heavy metals contained in groundwaters in the sandstones. The adsorption can be described in terms of Freundlich isotherms and can be simply modeled mathematically. The adsorption function has been integrated into a mass balance equation, and tested using a laboratory sand tank model and in a small field study. The results show that the transport-adsorption models are not easily applied in the field because of hydrogeological complications.  相似文献   
85.
In central Saudi Arabia, the combination of rock types and sedimentary bedding created a unique scarp landscape. The escarpments were formed during Late Miocene through Early Quaternary times. At present, cuesta formation and migration are restricted to the actual escarpments as a consequence of negligible sediment removal. The plains between the escarpments are sealed through periodically active fluvial processes and through eolian sedimentation. In this publication, the major escarpments of central Saudi Arabia are described. The interactions between tectonics, climate, and morphogenesis which created this unique landscape are reviewed.  相似文献   
86.
Recent acoustic Doppler current profiler (ADCP)-measurements in the Scheldt estuary near Antwerp, Belgium, revealed anomalous, i.e. anti-clockwise circulations in a left bend during the major part of the flood period; these circulations were established shortly after the turn of the tide. During ebb, anti-clockwise circulations persisted, as predicted by classical theory. These data were analysed with a 3D and a 1DV-model. The 3D simulations reveal that the anomalous circulations are found when salinity is included in the computations—without salinity “normal” circulations were found. From analytical and 1DV simulations, it is concluded that a longitudinal salinity gradient ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ may induce a near-bed maximum in flow velocity reversing the direction of the secondary currents. The 1DV-model was then used to assess the contribution of various processes one by one. It was found that because of a reduction in vertical mixing, the vertical velocity profile is not at equilibrium during the first phase of accelerating tide, further enhancing the effects of ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ . A small vertical salinity gradient ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial z}}} \right. \kern-0em} {\partial z}$ appeared to have a very large effect as the crosscurrents of the secondary circulations induced by ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ became an order of larger magnitude. However, at the site under consideration, the effects of transverse salinity gradients, generated by differential advection in the river bend, were dominant: adverse directions of the secondary circulations were found even when the vertical velocity profile became more regular with a more or less logarithmic shape, i.e. when the effects of ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial x}}} \right. \kern-0em} {\partial x}$ and ${\partial S} \mathord{\left/ {\vphantom {{\partial S} {\partial z}}} \right. \kern-0em} {\partial z}$ did not play a dominant role anymore. It is argued that data on the secondary velocity structure, which can be measured easily owing to today’s developments in ADCP equipment, may serve as an indicator for the accuracy at which the salinity field is computed with 3D numerical models. Moreover, the large effect of the salinity structure on the velocity field must have a large impact on the morphological development of estuaries, which should therefore be accounted for in morphological modelling studies.  相似文献   
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