New insights into the high-pressure polymorphism of SiO<Subscript>2</Subscript> cristobalite     

Przemyslaw Dera  John D. Lazarz  Vitali B. Prakapenka  Madison Barkley  Robert T. Downs 《Physics and Chemistry of Minerals》2011,38(7):517-529

Single-crystal X-ray diffraction experiments with SiO₂ α-cristobalite reveal that the well-known reversible displacive phase transition to cristobalite-II, which occurs at approximately 1.8 GPa, can be suppressed by rapid pressure increase, leading to an overpressurized metastable state, persisting to pressure as high as 10 GPa. In another, slow pressure increase experiment, the monoclinic high-pressure phase-II was observed to form at ~1.8 GPa, in agreement with earlier in situ studies, and its crystal structure has been unambiguously determined. Single-crystal data have been used to refine the structure models of both phases over the range of pressure up to the threshold of formation of cristobalite X-I at ~12 GPa, providing important constraints on the feasibility of the two competing silica densification models proposed in the literature, based on quantum mechanical calculations. Preliminary diffraction data obtained for cristobalite X-I reveal a monoclinic unit cell that contradicts the currently assumed model.  相似文献   

Surface complexation modeling for predicting solid phase arsenic concentrations in the sediments of the Mississippi River Valley alluvial aquifer, Arkansas, USA   总被引：1，自引：0，他引：1  

Md. Salah U. Sharif  Ralph K. DavisKenneth F. Steele  Burmshik KimPhillip D. Hays  Tim M. KresseJohn A. Fazio 《Applied Geochemistry》2011,26(4):496-504

The potential health impact of As in drinking water supply systems in the Mississippi River Valley alluvial aquifer in the state of Arkansas, USA is significant. In this context it is important to understand the occurrence, distribution and mobilization of As in the Mississippi River Valley alluvial aquifer. Application of surface complexation models (SCMs) to predict the sorption behavior of As and hydrous Fe oxides (HFO) in the laboratory has increased in the last decade. However, the application of SCMs to predict the sorption of As in natural sediments has not often been reported, and such applications are greatly constrained by the lack of site-specific model parameters. Attempts have been made to use SCMs considering a component additivity (CA) approach which accounts for relative abundances of pure phases in natural sediments, followed by the addition of SCM parameters individually for each phase. Although few reliable and internally consistent sorption databases related to HFO exist, the use of SCMs using laboratory-derived sorption databases to predict the mobility of As in natural sediments has increased. This study is an attempt to evaluate the ability of the SCMs using the geochemical code PHREEQC to predict solid phase As in the sediments of the Mississippi River Valley alluvial aquifer in Arkansas. The SCM option of the double-layer model (DLM) was simulated using ferrihydrite and goethite as sorbents quantified from chemical extractions, calculated surface-site densities, published surface properties, and published laboratory-derived sorption constants for the sorbents. The model results are satisfactory for shallow wells (10.6 m below ground surface), where the redox condition is relatively oxic or mildly suboxic. However, for the deep alluvial aquifer (21-36.6 m below ground surface) where the redox condition is suboxic to anoxic, the model results are unsatisfactory.  相似文献   

热带海气相互作用对大气BSISO年际振荡的影响     

林爱兰  LITim  李春晖  梁建茵  LUOJing-Jia 《海洋学报(英文版)》2011,30(4):62-73

利用卫星观测OLR资料以及海气耦合数值模拟试验结果,从每年波-频分析结果提取了各种传播模态的强度指数序列,分析了热带北半球夏季季节内振荡(BSISO)各种传播模态的年际变化谱特征,探讨了热带各海区海气相互作用对其影响。主要结果如下:赤道外西传波和印度洋北传波以准2 a为显著振荡周期,赤道东传波、南海北传波和西太平洋北传波则都包含准2 a和准5 a两种周期,南海北传波是5种指数中惟一以准5 a为最主要周期振荡的模态。热带印度洋、西太平洋、东太平洋各海区海气相互作用对各指数准2 a振荡、准5 a振荡既有加强作用,也有削弱作用。各海区比较而言,对赤道东传波准2 a和准5 a振荡、南海北传波准2 a和准5 a振荡起最大加强作用的是西太平洋海区海气相互作用;对赤道外西传波准2 a振荡、西太平洋北传波准2 a和准5 a振荡起最大加强作用的是印度洋海区海气相互作用。  相似文献   

A Brine Evolution Model and Mineralogy of Chemical Sediments in a Volcanic Crater,Lake Kitagata,Uganda     

Lichun Ma  Tim K. Lowenstein  James M. Russell 《Aquatic Geochemistry》2011,17(2):129-140

Lake Kitagata, Uganda, is a hypersaline crater lake with Na–SO₄–Cl–HCO₃–CO₃ chemistry, high pH and relatively small amounts of SiO₂. EQL/EVP, a brine evaporation equilibrium model (Risacher and Clement 2001), was used to model the major ion chemistry of the evolving brine and the order and masses of chemically precipitated sediments. Chemical sediments in a 1.6-m-long sediment core from Lake Kitagata occur as primary chemical mud (calcite, magadiite [NaSi₇O₁₃(OH)₃·3H₂O], burkeite [Na₆(CO₃)(SO₄)₂]) and as diagenetic intrasediment growths (mirabilite (Na₂SO₄·10H₂O)). Predicted mineral assemblages formed by evaporative concentration were compared with those observed in salt crusts along the shoreline and in the core from the lake center. Most simulations match closely with observed natural assemblages. The dominant inflow water, groundwater, plays a significant role in driving the chemical evolution of Lake Kitagata water and mineral precipitation sequences. Simulated evaporation of Lake Kitagata waters cannot, however, explain the large masses of magadiite found in cores and the formation of burkeite earlier in the evaporation sequence than predicted. The masses and timing of formation of magadiite and burkeite may be explained by past groundwater inflow with higher alkalinity and SiO₂ concentrations than exist today.  相似文献   

On the utility of identification schemes for digital earth science data: an assessment and recommendations   总被引：1，自引：1，他引：0  

Ruth E. Duerr  Robert R. Downs  Curt Tilmes  Bruce Barkstrom  W. Christopher Lenhardt  Joseph Glassy  Luis E. Bermudez  Peter Slaughter 《Earth Science Informatics》2011,4(3):139-160

In recent years, a number of data identification technologies have been developed which purport to permanently identify digital objects. In this paper, nine technologies and systems for assigning persistent identifiers are assessed for their applicability to Earth science data (ARKs, DOIs, XRIs, Handles, LSIDs, OIDs, PURLs, URIs/URNs/URLs, and UUIDs). The evaluation used four use cases that focused on the suitability of each scheme to provide Unique Identifiers for Earth science data objects, to provide Unique Locators for the objects, to serve as Citable Locators, and to uniquely identify the scientific contents of data objects if the data were reformatted. Of all the identifier schemes assessed, the one that most closely meets all of the requirements for an Unique Identifier is the UUID scheme. Any of the URL/URI/IRI-based identifier schemes assessed could be used for Unique Locators. Since there are currently no strong market leaders to help make the choice among them, the decision must be based on secondary criteria. While most publications now allow the use of URLs in citations, so that all of the URL/URI/IRI based identification schemes discussed in this paper could potentially be used as a Citable Locator, DOIs are the identification scheme currently adopted by most commercial publishers. None of the identifier schemes assessed here even minimally address identification of scientifically identical numerical data sets under reformatting.  相似文献   

Impacts of Drought, Flow Regime, and Fishing on the Fish Assemblage in Southern Australia’s Largest Temperate Estuary   总被引：1，自引：0，他引：1  

Greg J. Ferguson  Tim M. Ward  Qifeng Ye  Michael C. Geddes  Bronwyn M. Gillanders 《Estuaries and Coasts》2013,36(4):737-753

We analysed a 25-year time series of fishery catch and effort data, and age/size information for four large-bodied, native fish species to investigate the hypotheses that under conditions of reduced freshwater inflows and high fishing pressure: (1) the structure of fish assemblages in the lower Murray River system have changed, (2) species diversity of fishes has declined and (3) population age structures of large-bodied, late-maturing, native fish (Macquaria ambigua, Argyrosomus japonicus, Rhombosolea tapirina and Acanthopagrus butcheri) have been reduced. Annual catches and effort in the lower Murray River system were stable for 25 years, but proportional contribution to the total catch from each of freshwater, estuarine and adjacent marine habitats, and the species within them varied. Fish assemblages generally differed between subsequent 5-year periods, with the exception of 1989–1993 when floods occurred in 4 out of 5 years, and the following 5-year period (1994–1998). Species richness declined steeply over 25 years in freshwater and estuarine habitat and species diversity (Hill’s H ₂) also declined after 2001 in estuarine habitat. Species with rapid growth and early maturation (opportunistic strategists), increasingly dominated catches, whilst species with slow growth and late maturation (periodic strategists) declined. Truncated population age structures suggested longevity overfishing of three periodic strategist species: golden perch (M. ambigua), black bream (A. butcheri), mulloway (A. japonicus) and a fourth species with an intermediate strategy, greenback flounder (R. tapirina). This has implications for management because loss of older/larger individuals suggests reduced capacity to withstand or recover from deteriorated environmental conditions associated with a historically extreme drought in the lower Murray River system. Management of these species should seek to preserve the remnant population age structures and then to rebuild age structures by allowing recruits to become established in the adult population. We recommend that assessment of multi-species fisheries in changeable environments, such as occur in estuaries and other end-river environments, requires a suite of indicators that address changes in fish assemblages and populations.  相似文献   

Stock Origins of Subadult and Adult Atlantic Sturgeon, Acipenser oxyrinchus, in a Non-natal Estuary, Long Island Sound     

John R. Waldman  Tim King  Tom Savoy  Lorraine Maceda  Cheryl Grunwald  Isaac Wirgin 《Estuaries and Coasts》2013,36(2):257-267

The anadromous acipenserid Atlantic sturgeon Acipenser oxyrinchus was listed in 2012 under the U.S. Endangered Species Act as having four endangered and one threatened distinct population segment (DPS) in American waters. Anthropogenic activities outside of natal estuaries, particularly bycatch, may hinder the abilities of some populations to rebuild. Most Atlantic sturgeon are residential for their first 2–6 years within their natal estuaries, whereas older subadults and adults may migrate to non-natal estuaries and coastal locations. Previous studies demonstrated that subadults and adults aggregate during summer at locations in Long Island Sound (LIS) and its tributary, the Connecticut River; however, the population origin of these fish is unknown. Because of its geographic proximity and relatively robust population, we hypothesized that the LIS and Connecticut River aggregations were almost solely derived from the Hudson River. We used microsatellite nuclear DNA analysis at 11 loci and mitochondrial DNA control region sequence analyses to estimate the relative contributions of nine Atlantic sturgeon populations and the five DPS to these aggregations using individual-based assignment tests and mixed-stock analysis. From 64 to 73 % of specimens from LIS were estimated to be of Hudson origin. Similarly, 66–76 % of specimens from the Connecticut River were of Hudson origin. However, moderate numbers of specimens were detected from distant spawning populations in the southeastern DPS and from two populations once thought to be extirpated or nearly so, the James River (6–7.3 %), and the Delaware River (7.6–12 %). Additionally, specimens were detected from all five DPS in both the LIS and Connecticut River collections. These results highlight the difficulty of evaluating the status of individual Atlantic sturgeon populations because of the propensity of subadults and adults to migrate for extended duration to distant sites where they may be vulnerable to anthropogenic disturbances.  相似文献   

Institutions for global environmental change     

Andrew Jordan  Tim O&#x;Riordan 《Global Environmental Change》2001,11(4)

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The Caspian Sea: a microcosm for environmental science and international cooperation     

de Mora SJ  Turner T 《Marine pollution bulletin》2004,48(1-2):26-29

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An evaluation of the health status of the Lavaca Bay, Texas ecosystem using Crassostrea virginica as the sentinel species     

Wesley Bissett Jr.  Roger Smith  Robert Field  Tim Phillips  Terry Wade  James A. Thompson 《Marine pollution bulletin》2009,58(2):280-286

Locational risks for compromised ecosystem health for the eastern oysters (Crassostrea virginica) harvested from Lavaca Bay, Texas were estimated. Flow cytometric evaluation of variations in DNA content and the lysosomal destabilization assay were used for evaluation of genotoxicity and stress, respectively. Bayesian geo-statistical methods were utilized to estimate and evaluate spatial effects. For models with spatial risks, continuous surface maps of predicted parameter values were created to evaluate risk location. Lysosomal destabilization assay results were spatially oriented whereas flow cytometry results were fit best with the random effects model. While not spatially oriented, the highest levels of variations in DNA content were also present near industrial facilities. Locational risks of increased biomarkers of genotoxicity and stress in the eastern oyster (Crassostrea virginica) were increased with proximity to industrial facilities  相似文献