Activity–composition relations for phases in petrological calculations: an asymmetric multicomponent formulation     

Tim?HollandEmail author  Roger?Powell 《Contributions to Mineralogy and Petrology》2003,145(4):492-501

For petrological calculations, including geothermobarometry and the calculation of phase diagrams (for example, P–T petrogenetic grids and pseudosections), it is necessary to be able to express the activity–composition (a–x) relations of minerals, melt and fluid in multicomponent systems. Although the symmetric formalism—a macroscopic regular model approach to a–x relations—is an easy-to-formulate, general way of doing this, the energetic relationships are a symmetric function of composition. We allow asymmetric energetics to be accommodated via a simple extension to the symmetric formalism which turns it into a macroscopic van Laar formulation. We term this the asymmetric formalism (ASF). In the symmetric formalism, the a–x relations are specified by an interaction energy for each of the constituent binaries amongst the independent set of end members used to represent the phase. In the asymmetric formalism, there is additionally a "size parameter" for each of the end members in the independent set, with size parameter differences between end members accounting for asymmetry. In the case of fluid mixtures, for example, H₂O–CO₂, the volumes of the end members as a function of pressure and temperature serve as the size parameters, providing an excellent fit to the a–x relations. In the case of minerals and silicate liquid, the size parameters are empirical parameters to be determined along with the interaction energies as part of the calibration of the a–x relations. In this way, we determine the a–x relations for feldspars in the systems KAlSi₃O₈–NaAlSi₃O₈ and KAlSi₃O₈–NaAlSi₃O₈–CaAl₂Si₂O₈, for carbonates in the system CaCO₃–MgCO₃, for melt in the melting relationships involving forsterite, protoenstatite and cristobalite in the system Mg₂SiO₄–SiO₂, as well as for fluids in the system H₂O–CO₂. In each case the a–x relations allow the corresponding, experimentally determined phase diagrams to be reproduced faithfully. The asymmetric formalism provides a powerful and flexible way of handling a–x relations of complex phases in multicomponent systems for petrological calculations.  相似文献   

DEVEX-disdrometer evaluation experiment: Basic results and implications for hydrologic studies   总被引：1，自引：0，他引：1  

Witold F. Krajewski  Anton Kruger  Clelia Caracciolo  Peter Golé  Laurent Barthes  Jean-Dominique Creutin  Jean-Yves Delahaye  Efthymios I. Nikolopoulos  Fred Ogden  Jean-Paul Vinson 《Advances in water resources》2006

Increasing our understanding of the small scale variability of drop size distributions (DSD), and therefore of several bulk characteristics of rainfall processes, has major implications for our interpretation of the remote sensing based estimates of precipitation and its uncertainty. During the spring and summer of 2002 the authors conducted the DEVEX experiment (disdrometer evaluation experiment) to compare measurements of natural rain made with three different types of disdrometers collocated at the Iowa City Municipal Airport in Iowa City, Iowa in the Midwestern United States. This paper focuses on the evaluation of the instruments rather than analysis of the hydrometeorological aspects of the observed events. The comparison demonstrates discrepancies between instruments. The authors discuss the systematic and random effects in terms of rainfall quantities, drop size distribution properties, and the observed drop size vs. velocity relationships. Since the instruments were collocated, the effects of the natural variability of rain are reduced some with time integration, isolating the instrumental differences. The authors discuss the status of DSD measurement technologies and the implications for a range of hydrologic applications from remote sensing of rainfall to atmospheric deposition to soil erosion and sediment transport in the environment. The data set collected during the DEVEX experiment is made available to the research community.  相似文献   

井间断层的计算机分析方法     

周小军  薛林福  戴立明  李三忠 《应用地球物理》2006,3(3):133-140

井间断层分析的研究,是油气储层地质研究的一项重要基础性工作,对油气的运移和聚集其中重要的控制作用。它是利用测井资料,以地层分层为基础,采用计算机技术实现井间断层分析的一种井间断层自动分析方法。动态波形匹配算法是本次研究采用的主要算法,它能够很好地建立井间地层之间的对比关系,通过曲线拟合、特征提取、匹配代价计算等步骤,自动绘制井间地层对比的路径图解。本文在对各种构造的路径图分析的基础上,总结出正断层、逆断层、不整合、同沉积断层、犁式断层和地层尖灭等30种情况下的路径图模式,提出路径图模式及相关概念。在大港油田的实例分析中取得了很好的效果。  相似文献   

青藏高原东部全新世冬夏季风变化的高分辨率泥炭记录   总被引：7，自引：0，他引：7  

于学峰  周卫健  Lars G.Franzen  鲜锋  程鹏  A.J.Tim Jull 《中国科学D辑》2006,36(2):182-187

在建立了全新世泥炭沉积物高分辨率冬夏季风代用指标时间序列的基础上, 发现青藏高原若尔盖地区全新世冬夏季风的变化具有此消彼长和同时消长两种基本的模式, 冬季风与夏季风在不同时间尺度上两种模式又相互嵌套. 由冬夏季风指标叠加效应合成的气候状况却有与全球同步的规律性, 表现出千年-百年尺度的不稳定性, 6.2 ka的季风突然减弱事件要比8.0 ka的事件更显著, 反映了亚洲季风的区域特点或它本身就是全球气候的一个窗口.  相似文献   

The effect of organic materials on the mobility and toxicity of metals in contaminated soils     

René van Herwijnen  Tim Laverye  Jane Poole  Mark E. Hodson  Tony R. Hutchings 《Applied Geochemistry》2007

Organic materials such as compost are often proposed as suitable materials for the remediation of contaminated brownfield sites intended for soft end-use. In addition to vitalising the soil, they are also believed to immobilise metals thereby breaking contaminant-receptor pathways and reducing the ecotoxicity of the contaminants. However, some research has demonstrated contradictory effects between composts on metal immobilisation. In the present study, four different composts and a liming product containing organic matter (LimeX70) were tested to examine both their metal retention and toxicity reduction capabilities on three different metal contaminated soils. Leaching tests, a plant growth test with Greek cress (Lepidium sativum), an earthworm (Eisenia fetida) survival and condition test and a bacterial toxicity test using Vibrio fischeri were carried out. The leaching test results showed that spent mushroom compost caused an increase in metal concentration in the leachates, while LimeX70 caused a decrease. The variation in behaviour between different amendments for each soil was high, so a generic conclusion could not be drawn. Toxicity tests showed significant reduction of metal bioavailability and toxicity for Greek cress, earthworms and bacteria. The results also suggest that more research should be undertaken to understand the mechanisms involved in metal complexation using different types of organic matter, in order to optimise the use of organic materials like compost for soil remediation.  相似文献   

Analysis of the impact of conservation measures on stream flow regime in catchments of the Loess Plateau,China   总被引：3，自引：0，他引：3  

Xingmin Mu  Lu Zhang  Tim R. McVicar  Basang Chille  Peng Gau 《水文研究》2007,21(16):2124-2134

Catchments in the Loess Plateau have been under the influence of human activities for centuries. In the last four decades, soil conservation measures have accelerated and intensified. These measures were designed to reduce soil erosion, improve agricultural productivity, and enhance environmental quality. It is important to evaluate the effects of these measures on hydrology in order to develop sustainable catchment management plans in the region. This study evaluated changes in stream flow data for four selected catchments in the Loess Plateau following large‐scale soil conservation measures. The non‐parametric Mann–Kendall test was used to identify trends in annual stream flow and the results showed significant downward trends in three of the four catchments. The Pettitt test indicated that a change point occurred in 1978 in these three catchments. Annual precipitation in all the catchments showed no significant trend during the period of record. Comparison of daily flow duration curves for two 20‐year periods (1957–1978) and (1979–2003) showed significant changes in stream flow regime. Reduction in most percentile flows varied between 20 and 45%, and the reduction in low flows was greatest. Overall, the reductions in daily flow were increasing with time, with significant changes occurring in the 1990s. However, it is not clear whether these catchments have seen the full effects of the soil conservation measures, so the results of this study might underestimate the final impact of soil conservation on stream flow regime. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

The problem of underpowered rivers     

Fred Worrall  Tim P. Burt  Gregory R. Hancock  Nicholas J.K. Howden  John Wainwright 《地球表面变化过程与地形》2020,45(15):3869-3878

This study has hypothesized that for many rivers the trade-off between flow accumulation and the decrease in slope along channel length means that stream power increases downstream and, moreover, that given the low slope angles in headwater and low-order streams, they would have insufficient stream power to erode let alone transport sediment. The study considered the stream power profile, the particle travel distances and the application of the Hjulström curve based on the velocity profile of nine, large UK catchments. The study showed that:

1. Some rivers never showed a maximum in their longitudinal stream power profile, implying that some rivers never develop a deposition zone before they discharge at the tidal limit.
2. Particle travel distances during a bankfull discharge event showed that for some rivers 91% of the upper main channel would not be cleared of sediment. Furthermore, while some rivers could transport a 2 mm particle their entire length in one bankfull event, for another river it would take 89 such events.
3. The Hjulström curve shows that for three of the study rivers the upper 20 km of the river was not capable of eroding a 2 μm particle.
4. The study has shown that for all rivers studied, erosion is focused downstream and deposition upstream. Many UK rivers have a dead zone where, on time scales of the order of centuries, no erosion or transport occurs and erosion only occurs in the lower courses of the channel where discharge rather than slope dominates – we propose these as underpowered rivers.

© 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

An optimal extraction algorithm for imaging photometry     

Tim Naylor 《Monthly notices of the Royal Astronomical Society》1998,296(2):339-346

This paper is primarily an investigation of whether the 'optimal extraction' techniques used in CCD spectroscopy can be applied to imaging photometry. It is found that using such techniques provides a gain of around 10 per cent in signal-to-noise ratio over normal aperture photometry. Formally, it is shown to be equivalent to profile fitting, but offers advantages of robust error estimation, freedom from bias introduced by mis-estimating the point spread function, and convenience. In addition some other techniques are presented, which can be applied to profile fitting, aperture photometry and the 'optimal' photometry. Code implementing these algorithms is available at http://www.astro.keele.ac.uk/~timn/.  相似文献   

A Discussion of IGS Solutions and Their Impact on Geodetic and Geophysical Applications   总被引：1，自引：0，他引：1  

Jan Kouba  Yves Mireault  Gerhard Beutler  Tim Springer  Gerd Gendt 《GPS Solutions》1998,2(2):3-15

The International Association of Geodesy officially established the International GPS Service (IGS) on Janaury 1, 1994. Its prime objective is to provide support and a rerefence system for a wide variety of scientific and practical applications involving GPS. To fulfill its role the IGS also generates, in addition to its fundamental products (orbital/staion positions and consistent Earth orientation parameters), additional reference-system products providing the necessary infrastructure, standards, and means of calibrations for timing and various atmospheric applications of GPS. The generation and efficient application of IGS products and their impact on a number of positioning and atmospheric applications, including low earth orbit satellites, is reviewed and discussed. @ 1998 John Wiley & Sons, Inc.  相似文献   

U-Series Chronology of Lacustrine Deposits in Death Valley, California   总被引：1，自引：0，他引：1  

Teh-Lung Ku  Shangde Luo  Tim K. Lowenstein  Jianren Li  Ronald J. Spencer 《Quaternary Research》1998,50(3):261-275

Uranium-series dating on a 186-m core (DV93-1) drilled from Badwater Basin in Death Valley, California, and on calcareous tufas from nearby strandlines shows that Lake Manly, the lake that periodically flooded Death Valley during the late Pleistocene, experienced large fluctuations in depth and chemistry over the last 200,000 yr. Death Valley has been occupied by a long-standing deep lake, perennial shallow saline lakes, and a desiccated salt pan similar to the modern valley floor. The average sedimentation rate of about 1 mm/yr for core DV93-1 was punctuated by episodes of more-rapid accumulation of halite. Arid conditions similar to the modern conditions prevailed during the entire Holocene and between 120,000 and 60,000 yr B.P. From 35,000 yr B.P. to the beginning of the Holocene, a perennial saline lake existed, over 70 m at its deepest. A much deeper and longer lasting perennial Lake Manly existed from about 185,000 to 128,000 yr B.P., with water depths reaching about 175 m, if not 330 m. This lake had two significant “dry” excursions of 10²–10³yr duration about 166,000 and 146,000 yr B.P., and it began to shrink to the point of halite precipitation between 128,000 and 120,000 yr B.P. The two perennial lake periods correspond to marine oxygen isotopic stages (OIS) 2 and 6. Based on the shoreline tufa ages, we do not rule out the possible existence 200,000 yr ago of yet a third perennial lake comparable in size to the OIS 6 lake. The²³⁴U/²³⁸U data suggest that U in tufa owes its origin mainly to Ca-rich springs fed by groundwater that emanated along lake shorelines in southern Death Valley, and that an increase of this spring-water input relative to the river-water input apparently occurred during OIS 6.  相似文献