Factors affecting dissolved organic matter dynamics in mixed-redox to anoxic coastal sediments   总被引：1，自引：0，他引：1  

Tomoko Komada  Clare E. Reimers  David J. Burdige 《Geochimica et cosmochimica acta》2004,68(20):4099-4111

Mixed-redox (suboxic, or oscillating between oxidizing and reducing conditions) to anoxic marine sediments from the Raritan -New York Bay complex and the Inner New York Bight of the eastern U.S. were studied to investigate the factors controlling the accumulation of pore-water dissolved organic carbon (DOC). DOC increased with depth at each of four study sites, but accumulation was generally limited in the mixed-redox zone relative to the anoxic zone. Humic-like fluorescence intensity also differed between mixed-redox and anoxic zones of the sediment, such that anoxic pore waters were relatively enriched in fluorescent, humic-like compounds.A pore-water DOC model was tested for its capacity to explain these geochemical patterns. Model results for a heavily irrigated and a non-bioturbated site both suggest that, excluding the uppermost few cm of the sediment column, pore-water DOC is predominantly comprised of poorly-reactive material with estimated degradation rate constants on the order of 10⁻³ yr⁻¹. Model results are also consistent with the suggestion that DOC accumulation is suppressed in the mixed-redox compared to the anoxic zones of the sediment due to rapid oxidation of high-molecular-weight DOC, and limited production and enhanced oxidation of the less reactive polymeric low-molecular-weight component of the DOC pool. An assessment of sorptive behavior of DOC in the surface sediments of the study area suggests that sorption can influence pore-water DOC distributions under conditions of high sedimentation and low bioirrigation.  相似文献   

The crystal structure of CaFe3+SiAlO6 and the crystal chemistry of Fe3+—Al3+ substitution in calcium Tschermak's pyroxene     

Subrata Ghose  Fujio P. Okamura  Haruo Ohashi 《Contributions to Mineralogy and Petrology》1986,92(4):530-535

The crystal structure of a synthetic CaFe³⁺Al-SiO₆ pyroxene (20 kb, 1,375° C) with unit cell dimensions a=9.7797(16), b=8.7819(14), c=5.3685(5) Å, =105.78(1), space group C2/c has been refined by the method of least squares to an R-factor of 0.025 based on 812 reflections measured on an automatic single crystal diffractometer. The octahedral M1 site is occupied by 0.82 Fe³⁺ and 0.18 Al³⁺. Within the tetrahedral T site, Si⁴⁺ (0.50), Al³⁺ (0.41) and Fe³⁺ (0.09) ions are completely disordered, although submicroscopic domains with short-range order are very likely. The octahedral site preference energy of the Fe³⁺ ions with respect to Al³⁺ ions in CaFe³⁺AlSiO₆ is about 10 kcal/mole, which is much higher than that found in Y₃Al _x Fe_5–2O₁₂ garnets. Topologically the structure of CaFe³⁺AlSiO₆ is intermediate between that of diopside and calcium Tschermak's pyroxene, CaAlAlSiO₆. For CaM³⁺ AlSiO₆ clinopyroxenes an increase in the size of the M1 octahedron is accompanied by an increase in the average M2-0, bridging T-0 and 03-03 distances and kinking of the tetrahedral chain.  相似文献   

Correlation between dissolved He concentration and Cl in groundwater at Äspö, Sweden     

Yasunori Mahara  Takuma Hasegawa  Kimio Miyakawa  Tomoko Ohta 《Applied Geochemistry》2008,23(12):3305-3320

Tunnel excavation at Äspö Island, Sweden, has caused severe groundwater disturbance, gradually extending deeper into the tunnel as present-day Baltic seawater intrudes through fractures connecting to the surface. However, the paleo-hydrogeochemical conditions have remained in the deep highly saline waters that have avoided mixing. A correlation has been observed between dissolved ⁴He concentration and Cl⁻ ion concentration, measured every two years from 1995 to 2001 at Äspö. Groundwater mixing conditions can be examined by the correlations between 1/Cl, ³⁶Cl/Cl, and ³H concentrations. Subsurface production is responsible for the majority of the ³⁶Cl and excess dissolved ⁴He of interstitial groundwater in fractures. The secular equilibrium ratio of ³⁶Cl/Cl in rock was theoretically estimated to be (5.05 ± 0.82) × 10⁻¹⁴ based on the neutron flux intensity, a value comparable to the measured ³⁶Cl/Cl ratio in rock and groundwater. The degassing crustal ⁴He flux was estimated to be 2.9 × 10⁻⁸  1.3 × 10⁻⁶ (ccSTP/cm²a) using the HTO diffusion coefficient for the Äspö diorite. The ⁴He accumulation rate ranges from 6.8 × 10⁻¹⁰ (for the in situ accumulation rate) to 7.0 × 10⁻⁹ (ccSTP/(g_water · a) considering both ⁴He in situ production and the degassing flux, assuming ⁴He is accumulated constantly in groundwater. By comparing the subsurface ³⁶Cl increase with ⁴He concentrations in groundwater, the ⁴He accumulation rate was determined from data for groundwater arriving at the secular equilibrium of ³⁶Cl/Cl. The ⁴He accumulation rate was found to be (1.83 ± 0.72) × 10⁻⁸ ccSTP/(g_water · a) without determining the magnitude of degassing ⁴He flux.  相似文献   

Active tectonics around the junction of Southwest Japan and Ryukyu arcs: Control by subducting plate geometry and pre‐Quaternary geologic structure          下载免费PDF全文

Yukinobu Okamura 《Island Arc》2016,25(4):287-297

The origin of active faults in the Inner zone of the western part of Southwest Japan was explained by a decrease of the minimum principal stress and reactivation of ancient geologic structures. Although the E–W maximum principal stress in Southwest Japan due to the collision of the Southwest and Northeast Japan arcs along the Itoigawa–Shizuoka Tectonic Line is assumed to decrease westward, the density of active strike‐slip faults increases in the western margin of the Southwest Japan Arc (western Chugoku and northern Kyushu) where the subducting Philippine Sea Plate dips steeply. The E–W maximum compressional stress is predominant throughout Southwest Japan, while the N–S minimum principal stress that is presumably caused by coupling between Southwest Japan arc and Philippine Sea Plate decreases due to the weak plate coupling as the plate inclination increases under the western margin of Southwest Japan. The increase of the fault density in the western margin of the arc is attributed to a decrease of the minimum principal stress and consequent increase of shear stress. Low slip rates of the active faults in this region support the view that the westward increase of fault density is not a response to increasing maximum stress. These faults of onshore and offshore lie in three distinct domains defined on the basis of fault strike. They are defined domains I, II, and III which are composed of active faults striking ENE–WSW, NW–SE, and NE–SW, respectively. Faulting in domains I, II, and III is related to Miocene rift basins, Eocene normal faults, and Mesozoic strike‐slip faults, respectively. Although these active faults are strike‐slip faults due to E–W maximum stress, it is unclear whether their fault planes are the same as those of pre‐Quaternary dip‐slip faults.  相似文献   

Impacts of the Nakhodka heavy-oil spill on an intertidal ecosystem: an approach to impact evaluation using geographical information system     

Teruhisa K  Masahiro N  Hiroshi K  Tomoko Y  Kouichi O;Marine Life Research Group of Takeno 《Marine pollution bulletin》2003,47(1-6):99-104

A major heavy-oil spill from the Russian tanker Nakhodka occurred in the Sea of Japan on 2 January 1997. We investigated the impacts of this spill on a rocky intertidal ecosystem along the southern coast of the Sea of Japan. We selected Imago-Ura Cove as our study site to observe temporal changes along the oiled shore, because minimal cleaning effort was made in this area. Field surveys were conducted every autumn and spring from 1997 to 2000. We measured coverage by macroalgae in 1 x 1-m(2) quadrats and counted the animals in 5 x 5-m(2) quadrats along the intertidal zone. Changes in the ecosystem caused by the oil spill were analyzed by applying a geographical information system (GIS) to the Sea of Japan for the first time. The GIS showed that following the accident there were heavily oiled areas in sheltered regions, but these decreased over the three years. It also showed that coverage by macroalgae and the number of animals increased, although some species of algae with microscopic sporophyte generations, and some populations of perennial shellfish, remained stable or decreased during the study period. GIS was able to trace temporal changes in intertidal communities resulting from the impacts of heavy oil on flora and fauna at a spatial scale of 10-100 m. GIS is thus a practical tool for visualizing, analyzing, and monitoring changes in an ecosystem polluted by oil, taking into account topographic differences along the coastline.  相似文献   

Observation of Tidal Tilt On Kilauea Volcano, Hawaii     

P. M. Davis  P. A. Rydelek  D. L. Agnew  A. T. Okamura 《Geophysical Journal International》1987,90(1):233-244

Summary. We have analysed the east-west tilt components, O₁, K₁, N₂, M₂ and S₂ from a continuously recording tiltmeter located in Uwekahuna Vault on Kilauea Volcano, Hawaii, for the period 1971—79. Detailed analysis of the M₂ component gives values of 30.9 ± 2.0 (95 per cent) nrad and 116.0 ± 2.0° for the amplitude and phase, respectively, compared to values of 48.5 nrad and 139.4° for the equilibrium tide. the total theoretical tide, found by summing the equilibrium and load tides, amounts to 37.2 nrad at a phase of 121.7°. the 20 per cent discrepancy with that observed may be due to an inaccurate cotical chart, cavity effects in the vault, strain—tilt coupling or an inappropriate solid earth model. In the vicinity of Hawaii (≤ 3°) two independent cotidal charts give almost identical results for the near field ocean load. At greater distances, we use the Schwiderski (1978) cotidal chart. We estimate that local cavity and strain—tilt coupling effects are less than 12 per cent owing to the agreement between geodetically determined and instrumental tilt but we can not rule out regional effects. Assuming these are small and the cotical charts correct, we find that the M₂ results are brought into satisfactory agreement if, instead of using an average oceanic earth model in the (< 75 km) vicinity of Hawaii, we use an earth model with nearly one-half the oceanic rigidity. Such a low upper mantle and crustal rigidity is consistent with Kilauea's position above the thermal upwelling associated with the Hawaiian hotspot.  相似文献   

Prospects for Strongly Lensed Supernovae Behind Hubble Frontier Fields Galaxy Clusters with the James Webb Space Telescope     

T. Petrushevska  T. Okamura  R. Kawamata  L. Hangard  G. Mahler  A. Goobar 《Astronomy Reports》2018,62(12):917-925

Measuring time delays from strongly lensed supernovae (SNe) is emerging as a novel and independent tool for estimating the Hubble constant (H₀). This is very important given the recent discord in the value of H₀) from two methods that probe different distance ranges. The success of this technique will rely of our ability to discover strongly lensed SNe with measurable time delays. Here, we present the magnifications and the time delays for the multiply-imaged galaxies behind the Hubble Frontier Fields (HFF) galaxy clusters, by using recently published lensing models. Continuing on our previous work done for Abell 1689 (A1689) and Abell 370, we also show the prospects of observing strongly lensed SNe behind the HFF clusters with the upcoming James Webb Space Telescope (JWST). With four 1-hour visits in one year, the summed expectations of all six HFF clusters are ~0.5 core-collapse (CC) SNe and 0.06 Type Ia SNe (SNe Ia) in F115W band, while with F150W the expectations are higher, ~0.9 CC SNe and ~0.06 SNe Ia. These estimates match those expected by only surveying A1689, proving that the performance of A1689 as gravitational telescope is superior. In the five HFF clusters presented here, we find that F150W will be able to detect SNe Ia (SNe IIP) exploding in 93 (80) pairsmultiply-imaged galaxies with time delays of less than 5 years.  相似文献   

Comparison of stable isotopes,ratios of Cl/Cl and I/I in brine and deep groundwater from the Pacific coastal region and the eastern margin of the Japan Sea     

Yasunori Mahara  Tomoko Ohta  Tomochika Tokunaga  Hiroyuki Matsuzaki  Eiji Nakata  Yuki Miyamoto  Yukihiro Mizuochi  Toshiharu Tashiro  Masahiro Ono  Toshifumi Igarashi  Keisuke Nagao 《Applied Geochemistry》2012

Fifty-three samples, including brines associated with oil and natural gas reservoirs and groundwater samples from deep boreholes, were collected from the Pacific and Japan Sea coastal regions in Japan. The ¹²⁹I/¹²⁷I and ³⁶Cl/Cl ratios, and stable isotopes (δD and δ¹⁸O) are compared to investigate differences related to the geotectonic settings of the two regions. The δD and δ¹⁸O data indicate that brine and groundwater from the Pacific coastal region reflect mixing of meteoric water with connate seawater in the pores of sedimentary rocks. On the other hand, brine and groundwater from the Japan Sea coastal region have been hydrothermally altered. In particular, brines associated with petroleum accumulations at Niigata and Akita showed the same isotopic characteristics as fluids found in the Kuroko deposits of the Green Tuff region in northeastern Japan. There is little difference in the ³⁶Cl/Cl ratios in brine and groundwater from the Pacific and Japan Sea coasts. Most brine and some deep groundwater, except those from the Pleistocene Kazusa Group, have already reached the average secular equilibrium ratio of 9.9 ± 2.7 × 10⁻¹⁵ for their mudstone and sandstone reservoirs. There was no correlation between the ³⁶Cl/Cl ratios and differences in geotectonic setting between the Pacific and the Japan Sea coast. The molar I/Br ratio suggests that the I in all of water samples was of biogenic origin. The average ¹²⁹I/¹²⁷I ratio was 290 ± 130 × 10⁻¹⁵ to 294 ± 105 × 10⁻¹⁵ in both regions, showing no relationship to the different geotectonic settings. The uncontaminated brine and groundwater samples are likely to have retained the original ¹²⁹I/¹²⁷I ratios of marine I released from the old organic matter stored in sedimentary rock.  相似文献   

Ceramic waste glass fiber-reinforced plastic-containing filtering materials for turbid water treatment     

Kentaro Yasui  Shogo Goto  Hiroyuki Kinoshita  Shuta Kamiunten  Toshifumi Yuji  Yoshimi Okamura  Narong Mungkung  Mitsuhiro Sezaki 《Environmental Earth Sciences》2016,75(15):1135

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Antarctic lunar meteorites Yamato-793169, Asuka-881757, MIL 05035, and MET 01210 (YAMM): Launch pairing and possible cryptomare origin   总被引：1，自引：0，他引：1  

Tomoko Arai  B. Ray Hawke  Keiji Misawa  Masamichi Miyamoto 《Geochimica et cosmochimica acta》2010,74(7):2231-3852

The Antarctic lunar meteorite Meteorite Hills (MET) 01210 is a polymict regolith breccia, dominantly composed of mare basalt components. One relatively large (2.7 × 4.7 mm) basalt clast in MET 01210 (MET basalt) shows remarkable mineralogical similarities to the lunar-meteorite crystalline mare basalts Yamato (Y)-793169, Asuka (A)-881757, and Miller Range (MIL) 05035. All four basalts have similar rock texture, mineral assemblage, mineral composition, pyroxene crystallization trend, and pyroxene exsolution lamellae. The estimated TiO₂ contents (∼2.0 wt%) of the MET basalt and MIL 05035 are close to the bulk-rock TiO₂ contents of Y-793169 and A-881757. These similarities suggest that Y-793169, A-881757, MIL 05035, and the MET basalt came from the same basalt flow, which we designate the YAMM basalt. The source-basalt pairing of the YAMM is also supported by their similar REE abundances, crystallization ages (approx. 3.8-3.9 Ga), and isotopic compositions (low U/Pb, low Rb/Sr, and high Sm/Nd). The pyroxene exsolution lamellae, which are unusually coarse (up to a few microns) by mare standards, imply a relatively slow cooling in an unusually thick lava and/or subsequent annealing within a cryptomare. Reported noble gas and CRE data with close launch ages (∼1 Ma) and ejection depths (deeper than several meters) among the four meteorites further indicate their simultaneous ejection from the moon. Despite the marginally close terrestrial ages, pairing in the conventional Earth-entry sense seems unlikely because of the remote recovery sites among the YAMM meteorites.The high abundance (68%) of mare components in MET 01210 estimated from a two-component mixing model calculation could have resulted from either lateral mixing at a mare-highland boundary or vertical mixing in a cryptomare. The proportion of mare materials in MET 01210 is greater than in Apollo core samples at the mare-highland boundary. The burial depth (>several meters deep) inferred from the lack of surface irradiation of MET 01210 exceeds the typical mare regolith thickness (a few meters). Thus, the source of the YAMM meteorites is likely a terrain of locally high mare-highland mixing within a cryptomare. We searched for a possible source crater of the YAMM meteorites within the well-defined cryptomare, based on the multiple constraints obtained from this study and published data. An unnamed 1.4 km-diameter crater (53°W, 44.5°S) on the floor of the Schickard crater is the most suitable source for the YAMM meteorites.The ²³⁸U/²⁰⁴Pb (μ) value of the YAMM basalts is extremely low, relative to those of the Apollo mare basalts, but comparable to those of the Luna 24 very low-Ti basalts. The low-μ source indicates a derivation from a less differentiated mantle with a lack of KREEP components. Although the chemical sources of materials and heat source of melting might be independent, the heat source that generated the source magma of the YAMM and Luna 24 basalts may not be related to KREEP, unlike the case of the Apollo basalts. The distinct chemical and isotopic compositions of mantle sources between the Apollo basalts and the YAMM/Lunar 24 basalts imply differences in mantle composition and thermal evolution between the Procellarum KREEP Terrane (PKT) and non-PKT regions of the nearside.  相似文献