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Telli-Karakoç F Ruddock PJ Bird DJ Hewer A Van Schanke A Phillips DH Peters LD 《Marine environmental research》2002,54(3-5):511-515
Juvenile turbot (Scophthalmus maximus) were injected intraperitoneally with either corn oil or 5 mg/kg benzo[a]pyrene (BaP) dissolved in corn oil and sampled I and 3 days after injection. After 1 day, no elevation of 7-ethoxyresorufin O-deethylase (EROD) activity was observed, however bile metabolites (BaP-7,8 dihydrodiol representing 70% of the total metabolites) and a single hepatic DNA adduct spot (0.47 adducts/10(8) nucleotides) identified by 32P-postlabelling were formed. No BaP metabolites or DNA adducts were observed in either control or carrier control fish. Fish sampled after 3 days reported 5-fold higher (P < 0.05) levels of EROD activity, a shift in the bile metabolite profile towards BaP phenol formation (1OH and 30H BaP comprising up to 60% of total metabolites detected) and the formation of two adduct spots (0.86 and 0.71 adducts/10(8) nucleotides). These results show that BaP can be metabolised and form hydrophobic DNA adducts in turbot without EROD elevation. Following EROD elevation, a shift in the profile of both BaP metabolites and BaP metabolite-DNA interactions occurs indicative of other oxidative processes. 相似文献
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In this paper, we formulate a finite-element procedure for approximating the coupled fluid and mechanics in Biot’s consolidation
model of poroelasticity. We approximate the flow variables by a mixed finite-element space and the displacement by a family
of discontinuous Galerkin methods. Theoretical convergence error estimates are derived and, in particular, are shown to be
independent of the constrained specific storage coefficient, c
o
. This suggests that our proposed algorithm is a potentially effective way to combat locking, or the nonphysical pressure
oscillations, which sometimes arise in numerical algorithms for poroelasticity. 相似文献
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The stable isotopic composition (13C and 18O) and elemental (Sr and Mg) of marine molluscs are presented for Carditacea and Solenacea shells collected off the Mediterranean coast of Egypt. Based on shell microstructures and mineralogy, the bivalve shells are preserved in their original mineralogy and chemistry.The Sr and Mg concentrations of the bivalve shells have mean values of 1960 ppm and 226 ppm respectively. The stable isotopic composition generally show high values of 18O and 13C. The 18O values range from +0.1 to –1.8 PDB and most shells are highly enriched in13C; averaging +2.5 PDB. These elemental and isotopic signatures are analogous to modern marine bivalves from other localities.The oxygen and carbon isotopes, together with the calculated temperatures, suggest that the aragonitic bivalve shells were precipitated in isotopic equilibrium from warm marine waters. 相似文献
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The argon isotope systematics of vein-quartz samples with two different K-reservoirs have been evaluated in detail. Potassium is hosted by ultra-high-salinity fluid inclusions in quartz samples from the Eloise and Osborne iron-oxide-copper-gold (IOCG) deposits of the Mt Isa Inlier, Australia. In contrast, K is hosted by accidentally trapped mica within lower-salinity fluid inclusions of a sample selected from the Railway Fault, 13 km south of the Mt Isa copper mine, Australia. Imprecise apparent ages have been obtained for all of the samples studied and conclusively demonstrate that quartz fluid inclusions are retentive to Ar and have not leaked over billions of years. IOCG samples that host K in fluid inclusions only, have K/Cl values of <1 and the ages obtained represent the maximum ages for mineralization. In contrast, the Railway Fault samples that include accidentally trapped mica have K/Cl values of ?1. Excess 40ArE plus Cl hosted by fluid inclusions, and radiogenic 40ArR plus K, are strongly correlated in these samples and define a plane in 3D 40Ar-36Ar-K-Cl space. In this case, the plane yields an ‘excess 40ArE’ corrected age of ∼1030 Ma that is 100’s of Ma younger than nearby Cu-mineralization at Mt Isa. The age is interpreted to reflect 40Ar-loss from the accidentally trapped mica into the surrounding fluid inclusions, and is not related to the samples’ age of formation. The initial 40Ar/36Ar value of fluid inclusions is widely used to provide information on fluid origin. For the IOCG samples that host K in fluid inclusions only, the initial 40Ar/36Ar values are close to the measured values at every temperature of stepped heating experiments. For samples that include accidentally trapped mica, the correction for post-entrapment radiogenic 40ArR production is significant. Furthermore, because 39ArK present in accidentally trapped mica crystals is released at different temperatures to radiogenic 40ArR lost to the surrounding fluid inclusions, intra-sample 40Ar/36Ar variation cannot be reliably documented. The results demonstrate that noble gas analysis is readily applicable to Proterozoic, or older, samples but that if K-mineral impurities are present within quartz the abundance of K must be determined before calculation of mean 40Ar/36Ar values that are representative of the samples’ initial composition. 相似文献
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Tectonics and distribution of gold deposits in China – an overview 总被引:20,自引:0,他引:20
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Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: Six Case Studies 总被引:2,自引:0,他引:2
W.S Phillips J.T. Rutledge L.S. House M.C. Fehler 《Pure and Applied Geophysics》2002,159(1-3):345-369
—?The injection or production of fluids can induce microseismic events in hydrocarbon and geothermal reservoirs. By deploying sensors downhole, data sets have been collected that consist of a few hundred to well over 10,000 induced events. We find that most induced events cluster into well-defined geometrical patterns. In many cases, we must apply high-precision, relative location techniques to observe these patterns. At three sedimentary sites, thin horizontal strands of activity are commonly found within the location patterns. We believe this reflects fracture containment between stratigraphic layers of differing mechanical properties or states of stress. At a massive carbonate and two crystalline sites, combinations of linear and planar features indicate networks of intersecting fractures and allow us to infer positions of aseismic fractures through their influence on the location patterns. In addition, the fine-scale seismicity patterns often evolve systematically with time. At sedimentary sites, migration of seismicity toward the injection point has been observed and may result from slip-induced stress along fractures that initially have little resolved shear. In such cases, triggering events may be critical to generate high levels of seismic activity. At one crystalline site, the early occurrence of linear features that traverse planes of activity indicate permeable zones and possible flow paths within fractures. We hope the continued development of microseismic techniques and refinement of conceptual models will further increase our understanding of fluid behavior and lead to improved resource management in fractured reservoirs. 相似文献