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31.
The detection, surveying, and analysis of ancient settlement structures using remote sensing techniques offer a unique opportunity to quickly map the locations of archaeological objects in a relatively short time. High‐resolution images contribute information to the documentation and spatial relation of these objects, especially if Geographic Information Systems (GIS) and Web‐based applications are used. The aim of this study was to assess the potential use of satellite data and aerial imagesacquired by a remote‐controlled balloon to generate geospatial data with a range of resolutions and information depths. The study area was Doliche, in the landscape of ancient Commagene (Turkey), where conventional flight campaigns are impossible or strongly restricted. Recently generated data sets (i.e., topographic maps, ortho‐images, terrain models) were combined with field observations to derive ancient and modern landscape patterns and their possible relation to an assumed “ancient procession road” between the village Doliche (Dülük) and the nearby sanctuary of theRoman divinity Iupiter Dolichenus. © 2010 Wiley Periodicals, Inc.  相似文献   
32.
Eckfeld Maar: Window into an Eocene Terrestrial Habitat in Central Europe   总被引:1,自引:1,他引:0  
<正>To mark the occasion of the 175th anniversary of the Rheinische Naturforschende Gesellschaft in 2009 and of the centennial of the Mainz Natural History Museum in 2010,we present a short account of our present knowledge of the Eckfeld Maar after 20 years of continuous research.This paper does not attempt to include all of the detailed results on the geology of the Eckfeld site or its biota.To date,nearly 250 papers and books have been published since the start of our project.An up-to-date list of these publications can be found at www.eckfeldermaar. de.  相似文献   
33.
We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ11 B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ11 B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.  相似文献   
34.
The intra- and epicontinental basins in north-east Africa (Egypt, Sudan) bear ample evidence of weathering processes repeatedly having contributed to the formation of mineral deposits throughout the Phanerozoic.The relict primary weathering mantle of Pan-African basement rocks consists of kaolinitic saprolite, laterite (in places bauxitic) and iron oxide crust. On the continent, the reaccumulation of eroded weathering-derived clay minerals (mainly kaolinite) occurred predominantly in fluvio-lacustrine environments, and floodplain and coastal plain deposits. Iron oxides, delivered from ferricretes, accumulated as oolitic ironstones in continental and marine sediments. Elements leached from weathering profiles accumulated in continental basins forming silcrete and alunite or in the marine environment contributing to the formation of attapulgite/saprolite and phosphorites.The Early Paleozoic Tawiga bauxitic laterite of northern Sudan gives a unique testimony of high latitude lateritic weathering under global greenhouse conditions. It formed in close spatial and temporal vicinity to the Late Ordovician glaciation in north Africa. The record of weathering products is essentially complete for the Late Cretaceous/Early Tertiary. From the continental sources in the south to the marine sinks in the north, an almost complete line of lateritic and laterite-derived deposits of bauxitic kaolin, kaolin, iron oxides and phosphates is well documented.  相似文献   
35.
Further investigation of the three-parameter lumped mass model for the prediction of natural frequencies and transient response of Bernoulli-Euler clamped-clamped beams has resulted in a revised model, which is slightly superior to the original model, as it is applicable over a wider frequency range.  相似文献   
36.
The gold mineralization of the Hutti Mine is hosted by nine parallel, N–S trending, steeply dipping, 2–10 m wide shear zones, that transect Archaean amphibolites. The shear zones were formed after peak metamorphism during retrograde ductile D2 shearing in the lower amphibolite facies. They were reactivated in the lower to mid greenschist facies by brittle–ductile D3 shearing and intense quartz veining. The development of a S2–S3 crenulation cleavage facilitates the discrimination between the two deformation events and contemporaneous alteration and gold mineralization. Ductile D2 shearing is associated with a pervasively developed distal chlorite–sericite alteration assemblage in the outer parts of the shear zones and the proximal biotite–plagioclase alteration in the center of the shear zones. D3 is characterized by development of the inner chlorite-K-feldspar alteration, which forms a centimeter-scale alteration halo surrounding the laminated quartz veins and replaces earlier biotite along S3. The average size of the laminated vein systems is 30–50 m along strike as well as down-dip and 2–6 m in width.Mass balance calculations suggest strong metasomatic changes for the proximal biotite–plagioclase alteration yielding mass and volume increase of ca. 16% and 12%, respectively. The calculated mass and volume changes of the distal chlorite–sericite alteration (ca. 11%, ca. 8%) are lower. The decrease in δ18O values of the whole rock from around 7.5‰ for the host rocks to 6–7‰ for the distal chlorite–sericite and the proximal biotite–plagioclase alteration and around 5‰ for the inner chlorite-K-feldspar alteration suggests hydrothermal alteration during two-stage deformation and fluid flow.The ductile D2 deformation in the lower amphibolite facies has provided grain scale porosities by microfracturing. The pervasive, steady-state fluid flow resulted in a disseminated style of gold–sulfide mineralization and a penetrative alteration of the host rocks. Alternating ductile and brittle D3 deformation during lower to mid greenschist facies conditions followed the fault-valve process. Ductile creep in the shear zones resulted in a low permeability environment leading to fluid pressure build-up. Strongly episodic fluid advection and mass transfer was controlled by repeated seismic fracturing during the formation of laminated quartz(-gold) veins. The limitation of quartz veins to the extent of earlier shear zones indicate the importance of pre-existing anisotropies for fault-valve action and economic gold mineralization.  相似文献   
37.
By performing buoyancy-driven fracture experiments in brittle gelatin we observe that the ascent velocity of a fracture containing a finite volume of fluid increases when approaching the free surface. We theoretically describe this free-surface effect and quantify it by introducing an effective depth-dependent fracture toughness and developing an ascent model on the basis of linear fracture mechanics. We develop a successful inversion approach and resolve the actual and critical fracture length and the ascent velocity far away from the free surface from the observation of the fracture tip migration alone. Other parameters, as the fluid volume included in the fracture and the in situ fracture toughness, can be derived. Applying the model and inversion to the 1998 eruption at Piton de la Fournaise, Reunion Island, reveals estimates of the length and critical length of the feeding magma batch, the magma batch volume and the in situ fracture toughness. It further indicates that the ascent velocity of the magma batch was probably much smaller at greater depths and that the batch might have been initiated several months or years before the eruption.  相似文献   
38.
Ambient mixing ratios of NO, NO2, and O3 were determined together with the photolysis frequency of NO2, JNO2, at a rural, agricultural site in Germany. The data were collected during the POPCORN-campaign from August 1 to August 24, 1994, in a maize field 6 m above ground. The medians of the NO, NO2, and O3 mixing ratios between 10:00 and 14:00 UT were 0.25, 1.09, and 45 ppbv, respectively. The corresponding median of JNO2 was 6.0 · 10–3 s–1. NOx = NO + NO2 showed a strong diurnal variation with maximum mixing ratios at night, suggestive of a strong local surface source of NO, probably by microbial activity in the soil. The estimated average emission rate was 40 ng(N) m–2 s–1 of NOx, the major part of it probably in the form of NO. The available measurements allowed the estimation of the local NOx budget. At night the budget is almost closed and the measured NOx mixing ratios can be explained by the local source, local dry deposition of NO2, formation of NO3 and N2O5, and vertical exchange of air across the nocturnal inversion. During day-time, the local surface source of NO is not sufficient to explain the measured mixing ratios, and horizontal advection of NOx to the site must be included. The NO2/NO ratio during the morning und late afternoon is lower than predicted from the photostationary state owing to the local NO surface source, but is regulary higher during the hours around noon. For noon, August 10, 1994, the NO2/NO ratio was used to derive the momentary lower limit for the concentration of the peroxy-radicals of 2.2 · 109 cm–3 (86 pptv).  相似文献   
39.
 Complete chemical analyses, including ferric and ferrous iron, H2O contents and δD values for 16 phlogopite and biotite and 2 hornblende separates are presented. Samples were obtained from volcanic rocks from four localities: (1) phlogopite phenocrysts from minette lavas from the western Mexico continental arc, (2) biotite and hornblende phenocrysts from andesite lavas from Mono Basin, California, (3) phlogopite and biotite from clinopyroxenite nodules entrained in potassic lavas from the East African Rift, Uganda, and (4) phlogopite phenocrysts from a wyomingite lava in the Leucite Hills, Wyoming. The Fe2O3 contents in the micas range from 0.8 to 10.5 wt%, corresponding to 0.09 to 1.15 Fe3+ per formula unit (pfu). Water contents vary from 1.6 to 3.0 wt%, corresponding to 1.58 to 3.04 OH pfu, significantly less than would be expected for a site fully occupied by hydroxyl. Cation- and anion-based normalization procedures provide accurate mineral formulae with respect to most cations and anions, but are unable to generate accurate estimates of Fe3+/FeT, and overestimate OH at the expense of O on the hydroxyl site. These inaccuracies are present despite acceptable adjusted totals and stoichiometric calculated site occupancies. The phlogopite and biotite phenocrysts in arc-related lavas from western Mexico and eastern California have the highest Fe3+/FeT ratios (56–87%), reflecting high magmatic oxygen fugacities (ΔNNO = +2 to +5), in contrast to those from Uganda (25–40%) and the Leucite Hills (23%). There is no correlation between the OH content and the Fe3+/FeT ratio in the micas. Values of KMg/Fe2+D (± 2σ errors) were calculated for three phlogopite-olivine pairs (0.12 ± 0.12, 0.26 ± 0.14, 0.09 ± 0.12), two biotite-hornblende pairs (0.73 ± 0.08 and 1.22 ± 0.10) and a single phlogopite-augite pair (1.15 ± 0.12). Values of KF/OHD for two biotite and hornblende pairs could not be determined without significant error because of the extremely low F contents (< 0.2 wt%) of the four phases. The δD values obtained in this study encompass a large range (−137 to −43‰). The phlogopite and biotite separates from Uganda have δD values of −70 to −49‰, which overlap those believed to represent “primary” mantle. There is a larger range in δD values (−137 to −43‰) for phlogopite phenocrysts from western Mexico minette lavas, although their range in δ18O values (5.2–6.2‰) is consistent with “normal” mantle. It is unlikely, therefore, that the variable δD values reflect heterogeneity in the mantle source region of the minette magmas. Nor can the extremely low δD values reflect degassing of H2 or H2O since almost 100% loss of dissolved water in the magma is required, an unrealistic scenario given the stability of the hydrous phenocrysts. The very low δD values of the Mascota minette phlogopites require that the hydrogen be introduced from an external source (e.g., meteoric water). Whatever the process responsible for the observed hydrogen isotope composition, it had no effect on the δ18O value, f O 2, a H 2O or bulk composition of the host magmas. Received: 5 January 1995 / Accepted: 19 March 1996  相似文献   
40.
The effects of phosphate speciation on both rates of isotopic exchange and oxygen isotope equilibrium fractionation factors between aqueous phosphate and water were examined over the temperature range 70 to 180°C. Exchange between phosphate and water is much faster at low pH than at high pH, an observation that is similar to what has been observed in the analogous sulfate-water system. Oxygen isotope fractionations between protonated species like H3PO4 and H2PO4 that are dominant at relatively low pH and species like PO43− and ion pairs like KHPO4 that are dominant at relatively high pH, range between 5 and 8‰ at the temperatures of the experiments. In aqueous phosphate systems at equilibrium, 18O/16O ratios increase with increasing degree of protonation of phosphate. This effect can be explained in part by the relative magnitudes of the dissociation constants of the protonated species. Under equilibrium conditions, carbonate in solution or in solid phases concentrates 18O relative to orthophosphate in solution or in solid phases at all temperatures, supporting the traditional view that biogenic phosphate is precipitated in near oxygen isotope equilibrium with body/ambient aqueous fluids with no attendant vital effects.  相似文献   
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