Oxygen and Carbon Isotope Study of Calcite and Dolomite in the Disseminated Au-Ag Telluride Bulawan Deposit, Negros Island, Philippines     

Victor B. MAGLAMBAYAN  Daizo ISHIYAMA  Toshio MIZUTA  Osamu MATSUBAYA  Yohei ISHIKAWA 《Resource Geology》2001,51(2):107-116

Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ¹⁸O and δ¹³C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ¹⁸O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ¹³C values range from ‐6.1 to ‐1.0%. The δ¹⁸O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ¹³C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ¹⁸O and δ¹³C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ¹⁸O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ¹⁸O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and ¹⁸O‐enriched fluids which reacted with ¹⁸O‐ and ¹³C‐rich wallrocks such as limestone.  相似文献   

藏北高原D110点不同季节土壤温度的日变化特征   总被引：11，自引：0，他引：11  

杨梅学  姚檀栋  丁永建  王绍令  陈贤章  小池俊雄 《地理科学》1999,19(6):570-574

利用１９９８年ＧＡＭＥ－Ｔｉｂｅｔ加强观测期间取得的一个年周期的土壤温度资料,对藏北高原Ｄ１１０点土壤温度日变化特征的月际变化进行了分析。结果表明,在夏半年（５－９）月土壤温度存在明显的日变化,且基本上按正弦曲线变化,但相位随深度的增加而滞后;冬半年土壤温度尽管也存在日变化,但变幅较小。  相似文献   

Climato-limnological signals during the past 260 000 years in physical properties of bottom sediments from Lake Baikal     

Kenji Kashiwaya  Masayuki Ryugo  Masae Horii  Hideo Sakai  Toshio Nakamura  Takayoshi Kawai 《Journal of Paleolimnology》1999,21(2):143-150

The St.16 core obtained from the Academician Ridge of Lake Baikal in eastern Siberia may span about 260 000 years, and some physical properties of the core samples are closely related to aquatic paleoproductivity and climatic change. The median of grain size, grain density, and water content fluctuate synchronously. They also are connected with change in the abundance of biogenic silica (diatoms). The physical parameters indicate that there were high aquatic productivity periods around interglacial periods (MIS 5 and 7; 70 000-125 000 yr B.P. and 180 000-250 000 yr B.P.). Comparatively large clastics were transported from outside of the lake through various routes (ice rafting, etc.) in addition to fluvial routes during the glacials or 'stadials. There are ca. 20 000 yr, 40 000 yr and 100 000 yr periods in the variations of physical properties. These are related to the three Milankovitch parameters of solar insolation.  相似文献   

Age model, physical properties and paleoceanographic implications of the middle Pleistocene core sediments in the Choshi area, central Japan     

Koji  Kameo  Makoto  Okada  Moamen  El-Masry  Toshio  Hisamitsu  Saneatsu  Saito  Hiroomi  Nakazato  Naohiko  Ohkouchi  Minoru  Ikehara  Hisato  Yasuda  Hiroshi  Kitazato  Asahiko  Taira 《Island Arc》2006,15(3):366-377

Abstract   A continuous, well-preserved core was obtained from the Choshi area, on the Pacific side of Japan, to investigate paleoceanographic and paleoclimatic changes around the northwestern Pacific region during the middle Pleistocene. Siliciclastic sequences in the core are divided into five formations – the Obama, Yokone, Kurahashi and Toyosato Formations in the Inubo Group and the Katori Formation, in ascending order. Examination of calcareous nannofossils and magnetic polarities detected four datums in the core sediments of the Inubo Group: the top of Reticulofenestra asanoi , the base of Helicosphaera inversa , the top of Pseudoemiliania lacunosa and the Brunhes–Matuyama boundary. Fourteen marine isotope stages (MIS24–MIS11) were identified in the δ¹⁸O and δ¹³C records based on detected datums and the graphic correlation with the standard stack oxygen isotope curve. Magnetic susceptibility and gamma-ray attenuation porosity evaluator density were also measured and low values characterize the glacial intervals. Biogenic sedimentation by primary production may be larger during the glacial periods because of invasions of nutrient-rich northern surface-waters related to the southward shift of the Kuroshio front in the Choshi area.  相似文献   

Geology, Mineralogy, and Formation Environment of the Disseminated Gold-Silver Telluride Bulawan Deposit, Negros Occidental, Philippines     

Victor B. MAGLAMBAYAN  †  Daizo ISHIYAMA  Toshio MIZUTA  Akira IMAI  Yohei ISHIKAWA 《Resource Geology》1998,48(2):87-104

Abstract: The Bulawan deposit is located in the porphyry copper belt of southwest Negros island, Philippines. Propylitic, K–feldspar, sericitic, and carbonate alteration types can be distinguished in the deposit. Propylite alteration occurs mainly in Cretaceous-Eocene andesitic lavas and agglomerates while K–feldspar, sericite and carbonate alteration types occur mostly in the Middle Miocene dacite porphyry breccia pipes and stocks which were intruded into the andesites. K-feldspar zones occur in the inner parts of the sericitized zone. Sericite alteration overprinted the propylitized and K-feldspar alteration zones, at lower temperature than epidote and chlorite in the propylitized zone. Carbonate alteration is associated with the mineralization in the center of the breccia pipes and along faults. Mineralization consists of gold-silver telluride ores that are hosted by the carbonate– and sericite-altered dacite porphyry breccia pipes. The Bulawan ores occur mainly as disseminations, but unlike many epithermal gold deposits, lack classical epithermal colloform and crustiform quartz veins. The ore minerals are sphalerite, galena, chalcopyrite, pyrite and tetrahedite-tennantite with minor amounts of electrum, calaverite, petzite, sylvanite, hessite, tellurobismuthite, coloradoite, altaite, and rucklidgeite. Electrum and telluride minerals are associated mostly with calcite and dolomite-ankerite minerals. Fluid inclusions in quartz and calcite in clasts of propylitized andesite in the breccia pipes homogenize from about 300° to 400°C while fluid inclusions in quartz, calcite and sphalerite within the dacite porphyry breccia pipes homogenize between 300° to 310°C. The ores were formed around 300°C from hydrothermal solutions with salinity of about 6. 6 wt % NaCl equivalent. The presence of sylvanite and calaverite as intergrowths with each other, and the Ag content of calaverite are consistent with the above temperature estimate. Based on paragenesis, the Bulawan deposit formed in a pyrite-stable environment, with pH between 3. 4 and 5. 5, f_O2 between 10^-32 to 10^-30 atm, f_S2 between 10^-9.8 to 10^-7.8 atm, f_Te2 between 10^-8.9 to 10^-6.5 atm, and total sulfur content about 10^-2.8 molal. The dominant reduced sulfur species in the ore solutions may have been H₂S_(aq), and the likely aqueous tellurium species were H₂Te_(aq) and H₂TeO_3(aq). The ore minerals in the Bulawan deposit were probably formed by mixing of slightly saline and low salinity fluids.  相似文献   

Impacts of Indian Ocean SST biases on the Indian Monsoon: as simulated in a global coupled model     

Chloé Prodhomme  Pascal Terray  Sébastien Masson  Takeshi Izumo  Tomoki Tozuka  Toshio Yamagata 《Climate Dynamics》2014,42(1-2):271-290

In this study, the impact of the ocean–atmosphere coupling on the atmospheric mean state over the Indian Ocean and the Indian Summer Monsoon (ISM) is examined in the framework of the SINTEX-F2 coupled model through forced and coupled control simulations and several sensitivity coupled experiments. During boreal winter and spring, most of the Indian Ocean biases are common in forced and coupled simulations, suggesting that the errors originate from the atmospheric model, especially a dry islands bias in the Maritime Continent. During boreal summer, the air-sea coupling decreases the ISM rainfall over South India and the monsoon strength to realistic amplitude, but at the expense of important degradations of the rainfall and Sea Surface Temperature (SST) mean states in the Indian Ocean. Strong SST biases of opposite sign are observed over the western (WIO) and eastern (EIO) tropical Indian Ocean. Rainfall amounts over the ocean (land) are systematically higher (lower) in the northern hemisphere and the south equatorial Indian Ocean rainfall band is missing in the control coupled simulation. During boreal fall, positive dipole-like errors emerge in the mean state of the coupled model, with warm and wet (cold and dry) biases in the WIO (EIO), suggesting again a significant impact of the SST errors. The exact contributions and the distinct roles of these SST errors in the seasonal mean atmospheric state of the coupled model have been further assessed with two sensitivity coupled experiments, in which the SST biases are replaced by observed climatology either in the WIO (warm bias) or EIO (cold bias). The correction of the WIO warm bias leads to a global decrease of rainfall in the monsoon region, which confirms that the WIO is an important source of moisture for the ISM. On the other hand, the correction of the EIO cold bias leads to a global improvement of precipitation and circulation mean state during summer and fall. Nevertheless, all these improvements due to SST corrections seem drastically limited by the atmosphere intrinsic biases, including prominently the unimodal oceanic position of the ITCZ (Inter Tropical Convergence Zone) during summer and the enhanced westward wind stress along the equator during fall.  相似文献   

Characteristics of Triassic epithermal Au mineralization at the Q prospect,Chatree mining area,Central Thailand     

Ladda Tangwattananukul  Daizo Ishiyama  Osamu Matsubaya  Toshio Mizuta  Punya Charusiri  Hinako Sato  Koichiro Sera 《Resource Geology》2014,64(2):167-181

The Chatree deposit is located in the Loei‐Phetchabun‐Nakhon Nayok volcanic belt that extends from Laos in the north through central and eastern Thailand into Cambodia. Gold‐bearing quartz veins at the Q prospect of the Chatree deposit are hosted within polymictic andesitic breccia and volcanic sedimentary breccia. The orebodies of the Chatree deposit consist of veins, veinlets and stockwork. Gold‐bearing quartz veins are composed mainly of quartz, calcite and illite with small amounts of adularia, chlorite and sulfide minerals. The gold‐bearing quartz veins were divided into five stages based on the cross‐cutting relationship and mineral assemblage. Intense gold mineralization occurred in Stages I and IV. The mineral assemblage of Stages I and IV is characterized by quartz–calcite–illite–laumontite–adularia–chlorite–sulfide minerals and electrum. Quartz textures of Stages I and IV are also characterized by microcrystalline and flamboyant textures, respectively. Coexistence of laumontite, illite and chlorite in the gold‐bearing quartz vein of Stage IV suggests that the gold‐bearing quartz veins were formed at approximately 200°C. The flamboyant and brecciated textures of the gold‐bearing quartz vein of Stage IV suggest that gold precipitated with silica minerals from a hydrothermal solution that was supersaturated by boiling. The δ¹⁸O values of quartz in Stages I to V range from +10.4 to +11.6‰ except for the δ¹⁸O value of quartz in Stage IV (+15.0‰). The increase in δ¹⁸O values of quartz at Stage IV is explained by boiling. P_H2O is estimated to be 16 bars at 200°C. The f_CO2 value is estimated to be 1 bar based on the presence of calcite in the mineral assemblage of Stage IV. The total pressure of the hydrothermal solution is approximately 20 bars at 200°C, suggesting that the gold‐bearing quartz veins of the Q prospect formed about 200 m below the paleosurface.  相似文献   

Long-term variations of North Pacific Tropical Water along the 137°E repeat hydrographic section     

Toshiya Nakano  Tomoyuki Kitamura  Shusaku Sugimoto  Toshio Suga  Masafumi Kamachi 《Journal of Oceanography》2015,71(3):229-238

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Chaotic Itinerancy and Thermalization in a One-Dimensional Self-Gravitating System     

Toshio Tsuchiya  Naoteru Gouda  Tetsuro Konishi 《Astrophysics and Space Science》1997,257(2):319-341

Long time behavior of one-dimensional self-gravitating system is numerically investigated. Itinerant behavior among quasiequilibria is discovered, and its origin is clarified. The macroscopic distributions of the quasiquilibria are different from the isothermal distribution, but the transient states, which appears between two successive quasiequilibria, resemble the isothermal distribution. Averaging over the is itinerancy gives approximately the thermal equilibrium. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Transformation between surface spherical harmonic expansion of arbitrary high degree and order and double Fourier series on sphere     

Toshio Fukushima 《Journal of Geodesy》2018,92(2):123-130

In order to accelerate the spherical harmonic synthesis and/or analysis of arbitrary function on the unit sphere, we developed a pair of procedures to transform between a truncated spherical harmonic expansion and the corresponding two-dimensional Fourier series. First, we obtained an analytic expression of the sine/cosine series coefficient of the \(4 \pi \) fully normalized associated Legendre function in terms of the rectangle values of the Wigner d function. Then, we elaborated the existing method to transform the coefficients of the surface spherical harmonic expansion to those of the double Fourier series so as to be capable with arbitrary high degree and order. Next, we created a new method to transform inversely a given double Fourier series to the corresponding surface spherical harmonic expansion. The key of the new method is a couple of new recurrence formulas to compute the inverse transformation coefficients: a decreasing-order, fixed-degree, and fixed-wavenumber three-term formula for general terms, and an increasing-degree-and-order and fixed-wavenumber two-term formula for diagonal terms. Meanwhile, the two seed values are analytically prepared. Both of the forward and inverse transformation procedures are confirmed to be sufficiently accurate and applicable to an extremely high degree/order/wavenumber as \(2^{30}\,{\approx }\,10^9\). The developed procedures will be useful not only in the synthesis and analysis of the spherical harmonic expansion of arbitrary high degree and order, but also in the evaluation of the derivatives and integrals of the spherical harmonic expansion.  相似文献