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31.
Electron spin resonance (ESR) and red thermoluminescence (RTL) methods were applied to quartz of eight Japanese Quaternary tephras ranging from 30 to 900 kyr, which have independent ages from other dating methods. The ESR ages were consistent for younger samples, while those from the Ti–Li center are older than those for the Al center for older samples. RTL ages are consistent with the age references and are roughly consistent with Al center ages. The dose response of the Ti–Li center after heating at 260 °C for 15 min implies that thermally unstable component is created in Ti–Li center by irradiation, leading to possible overestimations in the dose values. 相似文献
32.
Yamada M Takada H Toyoda K Yoshida A Shibata A Nomura H Wada M Nishimura M Okamoto K Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113
Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant. 相似文献