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101.
Russell S. Crosbie Trevor Pickett Freddie S. Mpelasoka Geoff Hodgson Stephen P. Charles Olga V. Barron 《Climatic change》2013,117(1-2):41-53
This study used 16 Global Climate Models and three global warming scenarios to make projections of recharge under a 2050 climate for the entire Australian continent at a 0.05° grid resolution. The results from these 48 future climate variants have been fitted to a probability distribution to enable the results to be summarised and uncertainty quantified. The median results project a reduction in recharge across the west, centre and south of Australia and an increase in recharge across the north and a small area in the east of the continent. The range of results is quite large and for large parts of the continent encompasses both increases and decreases in recharge. This makes it difficult to utilise for water resources management so the results have been analysed with a risk analysis framework; this enables the future projections for groundwater recharge to be communicated to water managers in terms of likelihood and consequence of a reduction in recharge. This highlights an important message for water resource managers that in most areas of Australia they will be making decisions on water allocations under considerable uncertainty as to the direction and magnitude of recharge change under a future climate and that this uncertainty may be irreducible. 相似文献
102.
Trevor C. Hall Andrea M. Sealy Tannecia S. Stephenson Shoji Kusunoki Michael A. Taylor A. Anthony Chen Akio Kitoh 《Theoretical and Applied Climatology》2013,113(1-2):271-287
Present-day (1979–2003) and future (2075–2099) simulations of mean and extreme rainfall and temperature are examined using data from the Meteorological Research Institute super-high-resolution atmospheric general circulation model. Analyses are performed over the 20-km model grid for (1) a main Caribbean basin, (2) sub-regional zones, and (3) specific Caribbean islands. Though the model’s topography underestimates heights over the eastern Caribbean, it captures well the present-day spatial and temporal variations of seasonal and annual climates. Temperature underestimations range from 0.1 °C to 2 °C with respect to the Japanese Reanalysis and the Climatic Research Unit datasets. The model also captures fairly well sub-regional scale variations in the rainfall climatology. End-of-century projections under the Intergovernmental Panel on Climate Change SRES A1B scenario indicate declines in rainfall amounts by 10–20 % for most of the Caribbean during the early (May–July) and late (August–October) rainy seasons relative to the 1979–2003 baselines. The early dry season (November–January) is also projected to get wetter in the far north and south Caribbean by approximately 10 %. The model also projects a warming of 2–3 °C over the Caribbean region. Analysis of future climate extremes indicate a 5–10 % decrease in the simple daily precipitation intensity but no significant change in the number of consecutive dry days for Cuba, Jamaica, southern Bahamas, and Haiti. There is also indication that the number of hot days and nights will significantly increase over the main Caribbean basin. 相似文献
103.
D. Rees T.J. Fuller-Rowell M.F. Smith R. Gordon T.L. Killeen P.B. Hays N.W. Spencer L. Wharton N.C. Maynard 《Planetary and Space Science》1985,33(4):425-456
One of the most consistent and often dramatic interactions between the high latitude ionosphere and the thermosphere occurs in the vicinity of the auroral oval in the afternoon and evening period. Ionospheric ions, convected sunward by the influence of the magnetospheric electric field, create a sunward jet-stream in the thermosphere, where wind speeds of up to 1 km s?1 can occur. This jet-stream is nearly always present in the middle and upper thermosphere (above 200 km altitude), even during periods of very low geomagnetic activity. However, the magnitude of the winds in the jet-stream, as well as its location and range in latitude, each depend on geomagnetic activity. On two occasions, jet-streams of extreme magnitude have been studied using simultaneous ground-based and satellite observations, probing both the latitudinal structure and the local time dependence. The observations have then been evaluated with the aid of simulations using a global, three-dimensional, time-dependent model of thermospheric dynamics including the effects of magnetospheric convection and particle precipitation. The extreme events, where sunward winds of above 800 ms?1 are generated at relatively low geomagnetic latitudes (60–70°) require a greatly expanded auroral oval and large cross-polar cap electric field ( ~ 150 kV). These in turn are generated by a persistent strong Interplanetary Magnetic Field, with a large southward component. Global indices such as Kp are a relatively poor indicator of the magnitude and extent of the jet-stream winds. 相似文献
104.
105.
Trevor Greensmith 《Geology Today》2004,20(5):189-193
There is nothing like a good controversy in geology, when vehemently held conflicting opinions set the adrenaline running. The debate over hot spots or mantle plumes is developing in this way; as such it is pertinent to look at the Canary Islands archipelago where hot spot ideas have been in place for some time. 相似文献
106.
Ewan O'Sullivan Duncan A. Forbes Trevor J. Ponman 《Monthly notices of the Royal Astronomical Society》2001,324(2):420-426
The evolution in X-ray properties of early-type galaxies is largely unconstrained. In particular, little is known about how, and if, remnants of mergers generate hot gas haloes. Here we examine the relationship between X-ray luminosity and galaxy age for a sample of early-type galaxies. Comparing normalized X-ray luminosity to three different age indicators, we find that L X L B increases with age, suggesting an increase in X-ray halo mass with time after the last major star formation episode of a galaxy. The long-term nature of this trend, which appears to continue across the full age range of our sample, poses a challenge for many models of hot halo formation. We conclude that models involving a declining rate of type Ia supernovae, and a transition from outflow to inflow of the gas originally lost by galactic stars, offer the most promising explanation for the observed evolution in X-ray luminosity. 相似文献
107.
108.
Processing U ores in the JEB Mill of the McClean Lake Operation in northern Saskatchewan produces spent leaching solutions (raffinates) with pH 1.5, and As and Ni concentrations up to 6800 and 5200 mg L−1, respectively. Bench-scale neutralization experiments (pH 2–8) were performed to help optimize the design of mill processes for reducing As and Ni concentrations in tailings and raffinates to 1 mg L−1 prior to their disposal. Precipitate mineralogy determined by chemical analysis, XRD, SEM, EM, XM and EXAFS methods, included gypsum (the dominant precipitate), poorly crystalline scorodite (precipitated esp. from pH 2–4), annabergite, hydrobasaluminite, ferrihydrite, green rust II and theophrastite. The As was mostly in scorodite with smaller amounts in annabergite and trace As adsorbed and/or co-precipitated, probably by ferrihydrite. Geochemical modeling indicated that above pH 2, the ion activity product (IAP) of scorodite lies between the solubility products of amorphous and crystalline phases (log Ksp = −23.0 and −25.83, respectively). The IAP decreases with increasing pH, suggesting that the crystallinity of the scorodite increases with pH. Forward geochemical models support the assumption that during neutralization, particles of added base produce sharp local pH gradients and disequilibrium with bulk solutions, facilitating annabergite and theophrastite precipitation. 相似文献
109.
Julien?ReynesEmail authorView authors OrcID profile Michael?Jollands J?rg?Hermann Trevor?Ireland 《Contributions to Mineralogy and Petrology》2018,173(9):69
The incorporation mechanisms and diffusional loss of hydrogen in garnet have been experimentally investigated. A suite of gem-quality hydrous spessartine- and grossular-rich garnets were analysed by Fourier transform infrared spectroscopy (FTIR) and by ion microprobe (SHRIMP-SI) to determine the calibration coefficients for quantification of FTIR data. The excellent agreement between measured absorption and OH/O indicates that the same molar extinction coefficient can be used for spessartine and grossular. The coefficient of 14400 l mol??1 cm??2 proposed by Maldener et al. (Phys Chem Miner 30:337–344, 2003) seems the most appropriate for both minerals. A grossular with 6.4% andradite and 1.6% almandine containing 834 ppm H2O, and an almost pure spessartine with 282 ppm H2O, were selected for diffusion experiments. 1.5-mm cubes of garnets were heated between 12 h and 10 days at 1 atm under various temperature (750–1050 °C) and oxygen fugacity (\({f_{{{\text{O}}_2}}}\)) conditions, (ΔQFM +?15.2 to ??3.0). Diffusion profiles were acquired from sections through the cubes using FTIR, with a deconvolution algorithm developed to assess peak-specific behaviour. Different families of peaks have been identified based on their diffusive behaviour, representing hydrogen incorporated in different H-bearing defects. A dominant, fast, strongly \({f_{{{\text{O}}_2}}}\)-dependent oxidation-related diffusion mechanism is proposed \(\left( {\{ {{\text{M}}^{2+}}+{{\text{H}}^+}\} +\frac{1}{4}{{\text{O}}_2}={{\text{M}}^{3+}}+\frac{1}{2}{{\text{H}}_2}{\text{O}}} \right)\) (M=Fe, Mn) with a relatively low activation energy (158?±?19 kJ mol??1). This diffusion mechanism is likely restricted by availability of ferrous iron in grossular. At low oxygen fugacity, this diffusion mechanism is shut off and the diffusivity decreased by more than three orders of magnitude. A second, slower hydrogen diffusion mechanism has been observed in minor bands, where charge balance might be maintained by diffusion of cation vacancies, with much higher activation energy (≈?200–270 kJ mol??1). Spessartine shows clear differences in peak retentivity suggesting that up to four different H sites might exist. This opens exciting opportunities to use hydrogen diffusion in garnet as speedometer. However, it is essential to constrain the main diffusion mechanisms and the oxygen fugacity in the rocks investigated to obtain timescales for metamorphic or igneous processes. 相似文献
110.
Jordan G. Hamilton Jay Grosskleg David Hilger Kris Bradshaw Trevor Carlson Steven D. Siciliano Derek Peak 《Geochemical transactions》2018,19(1):1
Adsorption and precipitation reactions often dictate the availability of phosphorus in soil environments. Tripolyphosphate (TPP) is considered a form of slow release P fertilizer in P limited soils, however, investigations of the chemical fate of TPP in soils are limited. It has been proposed that TPP rapidly hydrolyzes in the soil solution before adsorbing or precipitating with soil surfaces, but in model systems, TPP also adsorbs rapidly onto mineral surfaces. To study the adsorption behavior of TPP in calcareous soils, a short-term (48 h) TPP spike was performed under laboratory conditions. To determine the fate of TPP under field conditions, two different liquid TPP amendments were applied to a P limited subsurface field site via an in-ground injection system. Phosphorus speciation was assessed using X-ray absorption spectroscopy, total and labile extractable P, and X-ray diffraction. Adsorption of TPP to soil mineral surfaces was rapid (< 48 h) and persisted without fully hydrolyzing to ortho-P. Linear combination fitting of XAS data indicated that the distribution of adsorbed P was highest (~ 30–40%) throughout the site after the first TPP amendment application (high water volume and low TPP concentrations). In contrast, lower water volumes with more concentrated TPP resulted in lower relative fractions of adsorbed P (15–25%), but a significant increase in total P concentrations (~ 3000 mg P kg soil) and adsorbed P (60%) directly adjacent to the injection system. This demonstrates that TPP application increases the adsorbed P fraction of calcareous soils through rapid adsorption reactions with soil mineral surfaces. 相似文献