华南地区中生代Cu (Mo) W Sn矿床成矿作用与洋岭/转换断层俯冲   总被引：25，自引：1，他引：24  

李晓峰  Watanabe Yasushi  华仁民  毛景文 《地质学报》2008,82(5):625-640

华南地区是我国重要的金属矿产资源产地,除了发育大量的钨锡钼铋和稀土等金属矿产外,还有铜金矿床分布。本文通过对华南地区29个典型CuMoWSn矿床的时空分布及其与之有关的花岗质岩体的侵位年龄分析,探讨了与不同成矿类型有关的花岗质岩石的地球化学特征。本文认为华南地区10个典型的与Cu有关的矿床主要发生在180~170Ma、160~150Ma以及105~90Ma三个时期,而10个钨矿床主要集中于170~130Ma;4个WSn矿床集中于170~130Ma和120~110Ma;而5个Sn矿床则发育于170~150Ma、130~110Ma以及100~90Ma三个时期。Cu矿床主要与同熔型花岗岩有关,而Mo、WSn既与同熔型花岗岩有关,又与改造型花岗岩有关。在岩石地球化学上,与Cu(Mo)WSn成矿作用有关的花岗质岩石也表现出不同的地球化学特点,如,从Cu(Mo)矿床到WSn矿床SiO2含量有逐渐增大、氧化性逐渐降低、还原性逐渐增加以及分异演化程度有逐渐增高的趋势。与Cu(Mo)Au矿床有关的花岗质岩石具有较低的SiO2（60.3%~68.1%）,氧化性较高（Fe2O3/FeO=0.31~1.81）,分异演化程度较低（Rb/Sr=0.05~3.3）的特点;与Cu(Pb)(Zn)矿床有关的花岗质岩石具有相对较高的SiO2（73.3%~75.2%）,氧化性稍高（Fe2O3/FeO=0.68~1.74）,分异程度稍低（Rb/Sr=10.8~57.8）的特点;而与Mo矿床有关的花岗质岩石具有较宽的SiO2（67.3%~76.2%）变化范围,氧化性稍低（Fe2O3/FeO=0.68~1.74）,分异演化程度稍低（Rb/Sr=0.6~9.29）;与W矿有关的花岗质岩石的SiO2含量为69.9%~80.1%,还原性稍低（Fe2O3/FeO=0.19~0.76）,分异演化程度稍高（Rb/Sr=21.9~61.7）;与WSn矿床有关的SiO2为74.8%~78.7%,还原性较低（Fe2O3/FeO=0.08~0.59）,分异程度较高（Rb/Sr=10.8~139）;与Sn矿床有关的花岗质岩石的SiO2为64.8%~76.9%,还原性高（Fe2O3/FeO=0.01~0.58）,分异演化程度高（Rb/Sr=1~530）。在结合华南地区花岗岩类岩石的分布特征以及盆岭构造的特点,本文提出华南地区CuMoWSn矿床的成矿作用是不同时期大洋板块或者洋岭多阶段俯冲结果的新成因模型,即早侏罗世休眠的FarallonIzanagi洋岭俯冲导致早—中侏罗世Cu成矿作用;中—晚侏罗世活动的FarallonIzanagi洋岭和转换断层俯冲是中晚侏罗世Cu(Mo)(W)成矿作用以及多阶段WSn成矿作用的触发动力,而白垩纪Izanagi大洋板块俯冲则是白垩纪斑岩型CuWSn成矿作用的诱因。该模型的提出较好地解释了华南中生代大规模岩石圈拆沉—减薄—伸展的机制及其大规模成矿作用的动力。  相似文献   

Thermoluminescence, electron paramagnetic resonance and optical absorption in natural and synthetic rhodonite crystals     

J. R. B. Paião  S. Watanabe 《Physics and Chemistry of Minerals》2008,35(9):535-544

Thermoluminescence, electron paramagnetic resonance and optical absorption properties of rhodonite, a natural silicate mineral, have been investigated and compared to those of synthetic crystal, pure and doped. The TL peaks grow linearly for radiation dose up to 4 kGy, and then saturate. In all the synthetic samples, 140 and 340°C TL peaks are observed; the difference occurs in their relative intensities, but only 340°C peak grows strongly for high doses. Al₂O₃ and Al₂O₃ + CaO-doped synthetic samples presented several decades intenser TL compared to that of synthetic samples doped with other impurities. A heating rate of 4°C/s has been used in all the TL readings. The EPR spectrum of natural rhodonite mineral has only one huge signal around g = 2.0 with width extending from 1,000 to 6,000 G. This is due to Mn dipolar interaction, a fact proved by numerical calculation based on Van Vleck dipolar broadening expression. The optical absorption spectrum is rich in absorption bands in near-UV, visible and near-IR intervals. Several bands in the region from 540 to 340 nm are interpreted as being due to Mn³⁺ in distorted octahedral environment. A broad and intense band around 1,040 nm is due to Fe²⁺. It decays under heating up to 900°C. At this temperature it is reduced by 80% of its original intensity. The pink, natural rhodonite, heated in air starts becoming black at approximately 600°C.  相似文献   

Boron cycling by subducted lithosphere; insights from diamondiferous tourmaline from the Kokchetav ultrahigh-pressure metamorphic belt     

Tsutomu Ota  Katsura Kobayashi  Takuya Kunihiro  Eizo Nakamura 《Geochimica et cosmochimica acta》2008,72(14):3531-3541

Subduction of lithosphere, involving surficial materials, into the deep mantle is fundamental to the chemical evolution of the Earth. However, the chemical evolution of the lithosphere during subduction to depth remains equivocal. In order to identify materials subjected to geological processes near the surface and at depths in subduction zones, we examined B and Li isotopes behavior in a unique diamondiferous, K-rich tourmaline (K-tourmaline) from the Kokchetav ultrahigh-pressure metamorphic belt. The K-tourmaline, which includes microdiamonds in its core, is enriched in ¹¹B relative to ¹⁰B (δ¹¹B = −1.2 to +7.7) and ⁷Li relative to ⁶Li (δ⁷Li = −1.1 to +3.1). It is suggested that the K-tourmaline crystallized at high-pressure in the diamond stability field from a silicate melt generated at high-pressure and temperature conditions of the Kokchetav peak metamorphism. The heavy isotope signature of this K-tourmaline differs from that of ordinary Na-tourmalines in crustal rocks, enriched in the light B isotope (δ¹¹B = −16.6 to −2.3), which experienced isotope fractionation through metamorphic dehydration reactions. A possible source of the heavy B-isotope signature is serpentine in the subducted lithospheric mantle. Serpentinization of the lithospheric mantle, with enrichment of heavy B-isotope, can be produced by normal faulting at trench-outer rise or trench slope regions, followed by penetration of seawater into the lithospheric mantle. Serpentine breakdown in the lithospheric mantle subducted in subarc regions likely provided fluids with the heavy B-isotope signature, which was acquired during the serpentinization prior to subduction. The fluids could ascend and cause partial melting of the overlying crustal layer, and the resultant silicate melt could inherit the heavy B-isotope signature. The subducting lithospheric mantle is a key repository for modeling the flux of fluids and associated elements acquired at a near the surface into the deep mantle.  相似文献   

Acceleration phenomena observed by interplanetary scintillation at 0.1–0.3 AU     

M. Kojima  H. Misawa  H. Watanabe  Y. Yamauchi 《Astrophysics and Space Science》1996,243(1):229-237

Interplanetary scintillation has observed high-latitude streams which show low speeds (400 km/s) within 0.3 AU and high speeds (700 km/s) beyond 0.3 AU. The foot points of these streams were located in the HeI coronal holes or at their boundaries. Since the IPS measurement is biased by one or several mechanisms, we investigated whether this acceleration phenomena could be caused by bias effects or not. Speed increase of more than 100 km/s is left without being explained by the bias effects.  相似文献   

Nitrogen, Oxygen and Argon Dissolved in the Northern North Pacific in Early Summer     

Noriko Nakayama  Shuichi Watanabe  Shizuo Tsunogai 《Journal of Oceanography》2002,58(6):775-785

Major gases dissolved in seawater were accurately determined with a shipboard gas chromatographic method. The standard deviations were 0.28, 0.34 and 0.36% for N₂, O₂ and Ar, respectively. The method was applied to water from the northwestern North Pacific Ocean collected in May to June 2000. We got 127 duplicate seawater samples from the surface 200 m layer at 11 stations. The O₂ concentrations obtained by this method agreed with those given by the Winkler method. All the seawater samples from the surface 200 m, especially those from the upper 30 m, were supersaturated with respect to atmospheric N₂ and Ar concentrations. In the topmost 30 m layer, the degrees of supersaturation in the inventory were 2.7–4.3% for N₂ (ΔN₂) and 1.7–2.6% for Ar (ΔAr), and their ratios, ΔN₂/ΔAr, ranged from 1.53 to 1.81. This supersaturation seems to be chiefly due to air bubbles injected into the water and dissolved due to the water pressure, because the N₂/Ar ratio of the air is around 2. The amounts of air bubbles dissolved in the upper 30 m water were relatively large, with mean value of 0.41 ml/kg or 18.4 μmol/kg. The ΔN₂, ΔAr and ΔN₂/ΔAr values were all positively well correlated with the wind velocities averaged for the last 24 hours prior to sampling, allowing the conclusion to be drawn that the weaker the wind velocity, the dissolved gas composition approaches in equilibrium with the air; while the stronger the wind velocity, it approaches in the air composition. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Estimated respiration rate of myctophid fish from the enzyme activity of the electron-transport-system     

Tsutomu Ikeda 《Journal of Oceanography》1989,45(3):167-173

Whole animal respiration rates (R) of myctophid fishes which migrate up to the surface at night were estimated using enzyme activities of the electron-transport-system (ETS). The fish, currently unsusceptible to laboratory experimentation, were caught at sea and stored frozen at –20°C for 14–17 days prior to enzyme assay. Supplemental tests on two tropical marine fishes (gobies and poma-centrids) showed no measurable loss of ETS activity during storage for up to 36 d at –20°C. The ETS/R ratio for gobies and pomacentrids was 1.61. Respiration rates of myctophid fishes estimated using this ETS/R ratio ranged from 17.7 to 453µl O₂ individual^–1 hr^–1 for specimens weighing 26–1101 mg wet weight atin situ temperature of 24–27°C. The relationship between the respiration rate standardized to a temperature of 20°C (R:µl O₂ individual^–1hr^–1) and wet weight (WW: mg) of myctophid fishes was expressed asR=0.790 WW^0.84 (r=0.964,n=27). This relationship does not differ appreciably from the respiration rates of other marine fishes calculated from Winberg's equation.  相似文献   

Growth characteristics ofChattonella antiqua (Raphidophyceae)     

Yasuo Nakamura  Makoto M. Watanabe 《Journal of Oceanography》1983,39(3):110-114

Chattonella antiqua (Raphidophyceae), which causes heavy red tides in the Seto Inland Sea, Japan, was placed in axenic clonal culture by micropipette washing. The effects of temperature, salinity, light intensity and pH on growth were monitored. Maximum growth occurred at 25°C, at salinities between 25 and 41‰, under light intensities above 0.04 ly min^?1. The pH effect was not significant in the pH range from 7.6 to 8.3. Comparisons of our results with those from field observations suggest that the development of theC. antiqua red tide is strongly temperature dependent.  相似文献   

Simultaneous vertical measurements of in situ pH and CO2 in the sea using spectrophotometric profilers     

Yoshiyuki Nakano  Hideshi Kimoto  Shuichi Watanabe  Koh Harada  Yutaka W. Watanabe 《Journal of Oceanography》2006,62(1):71-81

We have developed new systems capable of profiling to >1000 m for measuring in situ pH and fugacity of CO₂ (fCO₂) in the ocean using spectrophotometric analysis (pH and CO₂ profilers). The in situ pH is determined by detecting the color change of the pH indicator (m-cresol purple). It can withstand ambient pressure to 1000 m depth. The CO₂ profiler analyzed in situ fCO₂ by detecting the change of pH in an inner solution, equilibrated with the seawater through a gas permeable membrane. It can be operated to 2500 m depth. We used an amorphous fluoropolymer tubing form of AF-2400 for the gas permeable membrane due to its high gas permeability coefficients. The inner solution was a mixture of 2 μM bromocresol purple (BCP) and 5 μM sodium hydroxide. This system gave us a response time of 1 minute, which is twice as fast as previous systems. The precisions of pH and CO₂ profilers were within 0.002 and 2.5% respectively. We have used these profilers to study the North Pacific, obtaining good agreement with the difference between the data from profilers and a discrete bottle of 0.002 ± 0.005 pH (SE, n = 25) and −0.4 ± 3 μatm (SE, n = 31).  相似文献   

The Optical Characteristics of the Water in the Three Oceans Part—IV     

Kanau Matsuike  Tsutomu Morinaga  Tadayoshi Sasaki 《Journal of Oceanography》1970,26(1):52-60

An attempt to the approximate figures of seasonal distribution of solar energy reached to and penetrated in the water of the oceans, as a preliminary step to the estimation of primary production in the oceans from the optical point, was performed in the Indian Ocean, North Pacific Ocean and Antarctic Ocean on the same lines in the part III. In consequence, the total amount of solar energy for the year in each depth showed marked differences in each zone of the oceans as illustrated in Fig. 5. By way of example, it could be said that underwater solar energy already came to 33.4 Kg·cal/cm²·year in 10 m deep in the equator of Indian Ocean and was 54% of that, in the Kuroshio region of the North Pacific Ocean, 44% in the Sub-Antarctic zone, 13% in the Antarctic zone and 6% in the Antarctic Convergence zone, respectively. Besides, on the assumption that a lower limit of the photic zone is marked by the depth here underwater surface solar energy is reduced to 1% or 5g·cal/cm²·day, the ratio of the total photic zone for the year in unit area of sea surface was approximately 100∶80∶60∶25 or 100∶75∶50∶20 in the equator of the Indian Ocean, Kuroshio region, Sub-Antarctic zone, and Antarctic and Antarctic Convergence zones, respectively.  相似文献   

Metabolism and chemical composition of mesopelagic ostracods in the western North Pacific Ocean     

Kaeriyama  Hideki; Ikeda  Tsutomu 《ICES Journal of Marine Science》2004,61(4):535-541

  相似文献