The chemistry of lava-seawater interactions II: the elemental signature     

Joseph A Resing  Francis J Sansone 《Geochimica et cosmochimica acta》2002,66(11):1925-1941

The flow of lava into the ocean at the shoreline of Kilauea Volcano during the ongoing Pu’u O’o eruption has allowed a detailed study of the geochemical interaction between lava and seawater. This paper focuses on the chemistry of the major and minor elements in the fluids that resulted from this interaction. The elemental enrichments in these fluids are dominated by three processes: (1) evaporation of water from seawater, which creates solutions enriched in the major elements found in seawater, (2) congruent dissolution of the basalt glass matrix, which is limited by the solubility of some of the elements in seawater, and (3) removal of volatile phases from the lava on contact with seawater.Using a simple model of volatile emanation (using published emanation coefficients) and congruent dissolution, we are able to explain the concentrations observed for the majority of elements in precipitation from the steam plume at the shoreline lava entry and in water allowed to interact with molten lava in controlled experiments. Fe, Al, Ti, and some of the rare earth elements (REEs) in precipitation samples from the steam plume at the lava entry were > 10,000-times enriched over their ambient seawater concentrations, suggesting that these elements may be useful for identifying submarine eruptions. The flux of elements from the Kilauea ocean lava entry is greater than that from a typical midocean ridge hydrothermal vent field for Al, Cd, Co, and the REEs, whereas the opposite is true for the remainder of the elements studied.  相似文献   

Experimental silicate mineral/melt partition coefficients for beryllium and the crustal Be cycle from migmatite to pegmatite   总被引：1，自引：0，他引：1  

Joseph M Evensen  David London 《Geochimica et cosmochimica acta》2002,66(12):2239-2265

Partition coefficients (D_Be^mineral/melt) for beryllium between hydrous granitic melt and alkali feldspars, plagioclase feldspars, quartz, dark mica, and white mica were determined by experiment at 200 MPa H₂O as a function of temperature (650-900°C), activity of Be in melt (trace levels to beryl saturation), bulk composition, and thermal run direction. At trace levels, Be is compatible in plagioclase of An₃₁ (1.84 at 700°C) and muscovite (1.35 at 700°C) but incompatible in biotite (0.39-0.54 from 650-800°C), alkali feldspar (0.38-0.19 from 680-850°C), quartz (0.24 at 800°C), and albite (0.10 at 750°C). The partition coefficients are different at saturation of the melt in beryl: lower in the case of plagioclase of An₃₁ (0.89 at 700°C), muscovite (0.87 at 700°C), biotite (0.18-0.08 from 675-800°C), alkali feldspar (0.18-0.14 from 680-700°C), and quartz (0.17-0.08 from 750-800°C), but higher in the case of albite (0.37 at 750°C).With other data sources, these new partition coefficients were utilized to track, first, the distribution of Be between aluminous quartzofeldspathic source rocks and their anatectic melts, and second, the dispersion or concentration of Be in melt through igneous crystal fractionation of different magma types (e.g., S-type, I-type) up to beryl-saturated granitic pegmatites and, finally, into their hydrothermal aureoles. Among the rock-forming minerals, cordierite, calcic oligoclase, and muscovite (in this order) control the fate of Be because of the compatibility of Be in these phases. In general, beryl-bearing pegmatites can arise only after extended crystal fractionation of large magma batches (to F, fraction of melt remaining, ≤0.05); granitic magmas that originate from cordierite-bearing protoliths or that contain large modal quantities of calcic oligoclase will not achieve beryl saturation at any point in their evolution.  相似文献   

Microbial respiration and diffusive transport of O₂, O₂, and OO in unsaturated soils: a mesocosm experiment     

M.Jim HendryLeonard I Wassenaar  Tyler K Birkham 《Geochimica et cosmochimica acta》2002,66(19):3367-3374

Although the flux of molecular O₂ between the atmosphere and the subsurface is intrinsically linked to the net soil production of greenhouse gasses, few studies have focused on the controls affecting the isotopic composition of O₂ in the subsurface. Here, we developed and tested a stable oxygen isotope tracer technique and gas transport modeling approach to evaluate O₂ cycling and fluxes from the subsurface that used an environmentally controlled soil mescosm. We measured the O₂ and δ¹⁸O₂ profiles in a model unsaturated soil zone and quantified the O₂ consumption rates and the O₂ isotope fractionation factors resulting from the combined processes of subsurface microbial (including bacteria, fungi, and protozoa) consumption of O₂ and diffusive influx of O₂ from the atmosphere. We found that at high respiration rates in the mesocosm, there appeared to be very little isotope fractionation of O₂ by soil microorganisms. Although the mesocosm respiration rates are not typical of natural soils in northern temperate climes, they may be more representative of soils in warm and moist tropical environments. Our findings caution against the indiscriminate application of laboratory-determined oxygen isotope fractionation factors to field settings. The oxygen isotope tracer and modeling approach demonstrated here may be applied to gain a better understanding of biogenic gas production and O₂ cycling in subsurface systems and soils.  相似文献   

Determining the trophic guilds of fishes and macroinvertebrates in a seagrass food web     

Joseph J. Luczkovich  Garcy P. Ward  Jeffrey C. Johnson  Robert R. Christian  Daniel Baird  Hilary Neckles  William M. Rizzo 《Estuaries and Coasts》2002,25(6):1143-1163

We established trophic guilds of macroinvertebrate and fish taxa using correspondence analysis and a hierarchical clustering strategy for a seagrass food web in winter in the northeastern Gulf of Mexico. To create the diet matrix, we characterized the trophic linkages of macroinvertebrate and fish taxa present inHalodule wrightii seagrass habitat areas within the St. Marks National Wildlife Refuge (Florida) using binary data, combining dietary links obtained from relevant literature for macroinvertebrates with stomach analysis of common fishes collected during January and February of 1994. Heirarchical average-linkage cluster analysis of the 73 taxa of fishes and macroinvertebrates in the diet matrix yielded 14 clusters with diet similarity ≥ 0.60. We then used correspondence analysis with three factors to jointly plot the coordinates of the consumers (identified by cluster membership) and of the 33 food sources. Correspondence analysis served as a visualization tool for assigning each taxon to one of eight trophic guilds: herbivores, detritivores, suspension feeders, omnivores, molluscivores, meiobenthos consumers, macrobenthos consumers and piscivores. These trophic groups, corss-classified with major taxonomic groups, were further used to develop consumer compartments in a network analysis model of carbon flow in this seagrass ecosystem. The method presented here should greatly improve the development of future network models of food webs by providing an objective procedure for aggregating trophic groups.  相似文献   

Analytical Solution for Subsurface Gas Flow to a Well Induced by Surface Pressure Fluctuations   总被引：2，自引：0，他引：2  

Joseph Rossabi  Ronald W. Falta 《Ground water》2002,40(1):67-75

  相似文献   

Evaluating Earthquake-Triggered Landslide Hazard at the Basin Scale Through Gis in the Upper Sele River Valley   总被引：6，自引：0，他引：6  

Domenico Capolongo  Alberto Refice  Joseph Mankelow 《Surveys in Geophysics》2002,23(6):595-625

To evaluate techniques for assessing earthquake-triggeredlandslide hazard in the Southern Apennines (Italy), a GIS-based analysis was used to modelseismically induced slope deformations. Geological, geotechnical, geomorphological and seismologicaldata were integrated into a standard earthquake slope stability model. The model assessed thelandslide potential that existed during the 1980 Irpinian earthquake in the Upper Sele river Valley.The standard Newmark displacement analysis, widely used for predicting the location of shallowunstable slopes, does not take into account errors and/or uncertainties in the input parameters.Therefore, a probabilistic Newmark displacement analysis technique has been used. Probabilistictechniques allow, e.g., an estimation of the probability that a slope will exceed a certain criticalvalue of Newmark displacement. In our probabilistic method, a Monte-Carlo based simulation modelis used in conjunction with a GIS. The random variability of geotechnical data is modelled by probabilitydensity functions (pdfs), while for the seismic input three different regression laws wereconsidered. Input probability distributions are sampled and the resulting values input into empiricalrelations for estimating Newmark displacement. The outcome is a map in which to each siteis related a spatial probability distribution for the expected displacement in response to seismic loading.Results of the experiments show a high grade of uncertainty in the application of the Newmarkanalysis both for the deterministic and probabilistic approach in a complex geological setting suchas the high Sele valley, quite common in the Southern Apennines. They show a strong dependence onthe reliability of the spatial data used in input, so that, when the model is used at basin scale,results are strongly influenced by local environmental condition (e.g., topography, lithology, groundwatercondition) and decrease the model performance.  相似文献   

DNAPL Characterization Methods and Approaches, Part 2: Cost Comparisons   总被引：1，自引：1，他引：1  

Mark L. Kram  Arturo A. Keller  Joseph Rossabi  Lome G. Everett 《Ground Water Monitoring & Remediation》2002,22(1):46-61

Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, pose environmental threats to ground water resources worldwide. DNAPL site characterization method performance comparisons are presented in a companion paper (Kram et al. 2001). This study compares the costs for implementing various characterization approaches using synthetic unit model scenarios (UMSs), each with particular physical characteristics. Unit costs and assumptions related to labor, equipment, and consumables are applied to determine costs associated with each approach for various UMSs. In general, the direct-push sensor systems provide cost-effective characterization information in soils that are penetrable with relatively shallow (less than 10 to 15 m) water tables. For sites with impenetrable lithology using direct-push techniques, the Ribbon NAPL Sampler Flexible Liner Underground Technologies Everting (FLUTe) membrane appears to be the most cost-effective approach. For all scenarios studied, partitioning interwell tracer tests (PITTs) are the most expensive approach due to the extensive pre-and post-PITT requirements. However, the PITT is capable of providing useful additional information, such as approximate DNAPL saturation, which is not generally available from any of the other approaches included in this comparison.  相似文献   

Economic Filters Applied to Quantitative Mineral Resource Simulations     

Joseph S. Duval 《Natural Resources Research》2003,12(2):121-126

The U.S. Geological Survey has developed a technique that allows mineral resource experts to apply economic filters to estimates of undiscovered mineral resources. This technique builds on previous work that developed quantitative methods for mineral resource assessments. A Monte-Carlo calculation uses mineral deposit models to estimate commodity grades and tonnages of undiscovered deposits. The results then are analyzed using simple estimates of capital expenditures and daily operating costs for a mine and associated mill. The daily operating costs and the value of the ore are used to calculate the net present value of the deposit, which is compared to the capital expenditures to determine whether the deposit is economic. Repetition of these calculations for many deposits produces a table that can be interpreted in terms of the probability of there being deposits that have anet present value exceeding some specified amount. Sample calculations indicate that applying economic filters to simulated mineral resources might change the perception of the results compared to presenting the calculations in terms of the expected mean gross-in-place value of the minerals.  相似文献   

High spatial resolution hyperspectral mapping of in-stream habitats, depths, and woody debris in mountain streams     

W. Andrew Marcus  Carl J. Legleiter  Richard J. Aspinall  Joseph W. Boardman  Robert L. Crabtree 《Geomorphology》2003,55(1-4):363

This article evaluates the potential of 1-m resolution, 128-band hyperspectral imagery for mapping in-stream habitats, depths, and woody debris in third- to fifth-order streams in the northern Yellowstone region. Maximum likelihood supervised classification using principal component images provided overall classification accuracies for in-stream habitats (glides, riffles, pools, and eddy drop zones) ranging from 69% for third-order streams to 86% for fifth-order streams. This scale dependency of classification accuracy was probably driven by the greater proportion of transitional boundary areas in the smaller streams. Multiple regressions of measured depths (y) versus principal component scores (x₁, x₂,…, x_n) generated R² values ranging from 67% for high-gradient riffles to 99% for glides in a fifth-order reach. R² values were lower in third-order reaches, ranging from 28% for runs and glides to 94% for pools. The less accurate depth estimates obtained for smaller streams probably resulted from the relative increase in the number of mixed pixels, where a wide range of depths and surface turbulence occurred within a single pixel. Matched filter (MF) mapping of woody debris generated overall accuracies of 83% in the fifth-order Lamar River. Accuracy figures for the in-stream habitat and wood mapping may have been misleadingly low because the fine-resolution imagery captured fine-scale variations not mapped by field teams, which in turn generated false “misclassifications” when the image and field maps were compared.The use of high spatial resolution hyperspectral (HSRH) imagery for stream mapping is limited by the need for clear water to measure depth, by any tree cover obscuring the stream, and by the limited availability of airborne hyperspectral sensors. Nonetheless, the high accuracies achieved in northern Yellowstone streams indicate that HSRH imagery can be a powerful tool for watershed-wide mapping, monitoring, and modeling of streams.  相似文献   

A methane fuse for the Cambrian explosion: carbon cycles and true polar wander   总被引：1，自引：0，他引：1  

Joseph L. Kirschvink  Timothy D. Raub 《Comptes Rendus Geoscience》2003,335(1):65-78

The dramatic diversification of animal groups known as the Cambrian Explosion (evolution's ‘Big Bang’) remains an unsolved puzzle in Earth Science. The Vendian–Cambrian interval is characterized by anomalously high rates of apparent plate motion, interpreted as True Polar Wander (TPW), and by more than a dozen large, high-frequency perturbations in carbon isotopes that dwarf all others observed through the past 65 million years. We suggest that these biological, tectonic, and geochemical events are intimately related in the following fashion. First, tropical continental margins and shelf-slopes which formed during fragmentation of the supercontinent Rodinia accumulated massive quantities of isotopically-light organic carbon during Late Neoproterozoic time, as indicated by strikingly heavy isotope ratios in inorganic carbon during interglacial intervals. Second, an initial phase of Vendian TPW moved these organic-rich deposits to high latitude, where conditions favored trapping biogenic methane in layers of gas hydrate and perhaps permafrost. Continued sedimentation during Late Vendian time added additional hydrate/gas storage volume and stabilized underlying units until the geothermal gradient moved them out of the clathrate stability field, building up deep reservoirs of highly pressurized methane. Finally, a burst of TPW brought these deposits back to the Tropics, where they gradually warmed and were subjected to regional-scale thermohaline eddy variation and related sedimentation regime changes. Responding to the stochastic character of such changes, each reservoir reached a critical failure point independently at times throughout the Cambrian. By analogy with the Late Paleocene Thermal Maximum event, these methane deposits yield transient, greenhouse-induced pulses of global warming when they erupt. Temperature correlates powerfully with biodiversity; the biochemical kinetics of metabolism at higher temperature decrease generation time and maintain relatively rich and dense invertebrate populations. Repeated thermal pulses along with progressive disruption and alteration of global ocean circulation patterns by TPW could cause the increase in diversity that accompanied the radiation of metazoans. We suggest that a methane ‘fuse’ ignited the Cambrian Evolutionary Explosion.  相似文献