Evaluation of cosmogenic 3He and 21Ne production rates in olivine and pyroxene from two Pleistocene basalt flows,western Grand Canyon,AZ, USA     

Cassandra R. Fenton  Samuel Niedermann  Mirjam M. Goethals  Björn Schneider  Jan Wijbrans 《Quaternary Geochronology》2009,4(6):475-492

Combining cosmogenic ³He and ²¹Ne (³He_c and ²¹Ne_c) measurements on both pyroxene and olivine from the Pleistocene Bar Ten flows (85–107 ka) greatly increases our ability to evaluate the accuracy of ³He_c and ²¹Ne_c production rates and, therefore, ³He_c and ²¹Ne_c surface exposure ages. Comparison of ³He_c and ²¹Ne_c age-pairs yielded by experimentally determined production rates and composition-based model calculations indicates that the former give more accurate surface exposure ages than the latter in this study. However, experimental production rates should be adjusted to the composition of the minerals being analyzed to obtain the best agreement between ³He_c and ²¹Ne_c ages for any given sample. ²¹Ne_c/³He_c values are 0.400 ± 0.029 and 0.204 ± 0.014 for olivine and pyroxene, respectively, in Bar Ten lava flows, in agreement with previously published values, and indicate that ²¹Ne_c/³He_c in olivine and pyroxene is not affected by erosion and remains constant with latitude, elevation, and time (up to 10 Myr). Samples with ²¹Ne_c/³He_c that do not agree with these values may indicate the presence of non-cosmogenic helium and/or neon. The neon three-isotope diagram can also indicate whether or not all excess neon in mineral separates comes from cosmogenic sources. An error-weighted regression for olivine defines a spallation line [y = (1.033 ± 0.031)x + (0.09876 ± 0.00033)], which is indistinguishable from that for pyroxene (Schäfer et al., 1999). We have derived a production rate of 25 ± 8 at/g/yr for ²¹Ne_c in clinopyroxene (En_43–44) based on the ⁴⁰Ar/³⁹Ar age of the upper Bar Ten flow. Our study indicates that the production rate of ²¹Ne_c in olivine may be slightly higher than previously determined. Cosmogenic ³He and ²¹Ne remain extremely useful, particularly when paired, in determining accurate eruption ages of young olivine- and pyroxene-rich basaltic lava flows.  相似文献   

The seasonal cycle in coupled ocean-atmosphere general circulation models   总被引：1，自引：0，他引：1  

C. Covey  A. Abe-Ouchi  G. J. Boer  B. A. Boville  U. Cubasch  L. Fairhead  G. M. Flato  H. Gordon  E. Guilyardi  X. Jiang  T. C. Johns  H. Le Treut  G. Madec  G. A. Meehl  R. Miller  A. Noda  S. B. Power  E. Roeckner  G. Russell  E. K. Schneider  R. J. Stouffer  L. Terray  J.-S. von Storch 《Climate Dynamics》2000,16(10-11):775-787

We examine the seasonal cycle of near-surface air temperature simulated by 17 coupled ocean-atmosphere general circulation models participating in the Coupled Model Intercomparison Project (CMIP). Nine of the models use ad hoc “flux adjustment” at the ocean surface to bring model simulations close to observations of the present-day climate. We group flux-adjusted and non-flux-adjusted models separately and examine the behavior of each class. When averaged over all of the flux-adjusted model simulations, near-surface air temperature falls within 2?K of observed values over the oceans. The corresponding average over non-flux-adjusted models shows errors up to ～6?K in extensive ocean areas. Flux adjustments are not directly applied over land, and near-surface land temperature errors are substantial in the average over flux-adjusted models, which systematically underestimates (by ～5?K) temperature in areas of elevated terrain. The corresponding average over non-flux-adjusted models forms a similar error pattern (with somewhat increased amplitude) over land. We use the temperature difference between July and January to measure seasonal cycle amplitude. Zonal means of this quantity from the individual flux-adjusted models form a fairly tight cluster (all within ～30% of the mean) centered on the observed values. The non-flux-adjusted models perform nearly as well at most latitudes. In Southern Ocean mid-latitudes, however, the non-flux-adjusted models overestimate the magnitude of January-minus-July temperature differences by ～5?K due to an overestimate of summer (January) near-surface temperature. This error is common to five of the eight non-flux-adjusted models. Also, over Northern Hemisphere mid-latitude land areas, zonal mean differences between July and January temperatures simulated by the non-flux-adjusted models show a greater spread (positive and negative) about observed values than results from the flux-adjusted models. Elsewhere, differences between the two classes of models are less obvious. At no latitude is the zonal mean difference between averages over the two classes of models greater than the standard deviation over models. The ability of coupled GCMs to simulate a reasonable seasonal cycle is a necessary condition for confidence in their prediction of long-term climatic changes (such as global warming), but it is not a sufficient condition unless the seasonal cycle and long-term changes involve similar climatic processes. To test this possible connection, we compare seasonal cycle amplitude with equilibrium warming under doubled atmospheric carbon dioxide for the models in our data base. A small but positive correlation exists between these two quantities. This result is predicted by a simple conceptual model of the climate system, and it is consistent with other modeling experience, which indicates that the seasonal cycle depends only weakly on climate sensitivity.  相似文献   

Reservoir sediments – a witness of mining and industrial development (Malter Reservoir, eastern Erzgebirge, Germany)     

J. Müller  H. Ruppert  Y. Muramatsu  J. Schneider 《Environmental Geology》2000,39(12):1341-1351

The Malter Reservoir is situated about 30 km south of Dresden (eastern Germany) in a historical mining area of the eastern Erzgebirge. It was built in 1913 for the protection from floodwaters, droughts and for generating electricity. The river Rote Wei?eritz is the main source of clastic input into the lake. Geochemical and sedimentological data of gravity-and piston-cores, recovered from the deepest point of the lake, document the environmental history of the drainage area since 1963. ¹³⁷Cs dating gives an average sedimentation rate of ∼2.9 cm/year. Within the whole core, heavy metals are strongly enriched (parentheses refer to enrichment factors as compared with average shale): cadmium (290), silver (140), bismuth (90), antimony (25), lead (21), zinc (14), tin (13), uranium (9), tungsten (9), molybdenum (5), copper (4), thallium (3) and chromium (2). Enrichments are detectable for the whole registered time-period of 81 years. Peaks of up to 27 mg/kg silver, 37 mg/kg bismuth, 91 mg/kg cadmium, 410 mg/kg chromium, 240 mg/kg copper, 20 mg/kg molybdenum, 14000 mg/kg phosphorus, 740 mg/kg lead, 6,5 mg/kg antimony, 74 mg/kg tin, 52 mg/kg tungsten and 1900 mg/kg zinc reflect local events caused by human impact. Inputs from different pollution sources at different times are represented by highly variable elemental concentrations and ratios within the core. High pH values within the water and the sediment column, the large adsorption capacity of the fine-grained C_org.-rich sediment, and the presence of low Eh-values and sulphide ions in the sediment prevent the remobilisation of the toxic elements. Erosion of these contaminated sediments during floods, channel flows or resuspension during removal of the sediments may lead to a downstream transfer of pollutants. Contents of P and C_org., as well as diatom abundance, indicate a change from oligotrophic to eutrophic conditions in the lake during ∼1940–1950. This was mainly caused by high agricultural activity in the drainage area. Reduced contents of Cu, Zn, Cd and Cr since the reunification of East and West Germany are obviously caused by increasing environmental protection measures, such as wastewater purification and especially the closing of contaminating industries. Revision received: 23 September 1999 · Accepted: 17 December 1999  相似文献   

Atmospheric Pb and Cd input into the Baltic Sea: a new estimate based on measurements     

B. Schneider  D. Ceburnis  R. Marks  J. Munthe  G. Petersen  M. Sofiev 《Marine Chemistry》2000,71(3-4)

Bulk deposition samples were collected during a summer (1997) and a winter (1998) measurement campaign at four coastal stations along the southern Baltic Sea coast and on the Island of Gotland. The data were used to construct Pb and Cd deposition fields over the Baltic Sea. A weak gradient with decreasing deposition rates from the southwest towards the east and north was obtained for Pb. In the case of Cd, the spatial distribution pattern was characterized by an extreme deposition maximum at the Polish station on the Hel Peninsula. The total atmospheric input of Pb and Cd into the Baltic Sea was 550 and 33 t/year, respectively, and exceeds the riverine input by approximately about 50%. Previous measurement-based estimates were higher by a factor 2–3 and indicate a decrease of the atmospheric deposition during the past 10–15 years. The comparison with modelled deposition data yielded partly large differences and was impaired by the fact that 1990 emission inventories were used whereas our measurements were performed in 1997/1998.Relating our deposition estimate and the Pb/Cd input by rivers to the mean concentrations in Baltic Sea water, residence times of 0.29 and 3.6 years were obtained for Pb and Cd, respectively.  相似文献   

Shock waves—Phenomenology,experimental, and numerical simulation     

Klaus Thoma  Ulrich Hornemann  Martin Sauer  Eberhard Schneider 《Meteoritics & planetary science》2005,40(9-10):1283-1296

Abstract— The purpose of this paper is to review the results of long‐term cooperation between Dieter Stöffler and the authors in the field of shock wave deformation of minerals and rocks. First, the principal phenomena of shock wave generation and propagation, predominantly in solid media, are presented, and then analytical and numerical mathematical treatment of shock wave processes on the basis of mass, momentum, and energy conservation laws will be described and discussed. Experimental methods of shock wave investigations by means of impact and explosive techniques are summarized, including hypervelocity acceleration facilities and high‐pressure explosive devices. Shock pressure barometry by means of mineralogical evidence of distinct material phase transitions and characteristic shock structures is also discussed.  相似文献   

The two micron all sky survey     

S. G. Kleinmann  M. G. Lysaght  W. L. Pughe  S. E. Schneider  M. F. Skrutskie  M. D. Weinberg  S. D. Price  K. Y. Matthews  B. T. Soifer  J. P. Huchra  C. A. Beichman  T. J. Chester  T. Jarrett  G. L. Kopan  C. J. Lonsdale  J. Elias  J. W. Liebert  P. Seitzer 《Experimental Astronomy》1994,3(1-4):65-72

This paper describes the design, expectations, and prototyping of a new allsky survey, called 2MASS (Two Micron All Sky Survey) to be carried out with the new generation of infrared array detectors.  相似文献   

A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance   总被引：8，自引：0，他引：8  

Artur P. Deditius  Udo Becker  Stephen E. Kesler 《Geochimica et cosmochimica acta》2008,72(12):2919-2933

This report describes a new form of arsenian pyrite, called As³⁺-pyrite, in which As substitutes for Fe [(Fe,As)S₂], in contrast to the more common form of arsenian pyrite, As¹⁻-pyrite, in which As¹⁻ substitutes for S [Fe(As,S)₂]. As³⁺-pyrite has been observed as colloformic overgrowths on As-free pyrite in a hydrothermal gold deposit at Yanacocha, Peru. XPS analyses of the As³⁺-pyrite confirm that As is present largely as As³⁺. EMPA analyses show that As³⁺-pyrite incorporates up to 3.05 at % of As and 0.53 at. %, 0.1 at. %, 0.27 at. %, 0.22 at. %, 0.08 at. % and 0.04 at. % of Pb, Au, Cu, Zn, Ni, and Co, respectively. Incorporation of As³⁺ in the pyrite could be written like: As³⁺+yAu⁺+1-y(□)⇔2Fe²⁺; where Au⁺ and vacancy (□) help to maintain the excess charge. HRTEM observations reveal a sharp boundary between As-free pyrite and the first overgrowth of As³⁺-pyrite (20-40 nm thick) and co-linear lattice fringes indicating epitaxial growth of As³⁺-pyrite on As-free pyrite. Overgrowths of As³⁺-pyrite onto As-free pyrite can be divided into three groups on the basis of crystal size, 8-20 nm, 100-300 nm and 400-900 nm, and the smaller the crystal size the higher the concentration of toxic arsenic and trace metals. The Yanacocha deposit, in which As³⁺-pyrite was found, formed under relatively oxidizing conditions in which the dominant form of dissolved As in the stability field of pyrite is As³⁺; in contrast, reducing conditions are typical of most environments that host As¹⁻-pyrite. As³⁺-pyrite will likely be found in other oxidizing hydrothermal and diagenetic environments, including high-sulfidation epithermal deposits and shallow groundwater systems, where probably kinetically controlled formation of nanoscale crystals such as observed here would be a major control on incorporation and release of As³⁺ and toxic heavy metals in oxidizing natural systems.  相似文献   

Soil Carbon: Policy and Economics   总被引：4，自引：2，他引：4  

Gregg Marland  Bruce A. McCarl  Uwe Schneider 《Climatic change》2001,51(1):101-117

Agricultural soils provide a prospective way of mitigating the increasing atmospheric concentration of CO₂. A number of agricultural practices are known to stimulate the accumulation of additional soil carbon and early indications are that some might sequester carbon at relatively modest costs with generally positive environmental effects. We discuss, under 10 themes, policy and economic issues that will determine whether programs for sequestration of carbon in agricultural soils can succeed. The issues involve contexts for implementation, economics, private property rights, agricultural policy, and institutional and social structures. Ultimately, success will depend on the incentive structure developed and the way in which carbon sequestration is integrated into the total fabric of agricultural policy.  相似文献   

Phenomenon-based Specification of the Digital Representation of Terrain Surfaces     

Bernhard Schneider 《Transactions in GIS》2001,5(1):39-52

The phenomenon known as 'terrain' is a continuous surface. However, when a digital terrain representation is based on a regular raster (i.e. a DEM) the digital surface is commonly not continuous. This is the case for the derivation of variables such as slope, aspect, and curvature values as performed in today's Geographic Information Systems (GIS). Often, there is no surface specified at all, as, for instance, when flow lines or watersheds are constructed. The discrepancy between the phenomenon to be modelled and its digital representation causes the terrain analysis results to be less accurate than they could be. Furthermore, if more than one type of terrain information is derived the results are likely to be based on different specifications of the seemingly same terrain surface. The combined application of the derivation results will likely introduce inconsistencies. This paper suggests founding the specification of digital terrain representations on a careful analysis of the properties of the phenomenon. The paper details the reasons for, and advantages of, continuous surface representations and emphasises the importance of a comprehensive documentation of the conceptual models underlying digital terrain representations. A review of suitable interpolation approaches for the specification of terrain surfaces is given. The paper discusses how the resulting digital surfaces are analysed and how measurement uncertainty may be accounted for.  相似文献   

The geology of the Lega Dembi gold deposit, southern Ethiopia: implications for Pan-African gold exploration     

A. Y. Billay  A. F. M. Kisters  F. M. Meyer  J. Schneider 《Mineralium Deposita》1997,32(5):491-504

The Lega Dembi deposit is the largest gold producer in Ethiopia. It is situated in late-Precambrian metamorphosed sediments of the N-S trending, volcano-sedimentary Megado belt, which forms part of the late-Proterozoic Adola granite-greenstone terrane in southern Ethiopia. The lode-gold mineralization occurs in a N-S trending, steep westerly dipping quartz-vein system that follows the structural contact between underlying feldspathic gneisses and the volcanosedimentary sequence of the Megado belt. This contact also marks the northernmost extension of the regional-scale, sinistral strike-slip Lega Dembi-Aflata shear zone. Mineralization and intense quartz-veining is best developed in graphite-rich sediments within an area not more than 80 m away from this tectonic contact. Hydrothermal wall-rock alteration includes actinolite/tremolite-biotite-calcite-sericite and chlorite-calcite-epidote assemblages. Gold occurs preferentially in the sericite alteration zone, where it is closely associated and intergrown with galena. The variable deformation of the gold-quartz veins suggests a syn-kinematic timing for the gold mineralization during transcurrent shearing in a dilational segment of the shear zone. In addition to the structural control, lithological control on gold deposition is indicated by the almost exclusive occurrence of the gold mineralization in graphite-rich metasediments. This close relationship suggests that gold precipitation was the result of chemical reduction of regional ore-bearing fluids. Temperature conditions of mineralization are constrained by the actinolite-biotite alteration assemblage and by arsenopyrite chemistry, which indicate that ore deposition occurred at or close to peak metamorphic conditions at upper-greenschist to lower-amphibolite metamorphic grades. Rb-Sr dating of sericite indicates an age of about 545 Ma. for hydrothermal alteration and, thus, for gold mineralization. The style of gold mineralization, structural pattern and lithological assemblages at Lega Dembi are very similar to lode-gold deposits most commonly reported from Archaean granite-greenstone terranes. These similarities may open new perspectives for the exploration of lode-gold deposits, which has previously primarily focused on Archaean greenstone belts rather than Proterozoic or even Phanerozoic meta-volcanosedimentary belts. Received: 26 July 1996 / Accepted: 8 January 1997  相似文献