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Edwin K. Schneider 《Annales Geophysicae》1996,14(3):336-341
A flaw is pointed out in the manner in which flux correction is currently applied to coupled atmosphere-ocean general circulation models. If a transient climate simulation were carried out using perfect initial data and a perfect model, then a perfect simulation would be made. However, if the model were flux corrected so that it is in equilibrium for current conditions, according to current practice, then errors in the simulation would grow initially to a finite amplitude and persist indefinitely. Larger errors would be produced by a simulation with the flux corrected model beginning from pre-industrial conditions than by a simulation beginning from current conditions. An example with a simple linear model is constructed to illustrate this point, and the relationship to the cold start problem is demonstrated. An optimal flux correction for the simple example is shown to be one which would eliminate the error in the current climate from a transient simulation begun sufficiently far in the past. 相似文献
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Analysis of the historical record shows that reductions in guano production in the eastern tropical Atlantic Ocean were not related to El Niño events in the Pacific. Guano production in the Atlantic was negatively correlated with guano production in the Pacific. Significant reductions in guano production in the Atlantic occurred 1 to 4 years after increases in guano production in the Pacific. Negative association is consistent with the hypothesis that global shifts in weather associated with the Southern Oscillation affect guano production. 相似文献
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Single crystals of quartz, shock-loaded along the a axis to pressures of 22 Gpa, 24 GPa, 26 GPa and 30 GPa were examined by high-voltage transmission electron microscopy (TEM), scanning electron microscopy (SEM) and X-ray diffraction. Asymmetric broadenings of X-ray lines indicate spatial inhomogeneity of shock effects. X-ray streaking angles in the reciprocal lattice planes h0 \(\bar h\) l, 0k \(\bar k\) l and hki0 indicate a slight tilting deformation by rotation about [00.1] in (0001). TEM reveals glass lamellae which are mostly in (01 \(\bar 1\) 2) orientation, and are correlated with optical planar elements and with surface steps seen in SEM. No dislocations are found. There are (0001) lamellar features, probably Brazil twins. The (01 \(\bar 1\) 2) glass lamellae develop directly from bands of quartz in which intense deformation has produced a fine-scale lamellar to blocky structure, possibly also originating by twinning. Relics of crystalline structure are found in almost completely vitrified lamellae. Stishovite occurs in heavily deformed parts of the 22 GPa and 24 GPa specimens, in patches of densified glass distinct from the sharply bounded lamellae. The nucleationless, pervasive transformation of lamellae to glass, with preservation of their sharp boundaries, is attributed to defect coalescence analogous to vitrification by radiation damage (metamictization). Some patchy glass may be due to melting. 相似文献
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The trioctahedral mica ephesite, Na(LiAl2) [Al2Si2O10] (OH)2, has a large
-T stability field in the quaternary system NaAlSiO4-LiAlSiO4-Al2O3-H2O. At temperatures below 400–500° C it coexists with diaspore, while at higher temperatures it occurs with corundum, until it decomposes to nepheline +eucryptite+corundum+H2O at 600–800° C (Fig. 1). Nature faithfully reflects these phase relations; ephesite is found to coexist with diaspore or corundum in silicadeficient metamorphosed rocks or in hydrothermally altered nepheline-syenite pegmatite.Thermodynamic analysis of phase relations of ephesite in the silica saturated portion of the quinary system NaAlSiO4-LiAlSiO4-Al2O3-SiO2-H2O shows that the assemblage quartz+ephesite is always metastable with respect to paragonite+spodumene or paragonite+petalite at temperatures down to approximately 300° C (Fig. 3). At lower temperatures, a number of other phases like bikitaite, cookeite, Na-montmorillonite, and analcime are stabilized. Stability and compatibility relations involving these phases are presently not amenable to thermodynamic treatment due to lack of suitable data. Nevertheless, the absence of the assemblage quartz+ephesite in nature seems to vindicate our conclusion that it is metastable down to at least 300° C.The frequently encountered assemblage quartzspodumene (or petalite)-microcline-albite of some lithium pegmatites contains muscovite (±lepidolite), rather than paragonite. The absence of paragonite in such rocks is best explained by the inherent metastability of the phase-pair paragonite+microcline with respect to muscovite+albite. The pegmatite bulk compositions plot in the four-phase field spodumene (petalite)-microcline-muscovite-albite, cutting out paragonite from the observed assemblage Thus, absence of paragonite-spodumene or paragonitepetalite in nature reflects lack of suitable bulk compositions in rocks. 相似文献