Geostandards and Geoanalytical Research Bibliographic Review 2009     

Klaus P. Jochum  Xiaohong Wang  Regina Mertz-Kraus  Uwe Nohl  Steffen Schmidt  Beate Schwager  Brigitte Stoll  Qichao Yang  Ulrike Weis 《Geostandards and Geoanalytical Research》2010,34(4):407-410

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A combined paleolimnological/genetic analysis of diatoms reveals divergent evolutionary lineages of Staurosira and Staurosirella (Bacillariophyta) in Siberian lake sediments along a latitudinal transect     

Kathleen R. Stoof-Leichsenring  Nadine Bernhardt  Luidmila A. Pestryakova  Laura S. Epp  Ulrike Herzschuh  Ralph Tiedemann 《Journal of Paleolimnology》2014,52(1-2):77-93

Diatom diversity in lakes of northwest Yakutia (Siberia) was investigated by microscopic and genetic analysis of surface and cored lake sediments, to evaluate the use of sedimentary DNA for paleolimnological diatom studies and to identify obscure genetic diversity that cannot be detected by microscopic methods. Two short (76 and 73 bp) and one longer (577 bp) fragments of the ribulose 1,5-bisphosphate carboxylase/oxygenase (rbcL) gene, encoding the large subunit of the rbcL, were used as genetic markers. Diverse morphological assemblages of diatoms, dominated by small benthic fragilarioid taxa, were retrieved from the sediments of each lake. These minute fragilarioid taxa were examined by scanning electron microscopy, revealing diverse morphotypes in Staurosira and Staurosirella from the different lakes. Genetic analyses indicated a dominance of haplotypes that were assigned to fragilarioid taxa and less genetic diversity in other diatom taxa. The long rbcL_577 amplicon identified considerable diversification among haplotypes clustering within the Staurosira/Staurosirella genera, revealing 19 different haplotypes whose spatial distribution appears to be primarily related to the latitude of the lakes, which corresponds to a vegetation and climate gradient. Our rbcL markers are valuable tools for tracking differences between diatom lineages that are not visible in their morphologies. These markers revealed putatively high genetic diversity within the Staurosira/Staurosirella species complex, at a finer scale than is possible to resolve by microscopic determination. The rbcL markers may provide additional reliable information on the diversity of barely distinguishable minute benthic fragilarioids. Environmental sequencing may thus allow the tracking of spatial and temporal diversification in Siberian lakes, especially in the context of diatom responses to recent environmental changes, which remains a matter of controversy.  相似文献   

Inter-laboratory comparison of oxygen isotope compositions from biogenic silica     

Bernhard Chapligin  Melanie J. Leng  Anne Alexandre  Akira Ijiri  Aldo Shemesh  Ulrike Herzschuh  Hanno Meyer  Yusuke Okazaki  Zachary D. Sharp  Corinne Sonzogni  Florence Sylvestre  Ruth Yam 《Geochimica et cosmochimica acta》2011,75(22):7242-7256

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.  相似文献   

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination     

Klaus Peter Jochum  Steven A. Wilson  Wafa Abouchami  Marghaleray Amini  Jérome Chmeleff  Anton Eisenhauer  Ernst Hegner  Linda M. Iaccheri  Bruno Kieffer  Joachim Krause  William F. McDonough  Regina Mertz‐Kraus  Ingrid Raczek  Roberta L. Rudnick  Denis Scholz  Grit Steinhoefel  Brigitte Stoll  Andreas Stracke  Sonia Tonarini  Dominique Weis  Ulrike Weis  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines     

Klaus Peter Jochum  Ulrike Weis  Brigitte Stoll  Dmitry Kuzmin  Qichao Yang  Ingrid Raczek  Dorrit E. Jacob  Andreas Stracke  Karin Birbaum  Daniel A. Frick  Detlef Günther  Jacinta Enzweiler 《Geostandards and Geoanalytical Research》2011,35(4):397-429

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.  相似文献   

Listric versus planar normal fault geometry: an example from the Eisenstadt-Sopron Basin (E Austria)   总被引：1，自引：0，他引：1  

Darko Spahić  Ulrike Exner  Michael Behm  Bernhard Grasemann  Alexander Haring  Herbert Pretsch 《International Journal of Earth Sciences》2011,100(7):1685-1695

In a gravel pit at the eastern margin of the Eisenstadt-Sopron Basin, a satellite of Vienna Basin (Austria), Neogene sediments are exposed in the hanging wall of a major normal fault. The anticlinal structure and associated conjugated secondary normal faults were previously interpreted as a rollover anticline above a listric normal fault. The spatial orientation and distribution of sedimentary horizons and crosscutting faults were mapped in detail on a laser scan of the outcrop wall. Subsequently, in order to assess the 3D distribution and geometry of this fault system, a series of parallel ground penetrating radar (GPR) profiles were recorded behind the outcrop wall. Both outcrop and GPR data were compiled in a 3D structural model, providing the basis for a kinematic reconstruction of the fault plane using balanced cross-section techniques. However, the kinematic reconstruction results in a geologically meaningless normal fault cutting down- and up-section. Additionally, no evidence for a weak layer serving as ductile detachment horizon (i.e. salt or clay horizon) can be identified in stratigraphic profiles. Instead, the observed deflection of stratigraphic horizons may be caused by a displacement gradient along a planar master fault, with a maximum displacement in the fault centre, decreasing towards the fault tips. Accordingly, the observed deflection of markers in the hanging wall—and in a nearby location in the footwall of the normal fault—is interpreted as large-scale fault drag along a planar fault that records a displacement gradient, instead of a rollover anticline related to a listric fault.  相似文献   

Single-crystal structure and Raman spectroscopy of synthetic titanite analog CaAlSiO<Subscript>4</Subscript>F     

Hannes Krüger  Daniel M. Többens  Peter Tropper  Udo Haefeker  Volker Kahlenberg  Martin R. Fuchs  Vincent Olieric  Ulrike Troitzsch 《Mineralogy and Petrology》2015,109(5):631-641

Synthetic CaAlSiO₄F, the Al-F analog of titanite, has been investigated using single-crystal synchrotron diffraction experiments at Beamline X06DA (Swiss Light Source, Paul Scherrer Institute, Villigen, Switzerland) and Raman spectroscopy. The presented structural model with 40 parameters was refined against 506 unique reflections to a final R _{o b s} of 0.026 (space group A2/a, a = 6.9120(11), b = 8.5010(10), c = 6.435(2) Å, β = 114.670(11)°, and Z = 4) and exhibits less distorted coordination polyhedra than earlier models from powder data. Vibrational spectra were calculated in harmonic approximation at the Γ point from fully relaxed energy optimisations of the crystal structure, using 3D-periodic density functional theory with Gaussian basis sets and the software CRYSTAL06. The lattice parameters of the fully relaxed structure were in good agreement with the experimental values, with the calculated values 0.8 ± 0.4 % too large; the monoclinic angle was calculated 0.4° too large. The agreement of the calculated Raman frequencies with the observed ones was very good, with standard deviation ±3 cm^?1 and maximum deviations of ±7 cm^?1. Furthermore, a detailed discussion of the atomic displacements associated with each Raman mode is given.  相似文献   

Erratum to: Investigation of the geochemical impact of CO2 on shallow groundwater: design and implementation of a CO2 injection test in Northeast Germany     

Anita Peter  Hendrik Lamert  Matthias Beyer  Götz Hornbruch  Ben Heinrich  Alexandra Schulz  Helmut Geistlinger  Bernd Schreiber  Peter Dietrich  Ulrike Werban  Carsten Vogt  Hans-Hermann Richnow  Jochen Großmann  Andreas Dahmke 《Environmental Earth Sciences》2013,69(6):2123-2123

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Modification of climate signals by human activities recorded in varved sediments (AD 1608–1942) of Lake Holzmaar (Germany)     

Ulrike Kienel  Heinz Vos  Peter Dulski  Andreas Lücke  Robert Moschen  Norbert R. Nowaczyk  Markus J. Schwab 《Journal of Paleolimnology》2013,50(4):561-575

Paleolimnological data from varved sediments in Lake Holzmaar (Eifel, Germany) were combined with documentary data on human activities, long-term data from the Historical Climate Database (HISKLID) for Germany and with recent monitoring data to evaluate changes in deposition that arose from climatic and human influences. The sediment data included seasonal layer thickness in an established varve chronology (1608–1942 AD), subannual chemical element counts, and multiannual organic matter data (TOC, TN, δ¹³C_org), all combined on an annual scale. Indicators for detritus deposition (lithogenic element counts and detritus layers) determined the first principal component (PC1) of the sediment data. This detritus PC1 was compared to the first PCs of the seasonal precipitation and temperature from HISKLID. While no relation was found to precipitation, the correlation with the temperature PC1 determined by spring to fall temperatures was significant. From 1608 to 1870, a positive correlation of the PCs suggests an increase of detritus deposition in the lake center with increasing non-winter temperatures. These may be linked by lake-internal sediment redeposition that increases when the periods of winter stratification become shorter and that of lake circulation longer. The detritus deposition is modulated by external detritus input depending on the intensity of erosion-conducive land use (wood pasture, wood cutting, and rotational slash-and-burn cultivation). Detritus input diminished when land use slowed down with population decrease as the consequence of plague epidemics, warfare and emigration. After 1870, forest regeneration and improving agricultural practices led to a stabilization of the catchment. Erosion and detritus deposition decreased progressively. The negative correlation of detritus deposition with the gradually increasing temperature presumably mimics a cause-effect relation, although a link with decreasing freeze–thaw action is possible. The modernization of agriculture proceeded with manuring and fertilizing, which caused an increase of lake productivity as indicated by summer blooms of diatoms with enhanced nutrient demand, increased δ¹³C_org values and sulfur concentrations. Within this well established data base we found combinations of criteria that may be used to deduce natural climatic or anthropogenic influences. The quantitative attribution of these influences remains a challenging task in paleolimnology because their interaction makes the detection of linking mechanisms difficult even at high degree of detail and the processes themselves remain debatable.  相似文献   

BAM‐S005 Type A and B: New Silicate Reference Glasses for Microanalysis     

Qi‐Chao Yang  Klaus Peter Jochum  Brigitte Stoll  Ulrike Weis  Dmitry Kuzmin  Michael Wiedenbeck  Heike Traub  Meinrat O. Andreae 《Geostandards and Geoanalytical Research》2012,36(3):301-313

To test whether the silicate reference glasses BAM‐S005‐A and BAM‐S005‐B from BAM (The Federal Institute for Materials Research and Testing, Germany) are suitable materials for microanalysis, we investigated the homogeneity of these reference glasses using the microanalytical techniques EPMA, LA‐ICP‐MS and SIMS. Our study indicated that all major and most trace elements are homogeneously distributed at micrometre sampling scale in both types of glass. However, some trace elements (e.g., Cs, Cl, Cr, Mo and Ni) seem to be inhomogeneously distributed. We also determined the composition of BAM‐S005‐A and BAM‐S005‐B. The EPMA data of major elements confirmed the information values specified by the certificate. With the exception of Sr, Ba, Ce and Pb, our trace element data by LA‐ICP‐MS were also in agreement with the certified values within the stated uncertainty limits. The reasons for the discrepancy in these four elements are still unclear. In addition, we report new data for twenty‐two further trace elements, for which the concentrations were not certified. Based on our investigation, we suggest that both of these materials are suitable for many microanalytical applications.  相似文献