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311.
Uwe R. Kackstaetter 《Central European Journal of Geosciences》2014,6(2):170-181
Normative mineralogical calculations from bulk geochemistry of sedimentary rocks are problematic because of variable depositional environments, particle hydraulics and sedimentary source systems. The development of SEDMIN, a Microsoft Excel? spreadsheet solution, is a practical attempt for a computational routine focusing specifically on smectite, chlorite, kaolinite, illite and the ambiguous sericite within various pelitic sedimentary lithologies. While in essence a mathematical approach, the use of statistical evaluation of empirical lithogeochemical data combined with modal analytical procedures yields reasonable geochemical associations, more precise chemical phases and revised procedural allotment paradigms. Thus, an algorithm using TiO2 as a key to the normative calculation of kaolinite is proposed. Incorporating additional parameters, such as LOI (Loss-on-ignition) in conjunction with carbon, sulfur, carbonate and sulfate, provides that clay phases can be more accurately determined than from bulk oxides alone. Even when presented with atypical sample data, the spreadsheet solution is able to accurately predict predominant clay minerals. Besides some drawbacks, the likely benefit from SEDMIN is the incorporation of results in classification norms and diagrams indicative of sedimentary lithologies. The ”SEDMIN Sedimentary Mineral Calculator.xlsx” spreadsheet can be freely downloaded from http://earthscienceeducation.net/SEDMINSedimentaryMineralCalculator.xlsx. 相似文献
312.
Claudio RICCOMINI Alvaro P. CRÓSTA Renato L. PRADO Marie‐Pierre LEDRU Bruno J. TURCQ Lucy G. SANT’ANNA José A. FERRARI W. Uwe REIMOLD 《Meteoritics & planetary science》2011,46(11):1630-1639
Abstract– The near‐circular Colônia structure, located in the southern suburbs of the mega‐city of São Paulo, Brazil, has attracted the attention of geoscientists for several decades due to its anomalous character and the complete absence of any plausible endogenous geologic explanation for its formation. Origin by impact cratering has been suggested repeatedly since the 1960s, but no direct evidence for this has been presented to date. New seismic data have been recently acquired at Colônia, providing new insights into the characteristics and possible layering of infill of the structure, as well as into the depth to the underlying basement. We review the current knowledge about the Colônia structure, present the new seismic data, and discuss the existing—as yet still indirect—evidence for a possible origin by an impact. The new data suggest the existence of a sedimentary fill of approximately 275 m thickness and also the presence of two intermediate zones between sediment and basement: an upper zone that is approximately 65 m thick and can be interpreted as a possible crater‐fill breccia, whereas the other zone possibly represents fractured/brecciated basement, with a thickness of approximately 50 m. Although this depth to basement seems to be inconsistent with the expected geometry of a simple, bowl‐shape impact structure of such diameter, there are a number of still unconstrained parameters that could explain this, such as projectile nature, size and velocity, impact angle, and particularly the current erosion depth. 相似文献
313.
The results presented in this paper on uranium in bottled and tap water were determined within the scope of the project “European Groundwater Geochemistry: Bottled Water” of the Geochemistry Expert Group of EuroGeoSurveys. The analyses of bottled water provide an inexpensive approach to obtain information about European groundwater geochemistry. For this study, the uranium concentrations in 1785 European mineral water samples were analyzed by ICP–QMS in the BGR laboratories. The dataset is used to obtain a first impression about natural concentration levels and variation of uranium in groundwater (and bottled water) at the German and European scale. 相似文献
314.
Juraj Majzlan Tamara Ðorđević Uwe Kolitsch Jürg Schefer 《Mineralogy and Petrology》2010,100(3-4):241-248
Using single-crystal X-ray diffraction at 293, 200 and 100 K, and neutron diffraction at 50 K, we have refined the positions of all atoms, including hydrogen atoms (previously undetermined), in the structure of coquimbite ( $ P {\bar 3}1c $ , a?=?10.924(2)/10.882(2) Å, c?=?17.086(3) / 17.154(3) Å, V?=?1765.8(3)/1759.2(5) Å3, at 293 / 50 K, respectively). The use of neutron diffraction allowed us to determine precise and accurate hydrogen positions. The O–H distances in coquimbite at 50 K vary between 0.98 and 1.01 Å. In addition to H2O molecules coordinated to the Al3+ and Fe3+ ions, there are rings of six “free” H2O molecules in the coquimbite structure. These rings can be visualized as flattened octahedra with the distance between oxygen and the geometric center of the polyhedron of 2.46 Å. The hydrogen-bonding scheme undergoes no changes with decreasing temperature and the unit cell shrinks linearly from 293 to 100 K. A review of the available data on coquimbite and its “dimorph” paracoquimbite indicates that paracoquimbite may form in phases closer to the nominal composition of Fe2(SO4)3·9H2O. Coquimbite, on the other hand, has a composition approximating Fe1.5Al0.5(SO4)3·9H2O. Hence, even a “simple” sulfate Fe2-x Al x (SO4)3·9H2O may be structurally rather complex. 相似文献