Quantitative elemental mapping of granulite-facies monazite: Textural insights and implications for petrochronology     

Owen M. Weller  Simon Jackson  William G. R. Miller  Marc R. St-Onge  Nicole Rayner 《Journal of Metamorphic Geology》2020,38(8):853-880

Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving P–T conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.  相似文献   

Seasonal extreme rainfall variability over India and its association with surface air temperature     

Sardana  Divya  Kumar  Prashant  Weller  Evan  Rajni 《Theoretical and Applied Climatology》2022,147(1-2):185-204

Theoretical and Applied Climatology - Spatial variability in catchment processes is crucial for hydrologic and water resources planning and management. The spatial density of ground-based rain...  相似文献   

Quantifying Barrovian metamorphism in the Danba Structural Culmination of eastern Tibet   总被引：3，自引：0，他引：3  

O. M. Weller  M. R. St‐Onge  D. J. Waters  N. Rayner  M. P. Searle  S.‐L. Chung  R. M. Palin  Y.‐H. Lee  X. Xu 《Journal of Metamorphic Geology》2013,31(9):909-935

The Danba Structural Culmination is a tectonic window into the late Triassic to early Jurassic Songpan‐Garzê Fold Belt of eastern Tibet, which exposes an oblique section through a complete Barrovian‐type metamorphic sequence. Systematic analysis of a suite of metapelites from this locality has enabled a general study of Barrovian metamorphism, and provided new insights into the early thermotectonic history of the Tibetan plateau. The suite was used to create a detailed petrographic framework, from which four samples ranging from staurolite to sillimanite grade were selected for thermobarometry and geochronology. Pseudosection analysis was applied to calculate P–T path segments and determine peak conditions between staurolite grade at ～5.2 kbar and 580 °C and sillimanite grade at ～6.0 kbar and 670 °C. In situ U–Pb monazite geochronology reveals that staurolite‐grade conditions were reached at 191.5 ± 2.4 Ma, kyanite‐grade conditions were attained at 184.2 ± 1.5 Ma, and sillimanite‐grade conditions continued until 179.4 ± 1.6 Ma. Integration of the results has provided constraints on the evolution of metamorphism in the region, including a partial reconstruction of the regional metamorphic field gradient. Several key features of Barrovian metamorphism are documented, including nested P–T paths and a polychronic field gradient. In addition, several atypical features are noted, such as P–T path segments having similar slopes to the metamorphic field gradient, and T_max and P_max being reached simultaneously in some samples. These features are attributed to the effects of slow tectonic burial, which allows for thermal relaxation during compression. While nested, clockwise P–T–t loops provide a useful framework for Barrovian metamorphism, this study shows that the effects of slow burial can telescope this model in P–T space. Finally, the study demonstrates that eastern Tibet experienced a significant phase of crustal thickening during the Mesozoic, reinforcing the notion that the plateau may have a long history of uplift and growth.  相似文献   

Nutrient flux in a landscape: Effects of coastal land use and terrestrial community mosaic on nutrient transport to coastal waters   总被引：1，自引：0，他引：1  

David L. Correll  Thomas E. Jordan  Donald E. Weller 《Estuaries and Coasts》1992,15(4):431-442

Long-term interdisciplinary studies of the Rhode River estuary and its watershed in the mid-Atlantic coastal plain of North America have measured fluxes of nitrogen and phosphorus fractions through the hydrologically-linked ecosystems of this landscape. These ecosystems are upland forest, cropland, and pasture; streamside riparian forests; floodplain swamps; tidal brackish marshes and mudflats; and an estuarine embayment. Croplands discharged far more nitrogen per hectare in runoff than did forests and pastures. However, riparian deciduous hardwood forest bordering the cropland removed over 80 percent of the nitrate and total phosphorus in overland flows and about 85 percent of the nitrate in shallow groundwater drainage from cropland. Nevertheless, nutrient discharges from riparian forests downslope from croplands still exceeded discharges from pastures and other forests. The atomic ratio of nitrogen to phosphorus discharged from the watersheds into the estuary was about 9 for total nutrients and 6 for inorganic nutrient fractions. Such a low N:P ratio would promote nitrogen rather than phosphorus limitation of phytoplankton growth in the estuary. Estuarine tidal marshes trapped particulate nutrients and released dissolved nutrients. Subtidal mudflats in the upper estuary trapped particulate P, released dissolved phosphate, and consumed nitrate. This resulted in a decrease in the ratio of dissolved inorganic N:P in the estuary. However, the upper estuary was a major sink for total phosphorus due to sediment accretion in the subtidal area. Bulk precipitation accounted for 31 percent of the total nongaseous nitrogen influx to the landscape, while farming accounted for 69 percent. Forty-six percent of the total non-gaseous nitrogen influx was removed as farm products, 53 percent either accumulated in the watershed or was lost in gaseous forms, and 1 percent entered the Rhode River. Of the total phosphorus influx to the landscape, 7 percent was from bulk precipitation and 93 percent was from farming. Forty-five percent of the total phosphorus influx was removed as farm products, 48 percent accumulated in the watershed, and 7 percent entered the Rhode River. These nitrogen and phosphorus discharges into the Rhode River, although a small fraction of total loadings to the watershed, were large enough to cause seriously overenriched conditions in the upper estuary.  相似文献   

Quantifying the P–T–t conditions of north–south Lhasa terrane accretion: new insight into the pre‐Himalayan architecture of the Tibetan plateau          下载免费PDF全文

O. M. Weller  M. R. St‐Onge  M. P. Searle  D. J. Waters  N. Rayner  S. Chen  S.‐L. Chung  R. M. Palin 《Journal of Metamorphic Geology》2015,33(1):91-113

An integrated field, petrological and geochronological study of the Basong Tso region of south‐eastern Tibet has constrained the timing and P–T conditions of north–south Lhasa terrane accretion and provides new insight into the tectonothermal evolution of the Tibetan plateau. Two distinct high‐grade metamorphic belts are recognized in the region: a southern belt (the Basong Tso complex) that consists of sheared schist and orthogneiss; and a northern belt (the Zhala complex) that comprises paragneiss and granite. Combined pseudosection modelling and U–Pb geochronology of monazite and zircon indicates that the Basong Tso complex records peak metamorphic conditions of 9 ± 0.5 kbar and 690 ± 25 °C at c. 204–201 Ma, whereas the Zhala complex experienced peak metamorphic conditions of 5.0 ± 1.0 kbar and 740 ± 40 °C at c. 198–192 Ma. Microstructural analysis suggests that the two belts share a common early prograde history, after which the Basong Tso complex attained peak conditions following rapid burial, and the Zhala complex approached peak conditions along an isobaric path. Overall it is inferred that the Basong Tso and Zhala complexes represent the lower and upper structural levels of an evolving orogen that underwent Barrovian‐type metamorphism following collision (M1), followed by Buchan‐style overprinting at higher structural levels due to heat advection by syn‐tectonic granites (M2). Mylonitization (sensu lato) of the Basong Tso complex and juxtaposition of the two units occurred after attainment of peak conditions. The dominance of Mesozoic regional metamorphism across most of the Tibetan plateau indicates that Cenozoic crustal thickening processes, where present, are only manifested at depth.  相似文献   

Sources of nutrient inputs to the Patuxent River estuary   总被引：1，自引：0，他引：1  

Thomas?E.?JordanEmail author  Donald?E.?Weller  David?L.?Correll 《Estuaries and Coasts》2003,26(2):226-243

We quantified annual nutrient inputs to the Patuxent River estuary from point and nonpoint sources and from direct atmospheric deposition. We also compared nonpoint source (NPS) discharges from Piedmont and Coastal Plain regions and from agricultural and developed lands. Using continuous automated-sampling, we measured discharges of water, nitrogen, phosphorus, organic carbon (C), and suspended solids from a total of 23 watersheds selected to represent various proportions of developed land and cropland in the Patuxent River basin and the neighboring Rhode River basin. The sampling period spanned two years that differed in annual precipitation by a factor of 1.7. Water discharge from the watershed to the Patuxent River estuary was 3.4 times higher in the wet year than in the dry year. Annual water discharges from the study watersheds increased as the proportion of developed land increased. As the proportion of cropland increased, there were increases in the annual flow-weighted mean concentrations of nitrate (NO₃ ^?), total nitrogen (TN), dissolved silicate (Si), total phosphate (TPO₄ ^3?), total organic phosphorus (TOP), total P (TP), and total suspended solids (TSS) in NPS discharges. The effect of cropland on the concentrations of NO₃ ^? and TN was stronger for Piedmont watersheds than for Coastal Plain watersheds. As the proportion of developed land increased, there were increases in annual mean concentrations of NO₃ ^?, total ammonium (TNH₄ ⁺), total organic N (TON), TN, total organic C (TOC), TPO₄ ^3?, TOP, TP, and TSS and decreases in concentrations of Si. Annual mean concentrations of TON, TOC, forms of P, and TSS were highest in the wet year. Annual mean concentrations of NO₃ ^?, TNH₄ ⁺, TN, and Si did not differ significantly between years. We directly measured NPS discharges from about half of the Patuxent River basin and estimated discharges from the other half of the basin using statistical models that related annual water flow and material concentrations to land cover and physiographic province. We compared NPS discharges to public data on point source (PS) discharges. We estimated direct atmospheric deposition of forms of N, P, and organic C to the Patuxent River estuary based on analysis of bulk deposition near the Rhode River. During the wet year, most of the total terrestrial and atmospheric inputs of forms of N and P came from NPS discharges. During the dry year, 53% of the TNH₄ ⁺ input was from atmospheric deposition and 58% of the NO₃ ^? input was from PS discharges; NPS and PS discharges were about equally important in the total inputs of TN and TPO₄ ^3?. During the entire 2-yr period, the Coastal Plain portion of the Patuxent basin delivered about 80% of the NPS water discharges to the estuary and delivered similar proportions of the NPS TNH₄ ⁺, TN, TOP, and TSS. The Coastal Plain delivered greater proportions of the NPS TON, TOC, Si, and TP (89%, 90%, 93%, and 95%, respectively) than of water, and supplied nearly all of the NPS TPO₄ ^3? (99%). The Piedmont delivered 33% of the NPS NO₃ ^? while delivering only 20% of the NPS water to the stuary. We used statistical models to infer the percentages of NPS discharges supplied by croplands, developed lands, and other lands. Although cropland covers only 10% of the Patuxent River basin, it was the most important source of most materials in NPS discharge, supplying about 84% of the total NPS discharge of NO₃ ^?; about three quarters of the TPO₄ ^3?, TOP, TP, and TSS; and about half of the TNH₄ ⁺ and TN. Compared to developed land, cropland supplied a significantly higher percentage of the NPS discharges of NO₃ ^?, TN, TPO₄ ^3?, TOP, TP, and TSS, despite the fact development land covered 12% of the basin.  相似文献   

Measurements of spectral induced polarization for environmental purposes   总被引：2，自引：0，他引：2  

A. Weller  F. D. Börner 《Environmental Geology》1996,27(4):329-334

Hydraulic permeability is one of the most important parameters for the evaluation of sediments relevant to environmental and hydrogeological problems. Up to now, permeability could be determined only by time-consuming and expensive methods like pumping tests or sampling and laboratory investigations. The results are confined to few locations, and they depend on the scale of the investigation method. Measurements on rock samples in a laboratory can differ significantly from well test results. Geophysical measurements are performed on different scales from high resolution measurements in boreholes up to large-scale soundings. Variations in permeability are mainly caused by varying grain size and by changes in porosity. A decrease of average grain diameter results in an increasing internal surface area. Petrophysical investigations have shown a reliable correlation between the imaginary part of electrical conductivity and the porespace-related internal surface. The formation resistivity factor, which is related to porosity, can be determined by geoelectrical measurements if the electrical conductivity of the pore fluid is known. The internal surface area and the formation factor are the only two parameters used by a Kozeny-Carman-like equation to evaluate the permeability or hydraulic conductivity for the investigated representative volume. Complex electrical conductivity is determined by measurements of induced polarization in the frequency domain. Frequencies below 10 Hz are used to avoid electromagnetic coupling. The permeability values determined by electrical measurements in boreholes can well be compared with those derived from the grain size distribution of samples. The same algorithm can be applied to evaluate the hydraulic conductivity of subsurface layers by complex resistivity soundings. The high sensitivity of the imaginary conductivity component to changes at the internal surface may be used as an indicator for contaminations.  相似文献   

Detection of layer boundaries in wells using multi-electrode resistivity data     

A. Weller  M. Furche  J. H. Schön 《Geophysical Journal International》2003,153(1):175-186

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Optimizing the yield of Sunyaev–Zel'dovich cluster surveys     

Richard A. Battye  Jochen Weller 《Monthly notices of the Royal Astronomical Society》2005,362(1):171-183

We consider the optimum depth of a cluster survey selected using the Sunyaev–Zel'dovich effect. By using simple models for the evolution of the cluster mass function and detailed modelling for a variety of observational techniques, we show that the optimum survey yield is achieved when the average size of the clusters selected is close to the size of the telescope beam. For a total power measurement, we compute the optimum noise threshold per beam as a function of the beam size and then discuss how our results can be used in more general situations. As a by-product we gain some insight into what is the most advantageous instrumental set-up. In the case of beam switching observations one is not severely limited if one manages to set the noise threshold close to the point which corresponds to the optimum yield. Considering a variety of alternative scenarios, we discuss how robust our conclusions are to modifications in the cluster model and cosmological parameters. The precise optimum is particularly sensitive to the amplitude of fluctuations and the profile of the gas in the cluster.  相似文献   

Family or Enterprise? What shapes the business structures of Australian farming?     

Sally Weller  Erin F. Smith  Bill Pritchard 《The Australian geographer》2013,44(2):129-142

Australian farmers navigate their contemporary circumstances through the use of different business and legal arrangements that are shaped by the commercial realities of farming and the aspirations of farm-owning households. In posing the question ‘Family or Enterprise?’, this paper examines the extent to which various household and farm business indicators are associated with different forms of farm ownership, namely sole proprietorships, partnerships, trusts and companies. Results from a postal survey of farm enterprises in Victoria, Australia suggest that both household and enterprise factors contribute to the business structure used, although the strongest determinants appear to be those factors that are less well understood in the rural geographical and sociological literature: household composition, farmer age and farm size. Greater scrutiny of the business instruments deployed by farmers to manage family and enterprise pressures should inform expectations of the fate of family farming in advanced financialised economies.  相似文献