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81.
In rapidly growing urban areas, it is deemed vital to expand (or contract) an existing network of public facilities to meet anticipated changes in the level of demand. We present a multi-period capacitated median model for school network facility location planning that minimizes transportation costs, while functional costs are subject to a budget constraint. The proposed Vintage Flexible Capacitated Location Problem (ViFCLP) has the flexibility to account for a minimum school-age closing requirement, while the maximum capacity of each school can be adjusted by the addition of modular units. Non-closest assignments are controlled by the introduction of a parameter penalizing excess travel. The applicability of the ViFCLP is illustrated on a large US school system (Charlotte-Mecklenburg, North Carolina) where high school demand is expected to grow faster with distance to the city center. Higher school capacities and greater penalty on travel impedance parameter reduce the number of non-closest assignments. The proposed model is beneficial to policy makers seeking to improve the provision and efficiency of public services over a multi-period planning horizon.  相似文献   
82.
Hydrographic changes in the NW Arabian Sea are mainly controlled by the monsoon system. This results in a strong seasonal and vertical gradient in surface water properties, such as temperature, nutrients, carbonate chemistry and the isotopic composition of dissolved inorganic carbon (δ13CDIC). Living specimens of the planktic foraminifer species Globigerina bulloides and Globigerinoides ruber, were collected using depth stratified plankton tows during the SW monsoon upwelling period in August 1992 and the NE monsoon non-upwelling period in March 1993. We compare their distribution and the stable isotope composition to the seawater properties of the two contrasting monsoon seasons. The oxygen isotope composition of the shells (δ18Oshell) and vertical shell concentration profiles indicate that the depth habitat for both species is shallower during upwelling (SW monsoon period) than during non-upwelling (NE monsoon period). The calcification temperatures suggest that most of the calcite is precipitated at a depth level just below the deep chlorophyll maximum (DCM), however above the main thermocline. Consequently, the average calcification temperature of G. ruber and G. bulloides is lower than the sea surface temperature by 1.7±0.8 and 1.3±0.9 °C, respectively. The carbon isotope composition of the shells (δ13Cshell) of both species differs from the in situ δ13CDIC found at the calcification depths of the specimens. The observed offset between the δ13Cshell and the ambient δ13CDIC results from (1) metabolic/ontogenetic effects, (2) the carbonate chemistry of the seawater and, for symbiotic G. ruber, (3) the possible effect of symbionts or symbiont activity. Ontogenetic effects produce size trends in Δδ13Cshell–DIC and Δδ18Oshell–w: large shells of G. bulloides (250–355μm) are 0.33‰ (δ13C) and 0.23‰ (δ18O) higher compared to smaller ones (150–250 μm). For G. ruber, this is 0.39‰ (δ13C) and 0.17‰ (δ18O). Our field study shows that the δ13Cshell decreases as a result of lower δ13CDIC values in upwelled waters, while the effects of the carbonate system and/or temperature act in an opposite direction and increase the δ13Cshell as a result lower [CO32−] (or pH) values and/or lower temperature. The Δδ13Cshell–DIC [CO32−] slopes from our field data are close to those reported literature from laboratory culture experiments. Since seawater carbonate chemistry affects the δ13Cshell in an opposite sense, and often with a larger magnitude, than the change related to productivity (i.e. δ13CDIC), higher δ13Cshell values may be expected during periods of upwelling.  相似文献   
83.
84.
The two Palaeoarchaean volcano-sedimentary complexes of the Buck Ridge (Barberton Greenstone Belt, South Africa) and Kittys Gap (Coppin Gap Greenstone Belt, East Pilbara, Australia) have a similar geological setting and age (∼3.45 Ga). The predominantly volcaniclastic sediments are concentrated at the top of these complexes, and experienced thorough, (very) early diagenetic silicification. In many places the silicification process has led to excellent preservation of the primary sedimentary structures. Elsewhere it has resulted in their obliteration or replacement by diagenetic structures. The Buck Ridge chert forms a regressive-transgressive succession, deposited around base level, with lacustrine and littoral marine facies. Deposition of the Kittys Gap Chert was also close to base level, almost exclusively subaqueous, with tidal influence and a regressive sequential trend.  相似文献   
85.
Five similar glacial-lake outburst floods (GLOFs) occurred in April, October, December 2008, March and September 2009 in the Northern Patagonia Icefield. On each occasion, Cachet 2 Lake, dammed by the Colonia Glacier, released circa 200-million m3 water into the Colonia River. Refilling has occurred rapidly, such that further outbreak floods can be expected. Pipeflow calculations of the subglacial tunnel drainage and 1D hydraulic models of the river flood give consistent results, with an estimated peak discharge surpassing 3,000 m3 s?1. These floods were larger in magnitude than any flood on record, according to gauged data since 1963. However, geomorphological analysis of the Colonia valley shows physical evidence of former catastrophic outburst floods from a larger glacial-lake, with flood discharges possibly as high as 16,000 m3 s?1. Due to potential impacts of climate change on glacier dynamics in the area, jökulhlaups may increase future flood risks for infrastructure and population. This is particularly relevant in view of the current development of hydropower projects in Chilean Patagonia.  相似文献   
86.
Simulations performed with the climate model LOVECLIM, aided with a simple data assimilation technique that forces a close matching of simulated and observed surface temperature variations, are able to reasonably reproduce the observed changes in the lower atmosphere, sea ice and ocean during the second half of the twentieth century. Although the simulated ice area slightly increases over the period 1980–2000, in agreement with observations, it decreases by 0.5 × 106 km2 between early 1960s and early 1980s. No direct and reliable sea ice observations are available to firmly confirm this simulated decrease, but it is consistent with the data used to constrain model evolution as well as with additional independent data in both the atmosphere and the ocean. The simulated reduction of the ice area between the early 1960s and early 1980s is similar to the one simulated over that period as a response to the increase in greenhouse gas concentrations in the atmosphere while the increase in ice area over the last decades of the twentieth century is likely due to changes in atmospheric circulation. However, the exact contribution of external forcing and internal variability in the recent changes cannot be precisely estimated from our results. Our simulations also reproduce the observed oceanic subsurface warming north of the continental shelf of the Ross Sea and the salinity decrease on the Ross Sea continental shelf. Parts of those changes are likely related to the response of the system to the external forcing. Modifications in the wind pattern, influencing the ice production/melting rates, also play a role in the simulated surface salinity decrease.  相似文献   
87.
A novel and readily applicable Structure-Activity Relationship (SAR) for predicting the barrier height Eb to decomposition by C-C scission of (substituted) alkoxy radicals is presented. Alkoxy radicals are pivotal intermediates in the atmospheric oxidation of (biogenic) volatile organic compounds, and their fate is therefore of crucial importance to the understanding of atmospheric VOC degradation mechanisms. The SAR is based on available theoretical energy barriers and validated against barriers derived from experimental data. The SAR is expressed solely in terms of the number(s) Ni of alkyl-, hydroxy- and/or oxo-substituents on the - and -carbons of the breaking bond: Eb(kcal/mol) =17.5 – 2.1 × N(alk) – 3.1 ×N(alk) – 8.0 × N,(OH) – 8.0 × N(O=) – 12 × N(O=). For barriers below 7 kcal/mol, an additional, second-order term accounts for the curvature. The SAR reproduces the available experimental and theoretical data within 0.5 to 1 kcal/mol. The SAR generally allows conclusive predictions as to the fate of alkoxy radicals; several examples concerning oxy radicals from prominent atmospheric VOC are presented. Specific limitations of the SAR are also discussed. Using the predicted barrier height Eb, the high-pressure rate coefficient for alkoxy decomposition k diss (298 K) can be obtained from k diss (298 K) = L ×1.8 × 1013 exp(–Eb/RT) s–1, with L the reaction path degeneracy.  相似文献   
88.
89.
Reconstructing ancient topography through erosion modelling   总被引:1,自引:1,他引:1  
One of the main aims of geomorphology is to understand how geomorphic processes change topography over long time scales. Over the last decades several landscape evolution models have been developed in order to study this question. However, evaluation of such models has often been very limited due to the lack of necessary field data. In this study we present a topography based hillslope erosion and deposition model that is based on the WATEM/SEDEM model structure and works on a millennial time scale. Soil erosion, transport and deposition are calculated using slope and unit contributing area. The topography is iteratively rejuvenated by taking into account modelled erosion and deposition rates, thereby simulating topographic development backwards in time. A first attempt has been made to spatially evaluate the model, using detailed estimates for historical soil erosion and sediment deposition volumes, obtained from an augering campaign in a small catchment in the Belgian Loess Belt. The results show that the model can simulate realistic soil redistribution patterns. However, further research is necessary in order to deal with artificial flaws that cause routing problems and significantly influence results. Common problems and issues related to this type of backward modelling are also discussed.  相似文献   
90.
The Kundelungu foreland, north of the Lufilian arc in the Democratic Republic of Congo, contains a number of various vein-type and stratiform copper mineralisations. The geodynamic context and metallogenesis of these mineral occurrences remain enigmatic. Currently, the vein-type Cu–Ag ore deposit at Dikulushi is the most significant deposit in the region. Mineralisation at Dikulushi comprises two major styles: 1) a polysulphide assemblage (Zn–Pb–Fe–Cu–As) within brecciated rocks along an anticlinal closure; and 2) a vein-hosted Cu–Ag assemblage. Petrographic and fluid inclusion studies indicate that the early Zn–Pb–Fe–Cu–As assemblage formed from a high-salinity Ca–Na–Cl fluid of modest temperature (135–172 °C). The later, economically more significant vein-related Cu–Ag mineralisation formed from intermediate salinity, lower temperature (46–82 °C) Na–Cl fluids. Weathering of the sulphide minerals resulted in a supergene enrichment with the formation of secondary Cu-minerals.  相似文献   
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