Leakage pathway estimation in geologic CO<Subscript>2</Subscript> storage: application of inverse analysis to synthetic heterogeneous domains     

Seong Jun Lee 《Environmental Earth Sciences》2016,75(17):1227

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Sorption behaviour of pentachlorophenol in sub-Saharan tropical soils: soil types sorption dynamics     

Bamidele I. Olu-Owolabi  Paul N. Diagboya  Chukwunonso P. Okoli  Kayode O. Adebowale 《Environmental Earth Sciences》2016,75(24):1494

In order to predict exposure risks as well as appropriate remediation strategies for pesticides in soils, knowledge of pesticides sorption processes onto various representative soils is vital. Hence, laboratory batch experiments were carried out to study sorption of a pesticide, pentachlorophenol (PCP), on five soils obtained from different sub-Saharan agro-ecological zones (AEZs) in order to understand sorption equilibrium, kinetics, and thermodynamics. Experimental data showed that sorption equilibrium was attained within 24 h. The fitting of kinetic results and equilibrium data to different models suggested partly surface adsorption and partly partitioning of PCP within voids of the various soil components. Sorption was mainly attributed to sharing or exchange of valence electrons between negatively charged PCP molecules and positively charged soil sorption sites. The sorption process was spontaneous and accompanied by decreased entropy, but was pH and temperature dependent, reducing with increase in pH and temperature. The various soils’ PCP sorption capacities were directly proportional to their cation exchange capacities. The low PCP sorption observed in these soils suggested high risk of PCP being present in soil water solution, especially at higher temperatures, which can lead to contamination of the aquifer. This risk may be higher for soils obtained from AEZs with warmer natural temperatures.  相似文献   

Artificial neural network inversion of magnetic anomalies caused by 2D fault structures     

Mansour A. Al-Garni 《Arabian Journal of Geosciences》2016,9(2):156

A new approach is proposed to interpret magnetic anomalies caused by 2D fault structures. This approach is based on the artificial neural network inversion, utilizing particularly modular neural network algorithm. The inversion process is implemented to estimate the parameters of 2D fault structures where it has been verified first on synthetic models. The results of the inversion show that the parameters derived from the inversion agree well with the true ones. The analysis of noise has been studied in order to investigate the stability of the approach where it has been tested for contaminated anomalies with 5 and 10 % of white Gaussian noise. The results of the inversion provide satisfactory results even with contaminated signals.The validity of the approach has been demonstrated through real data taken from New South Wales, Australia. A comparable and satisfactory agreement is shown between the inversion results of the neural network and those from techniques published in literatures.  相似文献   

Factors controlling the adsorption of acid blue 113 dye from aqueous solution by dried <Emphasis Type="Italic">C. edulis</Emphasis> plant as natural adsorbent     

R. Aziam  M. Chiban  E. Eddaoudi  A. Soudani  M. Zerbet  F. Sinan 《Arabian Journal of Geosciences》2016,9(15):659

Contamination of surface water and groundwater by organic pollutants is a serious problem due to their persistence, bioaccumulation and biomagnification through food webs. Since the removal of dyes from wastewater is considered an environmental challenge and government legislation requires textile wastewater to be treated, therefore there is a constant need to have an effective process that can efficiently remove these dyes. The aim of the present study is to evaluate the potentiality of dried Carpobrotus edulis plant as low-cost adsorbent for the removal of the industrial acid blue 113 dye from aqueous solutions using the batch equilibration technique. The effects of different physicochemical parameters such as adsorbent dose, contact time, initial dye concentration, solution pH and temperature on adsorption rate of anionic AB113 dye on microparticles of dried C. edulis plant were investigated. The experimental data were analyzed by using mathematical models to determine the thermodynamic parameters. The negative values of free energy change indicated the spontaneous nature of the adsorption and negative value of enthalpy change suggested the exothermic nature of the adsorption process. These results indicate that dried C. edulis plant as an environmentally friendly adsorbent could be potentially used for the removal of anionic dyes from aqueous solutions.  相似文献   

Performance of seismic arrays in the presence of weathering layer variations     

Jubran Akram  Abdullatif A. Al-Shuhail 《Arabian Journal of Geosciences》2016,9(8):522

Near-surface layer variations can degrade the desired response of seismic arrays which are typically used to attenuate horizontally traveling coherent noise and enhance vertically traveling signal. We investigate the effect of variations in the near-surface layer thickness on the performance of arrays by studying their impulse and wavelet responses. The models considered include the topographic variations and a channel in the base of weathering layer. The topographic variations include a dipping surface layer as well as a surface layer that follows a sine wave. The geological channel is assumed to be present under the entire receiver array as well as partially under a few receivers. We use Ricker wavelet and model plane wavefronts with incidence angles (90, 70, 45, 20, and 5 °) on a 12-element equally weighted array for the weathering layer models. We found that the array responses are more degraded for near-vertically traveling waves in all cases. The array responses are also found to be more degraded when channel variations are present underneath a few receivers as compared to the entire array length. We recommend designing a spatial filter or using single-sensor records after correcting for intra-array statics to preserve the reflection amplitudes in the presence of weathering layer variations.  相似文献   

Changing depositional environment revealed from sediment components,west of “Swatch of No Ground”, northern Bay of Bengal     

Purnima Bejugam  G. N. Nayak 《Arabian Journal of Geosciences》2016,9(9):551

The sediment cores of 20 cm length collected from 31 to 83 m range of water depth from the inner shelf of Bay of Bengal west of “Swatch of No Ground” were analyzed for grain size, organic carbon, total nitrogen, calcium carbonate and clay mineralogy. Grain size analysis revealed that the sediment size decreases from west to east within the study area indicating a possible direction of transport towards east parallel to the coast. The grain size also decreases with increasing water depth, i.e. north to south, indicating sediment contribution to the area of study from Hooghly and other local rivers. In the cores studied, illite was the dominant clay mineral which seems to be a product of glacial weathering under arid conditions with its source being the Himalayan region. The organic carbon content was low in the sediments and was attributed to low plankton production or intense oxidation processes. Low calcium carbonate percentage also supports the view of a low productivity in this region. Organic carbon increases gradually from west to east indicating its association with finer sediments and also indicates transport due to currents which drift the organic carbon away before it settles down within the sediments. Higher values relatively closer to the coast in the eastern side indicate additional contribution from Sunderban mangroves. The C/N ratio obtained indicates mixed source of terrestrial and marine for the organic matter in the sediments. Sedimentation rates available for deltaic plains and shelves off Bangladesh when adopted for the present area revealed that a 20 cm long sediment column was deposited in around 10 years. In most of the cores studied, a change in the trend of sediment components and organic carbon was observed at around 10 cm where grain size increases and organic carbon decreases towards the surface inferring that during the last 5 years, possible floods during NE monsoon or due to melting of ice in Himalaya are responsible for releasing additional water and material which brought a change in hydrodynamic conditions. The surface depletion of organic carbon indicates its dilution by the addition of coarser materials.  相似文献   

Erratum to: Identifying the spatial and temporal distribution characteristics of precipitation in Iran     

G. A. Fallah Ghalhari  A. A. Dadashi Roudbari  M. Asadi 《Arabian Journal of Geosciences》2016,9(13):629

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An integration-based estimation approach for the determination of slug test parameters under various flow geometries     

A. Ufuk Şahin  Emin Çiftçi 《Arabian Journal of Geosciences》2016,9(14):639

A simple parameter estimation procedure, designated as integration-based estimation (IBE), was introduced to determine the hydraulic properties of an aquifer using slug test models subjected to certain flow geometries such as radial and spherical flows. The basic idea behind the proposed IBE approach is to link an integration value at pre-defined normalized head levels for field data with that of a theoretical type curve. The IBE method removes the need for the implementation of the classical graphical matching process which would be ineffective to acquire aquifer parameters for non-ideal aquifer conditions. As the second aspect of this study, a new decision tool was suggested to determine the suitable slug test model to be utilized for the site data since diagnosing the flow character properly is of crucial importance for following a convenient analysis procedure. The estimation performance and limitation of the proposed IBE method were tested for several slug test scenarios including radial and spherical flow models with a number of synthetically generated data sets as well as a field application. Results reveal that the IBE together with the identification methodology not only is able to retrieve aquifer parameters as reliable as the existing techniques in the literature but also diagnoses the flow character precisely as demonstrated in this study.  相似文献   

Preface to the Dust Topical Collection     

Domenico M. Doronzo  Ali Al-Dousari  Arnau Folch  Pavla Dagsson-Waldhauserova 《Arabian Journal of Geosciences》2016,9(6):468

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New occurrence of potential phosphate resource in northeast Jordan     

Khalil M. Ibrahim  Khitam Alzughoul  Mohammad Muhtaseb 《Arabian Journal of Geosciences》2016,9(7):497

An exploration program aided by field investigation, exploration drilling, detailed sampling, lithological and petrological studies, geochemical investigation, and resource calculation leads to the discovery of a potential phosphate resource in northeast Jordan close to the international border with Saudi Arabia and Iraq. The studied phosphate is of the Middle Eocene age that belongs to the Wadi Shallala Formation. It is equivalent to the phosphate deposits recorded in the lower part of the Umm Wual Formation in the Turayf region of Saudi Arabia and the Eocene Ratga Formation in the Ethna phosphate deposit west of Iraq. The phosphorites in the region are broadly similar in mineralogical composition and geochemical affinities. X-ray diffraction indicates the presence of francolite with variable amounts of calcite and quartz. Most samples consist of phosphate clasts embedded in carbonate and silica matrix and cement. P₂O₅ content is up to 32.3 % with an average equal to 18.6 %. The impurity is caused by the presence of variable amounts of SiO₂ and CaO. The F% and F/P₂O₅ ratio in studied phosphates is lower compared with that in phosphates from Jordan and Saudi Arabia. The geological and geochemical results were integrated for resource estimation. Three high-grade phosphate layers with ≥23 % P₂O₅ were considered in the calculations. The phosphate resource is classified as an inferred resource. The total volume of the resource is about 649 million tons. The average P₂O₅ content is 24.57, and the stripping ratio is 1:5.8.  相似文献