A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS     

Lin Xu  Chongguang Luo  Hanjie Wen 《Geostandards and Geoanalytical Research》2020,44(1):201-214

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.  相似文献   

准噶尔盆地玛湖凹陷西斜坡三叠系百口泉组扇三角洲优质储集层预测          下载免费PDF全文

桑林翔  刘军  王贵文  王苏天  李全  张云龙 《古地理学报》2020,22(6):1053-1064

针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10^-3μm²)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。  相似文献   

Hydraulic Performance of the Horizontal Reactive Media Treatment Well: Pilot and Numerical Study     

Blossom N. Nzeribe  Wen Li  Michelle Crimi  Guangming Yao  Craig E. Divine  Jeff McDonough  Jack Wang 《Ground Water Monitoring & Remediation》2020,40(3):30-41

This study is focused on a passive treatment system known as the horizontal reactive treatment well (HRX Well®) installed parallel to groundwater flow, which operates on the principle of flow focusing that results from the hydraulic conductivity (K) ratio of the well and aquifer media. Passive flow and capture in the HRX Well are described by simplified equations adapted from Darcy's Law. A field pilot-scale study (PSS) and numerical simulations using a finite element method (FEM) were conducted to verify the HRX Well concept and test the validity of the HRX Well-simplified equations. The hydraulic performance results from both studies were observed to be within a close agreement to the simplified equations and their hydraulic capture width approximately five times greater than the well diameter (0.20 m). Key parameters affecting capture included the aquifer thickness, well diameter, and permeability ratio of the HRX Well treatment media and aquifer material. During pilot testing, the HRX Well captured 39% of flow while representing 0.5% of the test pit cross-sectional volume, indicating that the well captures a substantial amount of surrounding groundwater. While uncertainty in the aquifer and well properties (porosity, K, well losses), including the effects of boundary conditions, may have caused minor differences in the results, data from this study indicate that the simplified equations are valid for the conceptual design of a field study. A full-scale HRX Well was installed at Site SS003 at Vanderberg Air Force Base, California, in July/August 2018 based on outcomes from this study.  相似文献   

Redundant and Nonredundant Information for Model Calibration or Hydraulic Tomography     

Jet-Chau Wen  Jyun-Lin Chen  Tian-Chyi Jim Yeh  Yu-Li Wang  Shao-Yang Huang  Zhong Tian  Chia-Yii Yu 《Ground water》2020,58(1):79-92

Drawdown data from independent pumping tests have widely been used to validate the estimated hydraulic parameters from inverse modeling or hydraulic tomography (HT). Yet, the independent pumping test has not been clearly defined. Therefore, the goal of this paper is to define this independent pumping test concept, based on the redundant or nonredundant information about aquifer heterogeneity embedded in the observed heads during cross-hole pumping tests. The definition of complete, moderate redundancy and high nonredundancy of information are stipulated using cross-correlation analysis of the relationship between the head and heterogeneity. Afterward, data from numerical experiments and field sequential pumping test campaigns reinforce the concept and the definition.  相似文献   

2020年5月6日新疆乌恰5.0级和5月9日柯坪5.2级地震总结     

马亚伟  宋治平  杨文  解孟雨  苑争一  钟骏  李美  姚丽  邓世广  臧阳 《地震地磁观测与研究》2020,41(4):179-192

2020年5月6日、5月9日,新疆地区南天山西段先后发生乌恰5.0级和柯坪5.2级地震,系统总结2次地震发生前出现的地震活动和地球物理观测异常,其中：①地震活动：震前存在调制地震集中、地震窗、5级以上地震成组等中短期异常;②地球物理观测：2次地震震中附近震前出现形变、电磁和流体观测异常,其中形变异常3项、电磁异常4项、流体异常1项,主要分布在柯坪5.2级地震震中附近。通过对2次地震序列进行跟踪,发现：乌恰5.0级地震余震较少,震后60天内共记录M_L 3.0以上余震4次,最大震级为M_L 4.5;柯坪5.2级地震后余震较丰富,震后60天内共记录M_L 3.0以上余震10次,最大震级为M_L 4.7,计算得到序列h值为1.6,b值为0.73。综合分析认为,2020年5月新疆地区2次5级以上地震前存在的地震活动异常较少,但区域地震活动水平较强,主要存在具有中短期指示意义的地球物理观测异常。  相似文献   

九寨沟国家级自然保护区长海夏季浮游植物群落结构及生态评价     

邢冰伟  徐季雄  曹玥  邓贵平  庞婉婷  王全喜 《湖泊科学》2020,32(4):1088-1099

高山湖泊对于全球气候变化及人类影响是一个极为敏感的参照系统.九寨沟国家级自然保护区长海作为一个独特的高山湖泊,研究其浮游植物群落结构及其与环境的关系,评估其水质现状及影响因素,有着重要的意义.本文于2014年7月对长海浮游植物群落结构进行了研究.全湖共布设12个采样点,并在中心采样点进行了垂直分层采样.本次调查共发现浮游植物6门38属63种,平均丰度为6.98×10~5cells/L,平均生物量为0.31 mg/L.浮游植物的水平分布差异不大;在垂直分布上,浮游植物的丰度从表层0.5 m至水下50 m呈现先增加后减少的趋势,在20 m水深处达到最大.长海浮游植物的优势种是长海小环藻(Cyclotella changhai)和飞燕角甲藻(Ceratium hirundinella),长海小环藻数量较多,飞燕角甲藻生物量较大.长海浮游植物多样性指数较低,综合各类水质评价方法,可以得出九寨沟长海处于贫-中营养状态.  相似文献   

洱海湖滨带冬季水鸟的水质指示作用     

张淑霞  吴慧琳  周俊  高颖  蒋鋆  肖文 《湖泊科学》2017,29(4):804-810

水鸟在物种或群落水平上可以对湿地营养状态有所响应,预警生态系统有害的改变.以大型淡水湖泊洱海为例,基于2015年2月沿岸17个观察点的冬季水鸟调查与水质同步监测,研究小(Podiceps ruficollis)、白骨顶(Fulica atra)和黑水鸡(Gallinula chloropus)密度对沿岸水体中总磷和总氮浓度的响应关系.结果发现白骨顶和小密度均与总氮浓度呈显著正相关,也均与总磷浓度呈显著正相关;黑水鸡密度与总氮和总磷浓度无显著相关性.结果表明,水鸟可以在物种水平上对洱海湖滨带水中营养物质变化有所响应,也强调了根据具体指示物种的生态学习性选择水鸟指示物种尤为重要.白骨顶和小在更大空间和时间尺度上的水质指示作用有待于更多湖泊或水库水体的长期相关研究.  相似文献   

整点气温缺测的插补方法研究及其初步应用     

闫丽莉  温少妍  高文晶  刘传军  杨甜 《震灾防御技术》2019,14(2):446-455

长期连续完整的历史气温资料是震前气温异常判别研究的重要数据基础。本文考虑了参考站与缺测站之间的距离,建立改进的线性回归模型。利用该模型插补缺测和错误的气温整点值数据,在一定程度上解决了长期连续观测数据缺测的情况。通过对收集的唐山观测站气温整点值数据进行插补,并应用插补完整的数据分析研究了2012年5月28日唐山4.8级地震前兆异常。结果表明:①插补值与其前后观测值衔接吻合,插补后完整连续数据符合夏高冬低的年变规律;②插补误差在±0.5℃范围内的比例为60.2%,在±0.8℃范围内的比例为80.3%,其误差绝对值大于1.0℃的比例为9.6%,平均绝对误差为0.84℃,插补值与观测值的相关系数大部分在0.9以上;③从3月27日起出现增温异常,特别是震前2天增温幅度约8℃。  相似文献   

Smart Semi-active PID-ACO control strategy for tower vibration reduction in Wind Turbines with MR damper     

Rahman  Mahmudur  Ong  Zhi Chao  Chong  Wen Tong  Julai  Sabariah 《地震工程与工程振动(英文版)》2019,18(4):887-902

Wind turbine technology is well known around the globe as an eco-friendly and effective renewable power source. However, this technology often faces reliability problems due to structural vibration. This study proposes a smart semi-active vibration control system using Magnetorheological (MR) dampers where feedback controllers are optimized with nature-inspired algorithms. Proportional integral derivative (PID) and Proportional integral (PI) controllers are designed to achieve the optimal desired force and current input for MR the damper. PID control parameters are optimized using an Ant colony optimization (ACO) algorithm. The effectiveness of the ACO algorithm is validated by comparing its performance with Ziegler-Nichols (Z-N) and particle swarm optimization (PSO). The placement of the MR damper on the tower is also investigated to ensure structural balance and optimal desired force from the MR damper. The simulation results show that the proposed semi-active PID-ACO control strategy can significantly reduce vibration on the wind turbine tower under different frequencies (i.e., 67%, 73%, 79% and 34.4% at 2 Hz, 3 Hz, 4.6 Hz and 6 Hz, respectively) and amplitudes (i.e. 50%, 58% and 67% for 50 N, 80 N, and 100 N, respectively). In this study, the simulation model is validated with an experimental study in terms of natural frequency, mode shape and uncontrolled response at the 1st mode. The proposed PID-ACO control strategy and optimal MR damper position is also implemented on a lab-scaled wind turbine tower model. The results show that the vibration reduction rate is 66% and 73% in the experimental and simulation study, respectively, at the 1st mode.

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福建地区环境噪声特性研究     

蔡辉腾  陈颙  金星  徐嘉隽  徐艺鹤  李稳 《地震研究》2019,42(1):64-71,I0001

为进一步加强对福建地区噪声特性的认识以及提升台站地震观测质量,计算了2014年福建地震台网宽频带地震仪连续观测数据的功率谱概率密度函数,并分析其影响因素和不同频段时空变化特性。结果表明:人文噪声平均水平最高地区位于福建沿海福州至厦门一带,07:00—18:00的功率谱密度要明显高于其它时间段,12:00左右出现间歇性低谷期,夜间有不同程度的降低,日变化除了在春节假期大幅下降外,均处于较为稳定态势;福建地区次级微震主要成分是Rayleigh波,主频约为2.7 s,主微震主频约为16 s,次级微震平均水平最高地区也位于沿海一带,向内陆方向呈衰减趋势,其日变化明显,与台风和潮高有较高的相关性。  相似文献