量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

The scaling of the redshift power spectrum: observations from the Las Campanas redshift survey     

Y.P. Jing  G. Börner 《Monthly notices of the Royal Astronomical Society》2001,325(4):1389-1396

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Determination of physical parameters of NGC 2023 using the hyperfine NH₃ spectrum     

Xing Jun  Xu Lan-Ping 《Chinese Astronomy and Astrophysics》1985,9(4):283-290

An improved approach is given for deriving the physical parameters of a molecular cloud by its NH₃ rotation-inversion hyperfine spectra. The optical depth τ₀(1, 1) of NH₃ (1,1) is obtained by considering the blending effect of the magnetic hyperfine spectral lines, the (1-1) excitation temperature T_ex (1, 1) is calculated by a two level model, the effect of different collision rate and the thermalization of the (1, 1) inversion lines are discussed, the rotation temperature T_R ( 2, 1) between the NH₃ levels (2, 2) and (1, 1) and the column density N( 1, 1) of the NH₃ (1, 1) inversion level are derived, the results of the total column density from different assumptions for the abundance ratio of ortho-NH₃ and para-NH₃ are also discussed.

This approach is used for the molecular cloud NGC 2023 by using the relevant observed data and its optical depth and other physical parameters are obtained.  相似文献   

Silicon limitation on primary production and its destiny in Jiaozhou Bay, China——Ⅳ：Study on cross-bay transect from estuary to ocean   总被引：1，自引：0，他引：1  

Yang Dongfang  Chen Yu  Gao Zhenhui  Zhang Jing  Wang Fan 《中国海洋湖沼学报》2005,23(1):72-90

The authors analyzed the data collected in the Ecological Station Jiaozhou Bay from May 1991 to November 1994, including 12 seasonal investigations, to determine the characteristics, dynamic cycles and variation trends of the silicate in the bay. The results indicated that the rivers around Jiaozhou Bay provided abundant supply of silicate to the bay. The silicate concentration there depended on river flow variation. The horizontal variation of silicate concentration on the transect showed that the silicate concentration decreased with distance from shorelines. The vertical variation of it showed that silicate sank and deposited on the sea bottom by phytoplankton uptake and death, and zooplankton excretion. In this way, silicon would endlessly be transferred from terrestrial sources to the sea bottom. The silicon took up by phytoplankton and by other biogeochemical processes led to insufficient silicon supply for phytoplankton growth. In this paper, a 2D dynamic model of river flow versus silicate concentration was established by which silicate concentrations of 0.028–0.062 μmol/L in seawater was yielded by inputting certain seasonal unit river flows (m³/s), or in other words, the silicate supply rate; and when the unit river flow was set to zero, meaning no river input, the silicate concentrations were between 0.05–0.69 μmol/L in the bay. In terms of the silicate supply rate, Jiaozhou Bay was divided into three parts. The division shows a given river flow could generate several different silicon levels in corresponding regions, so as to the silicon-limitation levels to the phytoplankton in these regions. Another dynamic model of river flow versus primary production was set up by which the phytoplankton primary production of 5.21–15.55 (mgC/m²·d)/(m³/s) were obtained in our case at unit river flow values via silicate concentration or primary production conversion rate. Similarly, the values of primary production of 121.98–195.33 (mgC/m²·d) were achieved at zero unit river flow condition. A primary production conversion rate reflects the sensitivity to silicon depletion so as to different phytoplankton primary production and silicon requirements by different phytoplankton assemblages in different marine areas. In addition, the authors differentiated two equations (Eqs. 1 and 2) in the models to obtain the river flow variation that determines the silicate concentration variation, and in turn, the variation of primary production. These results proved further that nutrient silicon is a limiting factor for phytoplankton growth. This study was funded by NSFC (No. 40036010), and the Director's Fund of the Beihai Sea Monitoring Center, the State Oceanic Administration.  相似文献   

基于Chandra的活动星系核观测     

李丹丹  王竞  陈阳  何香涛 《天文学进展》2005,23(3):239-247

活动星系核（AGN）是宇宙中最奇特的天体之一。它是真正意义上的全波天体，其中X射线波段的发射功率占到全波段功率的50％左右。AGN的X射线辐射研究涉及天体物理中的最基本问题，例如能量产生、辐射机制和宇宙论等，而Chandra X射线卫星的高分辨率图像和光谱对这一研究有着重要作用。以Chandra卫星的部分观测结果为例，简要介绍了几类不同类型AGN的X射线辐射研究进展：（1）宽吸收线类星体APM08279＋5255（z=3．91）的X射线谱分析，以及高红移类星体的观测概况；（2）Seyfert星系NGC 4151延展X射线发射问题的解决，及NGC 1068X射线辐射与光学波段的高激发态发射线（[OⅢ]λ5007）有很强相关性的发现；（3）6个BLLac天体样本的X射线环境分析；（4）射电星系X射线喷流的观测等。  相似文献   

调频式电涡传感器微机实现的探讨     

林菁 《广东海洋大学学报》1996,(1)

分析了分频和ＣＴＣ计数采样中误读数的原因和解决方法，并利用微机软件实现非线性校正。此传感器用于位移测量系统中，具有０．０１ｍｍ的分辨率及优于１％的精度，可在－２０～６０℃温度范围内工作。  相似文献   

Historical records of outburst of R Aquarii     

Li Jing 《Chinese Astronomy and Astrophysics》1985,9(4):322-323

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八庙—青山金红石矿床化学成分与成矿关系     

徐少康  李博昀  程建祖  刘振山 《河南国土资源》1996,(4)

本矿床是我国金红石矿床重要的成因及工业类型，为具有特定化学成分的岩石在特定变质条件下形成的。本文通过对大量数据的处理，查明了化学成分与成矿的关系：高Ａｌ２Ｏ３、ＭｇＯ、Ｆｅ２Ｏ３＋ＦｅＯ、Ｋ２Ｏ、Ｐ２Ｏ５、Ｈ２Ｏ＋、ＭｎＯ，低ＳｉＯ２、ＣａＯ、Ｎａ２Ｏ、ＣＯ２、Ｓ等，利于钛富集；高ＴｉＯ２、ＭｇＯ、Ｐ２Ｏ５、Ｓ，低ＳｉＯ２、ＣａＯ、Ｋ２Ｏ、Ａｌ２Ｏ３、Ｆｅ２Ｏ３／ＦｅＯ，利于金红石形成；高Ｓｃ、Ｚｒ、Ｎｉ、Ｚｎ及Ｌａ／Ｙｂ，低Ｙ、Ｎｂ、Ｔｈ、Ｃｄ、Ｂａ、Ｂｅ、ΣＲＥＥ，利于金红石纯度提高。对研究矿床成因及寻找新的同类矿床等有重要意义  相似文献   

Ion-cyclotron instability and electron acceleration in coronal loops     

Dingyi Li  Deyu Wand  Shihtung Tsai  Minjian Xu  Dingyi Mao 《Solar physics》1993,143(2):235-245

Quasi-electrostatic electron and ion-cyclotron instabilities are studied. The result indicates that the higher harmonic ion cyclotron instabilities (ICI) can be excited while the fast ions produced from reconnection are injected into a coronal loop. Part of the energetic ions can be dragged out of the magnetic mirror turning points and a negative plasma potential is generated. The plasma potential may directly accelerate the electrons up to the relativistic velocity within a short time. This acceleration is similar to the processes occurring in the magnetic mirror devices of controlled thermonuclear fusion. The spectrum and flux of accelerated electrons have also been obtained. Some observational results during the solar flare might be explained by this acceleration mechanism.  相似文献   

河外H_2O超脉泽辐射     

徐烨  蒋栋荣  郑兴武  俞志尧 《天文学进展》2001,(3)

介绍了近年来河外Ｈ２Ｏ超脉泽的主要观测结果。Ｈ２Ｏ超脉泽通常起源于活动星系核中央的拱核盘。它们主要寄生在 Ｓｅｒｆｅｒｔ ２星系或低电离核区。至今为止，已有２０个星系探测到Ｈ２Ｏ超脉泽。脉泽辐射的各向同性光度为１０～６０００Ｌ⊙。所有超脉泽星系显示出核的活动，显然，脉泽是由核活动所产生的射电和Ｘ射线光子或激波来抽运的。Ｈ２Ｏ超脉泽倾向存在于高倾斜度的星系，这使得沿视线上的分子柱密度增高，产生足够大的放大光深。最有可能产生Ｈ２Ｏ超脉泽辐射的星系应有一个包含着射电源的侧向的分子盘以及一个适当的抽运机制。  相似文献