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171.
 This paper presents the results of field tests of hydrologic parameters in a landfill and the results of numerical simulation to find the efficiency of the pumping method to reduce leachate levels in the landfill. The field hydraulic conductivity and storativity of waste and buried cover soils in the landfill are measured by pumping and slug tests. The hydrologic condition inside the landfill is first calibrated using the drawdown-time curve obtained from the pumping test, and the flow behavior of leachate during pumping in the landfill, when various layers of waste and buried cover soil exist, is analyzed through three-dimensional numerical simulation of flow. The results of the field investigation show that the buried cover soil of low hydraulic conductivity forms an impermeable layer preventing the downward flow of leachate and upward flow of landfill gas. The hydraulic conductivities of the pumping test and slug tests were quite close on the same order of magnitude. It was also possible to match the drawdown-time data of the field tests with those of the model using input data close to the hydrologic property obtained from the field tests. The numerical flow analysis showed that pumping was possible up to 120 tons/day for a single well without a drain, while the pumping rate could be increased to 300 tons/day for the same well with the drain. From the vertical section of the flow vector with a horizontal drain, the barrier role of buried cover soil is identified, which was proposed by examining the water contents of the disposed cover soil and waste in the field. Received: 15 May 1998 · Accepted: 4 January 1999  相似文献   
172.
173.
Developing a reliable model for aquifer vulnerability   总被引:1,自引:0,他引:1  
The assessment of aquifer vulnerability to pollution is crucial for planning a sound management strategy of groundwater quality protection and farmland fertilizer use. This study establishes a reliable model for aquifer vulnerability assessment with an excellent performance for predicting groundwater nitrate-N contamination in the Choushui River alluvial fan, Taiwan based on the DRASTIC method. To promote the prediction performance of aquifer vulnerability assessment, discriminant analysis (DA) was applied to determine the weights of factors in the DRASTIC model by comparing the model results with the observed nitrate-N data. Key factors influencing the presence of groundwater nitrate-N pollution were characterized for different concentration thresholds. The results of analysis reveal that the modified DRASTIC model using DA significantly improves prediction performance for aquifer vulnerability assessment, and groundwater protection zones can be determined correctly based on the modified DRASTIC index. Furthermore, the sensitivity of the factors in the modified DRASTIC model indicates that the depth to the groundwater and aquifer media are critical when the nitrate-N concentration is less than 3 mg/L, while the impact of the vadose zone plays a vital role in controlling nitrate-N pollution of over 5 mg/L.  相似文献   
174.
Transmissivity is often estimated using specific capacity data when standard pumping test data are not available or the drawdown is stabilized early, as in this study. Previous researchers studied the relationship between transmissivity and specific capacity in the leaky aquifer system of volcanic rocks on Jeju Island, Korea, using the Cooper–Jacob equation. The current study utilizes the Moench leaky aquifer model. The linear relationship between transmissivity and specific capacity on a log–log scale for volcanic aquifers on Jeju Island is remarkably strong, with a correlation coefficient of 0.94. The width of the 90% prediction interval is about 0.89 log cycles, indicating a ±0.44 order of magnitude uncertainty when transmissivity is estimated using specific capacity.  相似文献   
175.
X-ray photoelectron spectra have been obtained under the same experimental conditions for synthetic α-NiS and natural β-NiS in order to establish any difference in S electronic environment, and to test the proposition that S core electron binding energies increase measurably with coordination number when the same metal is in different sulfide structures or lattice sites. The Ni and S electronic environments in the two NiS structures have been further probed by near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, and the NEXAFS spectra interpreted by reference to spectra simulated by ab initio calculations. The photoelectron and NEXAFS spectra for freshly prepared surfaces of α-NiS and β-NiS were found to be similar, with only subtle differences in electronic environment evident in the experimental and simulated NEXAFS spectra. The measured and calculated core electron binding energies did not support the previously postulated relationship between S coordination number and electron binding energies.  相似文献   
176.
A number of freshly abraded surfaces of pentlandite have been characterised by X-ray photoelectron spectroscopy to establish whether the initial intensity of the S 2p component near 161.4 eV, previously assigned to the 25% of S atoms in fourfold coordination by metal atoms in pentlandite, was always at least 25% of the total S 2p intensity. It was found that the intensity of this S 2p component could be lower than 20% for surfaces that were not significantly oxidised. To assess whether the proposed 0.75–0.8 eV 2p binding energy difference for the two sulfur environments in pentlandite was justified, ab initio calculations of the difference in core electron binding energies and of the densities of unfilled states have been carried out. The corresponding simulated S K near-edge X-ray absorption fine structure (NEXAFS) spectra have been compared with experimental spectra. The calculated S 2p and S 1s binding energy differences were 0.45 and 0.5 eV at most, in agreement with the experimental NEXAFS spectra. It was concluded that the S 2p component near 161.4 eV arises entirely from violarite present at the pentlandite surface rather than from 4-coordinate S in pentlandite itself. Ab initio calculations of the difference in S 2p binding energies for the 2- and 3-coordinate S in stibnite have also been carried out and found to be quite small, in agreement with previously reported experimental values. Nevertheless, for both pentlandite and stibnite, calculations have confirmed that an increase in coordination number is associated with an increase in sulfur core electron binding energies, even although that increase is barely measurable for the latter sulfide.  相似文献   
177.
178.
The pyranometer for observing the solar radiation reaching the surface of the earth is manufactured by various companies around the world. The sensitivity of the pyranometer at the observatory is required to be properly controlled based on the reference value of the World Radiometric Center (WRC) and the observatory environment; otherwise, the observational data may be subject to a large error. Since the sensitivity of the pyranometer can be calibrated in an indoor or outdoor calibration, this study used a CSTM-USS-4000C Integrating Sphere by Labsphere Inc. (USA) to calibrate the sensitivity of CMP22 pyranometer by Kipp&Zonen Inc. (Netherlands). Consequently, the factory sensitivity of CMP22 was corrected from 8.68 μV·(Wm?2)?1 to 8.98 μV·(Wm?2)?1, and the result from the outdoor calibration according to the observatory environment was 8.90 μV·(Wm?2)?1. After the indoor calibration of the pyranometer sensitivity, the root mean square error (RMSE) of the observational data at the observatory on a clear day without clouds (July 13, 2017) was 7.11 Wm?2 in comparison to the reference pyranometer. After the outdoor calibration of the pyranometer sensitivity based on these results, the RMSE of the observational data was 1.74 Wm?2 on the same day. Periodic inspections are required because the decrease of sensitivity over time is inevitable in the pyranometer data produced at the observatory. The initial sensitivity after indoor calibration (8.98 μV·(Wm?2)?1) is important, and the sensitivity after outdoor calibration (8.90 μV·(Wm?2)?1) can be compared to the data at the Baseline Surface Radiation Network (BSRN) or can be used for various studies and daily applications.  相似文献   
179.
This study investigates the impacts of shallow convection schemes on a simulated seasonal climatology in the Global and Regional Integrated Model system (GRIMs). The eddy-diffusivity scheme of Tiedtke (TDK) is evaluated, focusing on the dependency upon deep convection schemes. Drying and warming near the top of the planetary boundary layer (PBL) and opposing effects above are observed. The height of PBL is reduced due to the increase of thermal stability near the PBL top. The weakened PBL turbulence is partly compensated with the increased downward solar radiation due to the reduction of low clouds. These effects are pronounced over the oceans, which leads to the modulation of tropical precipitation. It is found that the original TDK scheme shows similar behavior regardless of the choice of deep convection schemes. A revised TDK scheme that explicitly couples the PBL and shallow convection processes is proposed and evaluated. The proposed scheme generally improves the simulated climatology over the results with the original TDK scheme, along with further improvement in the case of the revised deep convection scheme. Our results indicate that the role of the shallow convection scheme needs to be carefully examined to improve the performance of atmospheric models, with a focus on modulated PBL and deep convection processes.  相似文献   
180.
We analyzed the short period Rayleigh waves from the first crustal-scale seismic refraction experiment in the Korean peninsula, KCRUST2002, to determine the shear wave velocity and attenuation structure of the uppermost 1 km of the crust in different tectonic zones of the Korean peninsula and to examine if this can be related to the surface geology of the study area. The experiment was conducted with two large explosive sources along a 300-km long profile in 2002. The seismic traces, recorded on 170 vertical-component, 2-Hz portable seismometers, show distinct Rayleigh waves in the period range between 0.2 s and 1.2 s, which are easily recognizable up to 30–60 km from the sources. The seismic profiles, which traverse three tectonic regions (Gyeonggi massif, Okcheon fold belt and Yeongnam massif), were divided into five subsections based on tectonic boundaries as well as lithology. Group and phase velocities for the five subsections obtained by a continuous wavelet transform method and a slant stack method, respectively, were inverted for the shear wave models. We obtained shear wave velocity models up to a depth of 1.0 km. Overall, the shear wave velocity of the Okcheon fold belt is lower than that of the Gyeonggi and Yeongnam massifs by  0.4 km/s in the shallowmost 0.2 km and by 0.2 km/s at depths below 0.2 km. Attenuation coefficients, determined from the decay of the fundamental mode Rayleigh waves, were used to obtain the shear wave attenuation structures for three subsections (one for each of the three different tectonic regions). We obtained an average value of Qβ− 1 in the upper 0.5 km for each subsection. Qβ− 1 for the Okcheon fold belt ( 0.026) is approximately three times larger than Qβ− 1 for the massif areas ( 0.008). The low shear wave velocity in the Okcheon fold belt is consistent with the high attenuation in this region.  相似文献   
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