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101.
102.
Major minerals (sulfates, sulfides, quartz) are distributed in different parts of submarine hydrothermal ore deposits. For instance, the abundance of barite increases stratigraphically upwards in the massive orebodies of the Kuroko deposits (black and yellow ores), while quartz is abundant in the lower parts (siliceous ore). The different distribution of barite and quartz in the Kuroko deposits can not be accounted for by thermochemical equilibrium calculations based on the precipitation due to mixing of ascending hydrothermal solutions with ambient cold seawater. In the present study, a coupled fluid flow‐precipitation kinetics model was used to calculate the amounts of quartz, barite, and anhydrite precipitated from a hydrothermal solution mixed with seawater, assuming reasonable values for temperature, precipitation rate, fluid flow velocity, mineral surface area/fluid mass ratio (A/M), and initial concentrations of hydrothermal solution and seawater before mixing occurred. The results indicate that barite precipitates more efficiently than quartz from discharging fluids with relatively higher flow velocity, lower temperatures and under the condition of lower A/M ratios on the seafloor (black ore), whereas quartz precipitates more effectively from solutions with lower flow velocity, higher temperatures and higher A/M ratios beneath the seafloor (siliceous ore) and in the orebody (barite ore, ferruginous chert ore). Anhydrite precipitates in shallow sub‐seafloor environments with lower precipitation rates and higher A/M ratios than barite and higher precipitation rates and lower A/M ratios than quartz. These results explain the observed occurrences of barite, anhydrite, and quartz in the Kuroko deposits. Namely, barite is abundant in black ore and barite ore which formed above the seafloor, anhydrite formed in high‐permeability tuff breccias, and quartz formed in low permeability dacite intrusive bodies in the sub‐seafloor environment.  相似文献   
103.
Continuous magnetotelluric (MT) measurements were conducted from May 2008 to July 2009 at Sakurajima, one of the most active volcanoes in Japan. Two observation sites were established at locations 3.3 km east and 3 km west–northwest of the summit crater. At both observation sites, the high-quality component of the impedance tensor (Zyx) showed variations in apparent resistivity of approximately ± 20% and phase change of ± 2°, which continued for 20–180 days in the frequency range between 320 and 4 Hz. The start of the period of changes in apparent resistivity approximately coincided with the start of uplift in the direction of the summit crater, as observed by a tiltmeter, which is one of the most reliable pieces of equipment with which to detect magma intrusion beneath a volcano. A 2D inversion of MT impedance suggests that the resistivity change occurred at a depth around sea level. One of the possible implications of the present finding is that the degassed volatiles migrated not only vertically through the conduit but also laterally through a fracture network, mixing with shallow groundwater beneath sea level and thereby causing the observed resistivity change.  相似文献   
104.
Water and sediment samples were collected from 20 location of the Buriganga river of Bangladesh during Summer and Winter 2009 to determine the spatial distribution, seasonal and temporal variation of different heavy metal contents. Sequential extraction procedure was employed in sediment samples for the geochemical partitioning of the metals. Total trace metal content in water and sediment samples were analyzed and compared with different standard and reference values. Concentration of total chromium, lead, cadmium, zinc, copper, nickel, cobalt and arsenic in water samples were greatly exceeded the toxicity reference values in both season. Concentration of chromium, lead, copper and nickel in sediment samples were mostly higher than that of severe effect level values, at which the sediment is considered heavily polluted. On average 72 % chromium, 92 % lead, 88 % zinc, 73 % copper, 63 % nickel and 68 % of total cobalt were associated with the first three labile sequential extraction phases, which portion is readily bioavailable and might be associated with frequent negative biological effects. Enrichment factor values demonstrated that the lead, cadmium, zinc, chromium and copper in most of the sediment samples were enriched sever to very severely. The pollution load index value for the total area was as high as 21.1 in Summer and 24.6 in Winter season; while values above one indicates progressive deterioration of the sites and estuarine quality. The extent of heavy metals pollution in the Buriganga river system implies that the condition is much frightening and may severely affect the aquatic ecology of the river.  相似文献   
105.
The concentrations of dissolved organic carbon and nitrogen (DOC and DON, respectively) were measured in Shiraho fringing reef (Japan), using a high-temperature catalytic-oxidation method. When the seawater on the reef flat (shallow lagoon) was isolated from the surrounding ocean due to the low tide, the concentrations of DOC and DON on the reef flat were 66–75 and 4.8–5.7 μmol l−1, respectively. The DOC and DON concentrations were higher than those of the adjacent outer ocean (57–58 and 3.8 μmol l−1, respectively), suggesting that the coral reef functioned as a net source of dissolved organic matter for the surrounding ocean. In order to investigate long-term bacterial decomposition of the reef-derived DOC (RF-DOC), the seawater samples collected on the reef flat and at the adjacent ocean were incubated in the dark for 1 year. Regression analysis using an exponential curve that considered two degradability pools (labile and refractory) fitted the mineralization of the RF-DOC very well (r 2 > 0.89). According to the regression analysis, the DOC produced on the reef flat was composed of the labile fraction of 63–94% (average 77%) and the refractory fraction of 6–37% (average 23%). It was concluded that some of the DOC that was produced in the coral reef ecosystem was exported to the surrounding ocean if the reef flat had a water residence time less than several months. The exported organic matter may support microbial communities in the ocean as an energy source.  相似文献   
106.
Bengal Fan Miocene sediments were collected during International Ocean Discovery Program Expedition 354 and investigated using petrographic and detrital garnet chemistry analyses. The Miocene Siwalik Group, which is composed of sediments deposited in the Himalayan foreland basin, was also analyzed for comparison with the Bengal Fan data for the provenance change during the Miocene. Our petrographic analyses revealed that the Miocene sediments of the Bengal Fan and Siwalik Group consist predominantly of Higher Himalayan Crystalline (HHC)-derived detritus such as chloritoid, staurolite, sillimanite, and/or kyanite, which appear among the accessory minerals. The chemistry of the detrital garnet varies across the stratigraphy; most of the garnet is rich in almandine and poor in spessartine and pyrope. However, pyrope-rich garnet, which is considered to originate from the HHC core (granulite facies), was found in the lower to upper Miocene deposits. The deposition of HHC-derived detrital garnet began before the Middle Miocene (15 Ma) and before the Late Miocene (10–9 Ma) in the Siwalik Group. The Bengal Fan data, by contrast, indicated that pyrope-rich garnet appeared in the Early Miocene (17.3 Ma) and Late Miocene (8.5–6.5 Ma). We conclude that the Bengal Fan sediments record the erosion of the HHC zone since the Early Miocene that appears in the Siwalik sediments. Furthermore, we found that the HHC-derived inputs decreased from the late Middle Miocene (12 Ma) to the early Middle Miocene (10 Ma) in both the Nepal Himalaya foreland basin and the Bengal Fan. The disappearance of the HHC-derived detritus is probably the result of dilution by Lesser Himalayan detritus, which suggests that the Lesser Himalayan zone, which is composed of metamorphosed and unmetamorphosed sedimentary rocks, was uplifted.  相似文献   
107.
Estimation of groundwater residence time using the 36Cl bomb pulse   总被引:1,自引:0,他引:1  
We propose a methodology for estimating the residence time of groundwater based on bomb-produced (36)Cl. Water samples were collected from 28 springs and 2 flowing wells located around Mt. Fuji, Central Japan. (36)Cl/Cl ratios in the water samples, determined by accelerator mass spectrometry (AMS), were between 43 × 10(-15) and 412 × 10(-15). A reference time series of the above-background (i.e., bomb-derived) (36)Cl concentration was constructed by linearly scaling the background-corrected Dye-3 data according to the estimated total bomb-produced (36)Cl fallout in the Mt. Fuji area. Assuming piston flow transport, estimates of residence time were obtained by comparing the measured bomb-derived (36)Cl concentrations in spring water with the reference curve. The distribution of (36)Cl-based residence times is basically consistent with that of tritium-based estimates calculated from data presented in previous studies, although the estimated residence times differ between the two tracers. This discrepancy may reflect chlorine recycling via vegetation or the relatively small change in fallout rate, approximately since 1975, which would give rise to large uncertainties in (36)Cl-based estimates of recharge for the period, approximately since 1975. Given the estimated ages for groundwater from flowing wells, dating based on a (36)Cl bomb pulse may be more reliable and sensitive for groundwater recharged before 1975, back as far as the mid-1950s.  相似文献   
108.
为了测量距地表1 000 m以下位置的地壳应力状态,我们研究并开发了钻孔千斤顶压裂技术.技术的原理是:当钻孔千斤顶对钻孔壁加载时,与钻孔轴向平行的方向将会产生两个相对的新裂隙;卸载之后,如果千斤顶对钻孔壁的同一个地方进行施压,这对裂隙将会再次张开.与钻孔轴向垂直的平面上的两个主应力的大小和方向分别是由重张压力和裂隙的方...  相似文献   
109.
The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm3 non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value of the excess mixing volume of iron–light element alloys in the outer core.  相似文献   
110.
The sound velocities of two aluminum-rich phases in the lower mantle, hexagonal new Al-rich phase (NAL) and its corresponding high-pressure polymorph orthorhombic Ca-ferrite-type phase (CF), were determined with the Brillouin scattering method in a pressure range from 9 to 73 GPa at room temperature. Both NAL and CF samples have identical chemical composition of Na0.4Mg0.6Al1.6Si0.4O4 (40 % NaAlSiO4–60 % MgAl2O4). Infrared laser annealing in the diamond anvil cell was performed to minimize the stress state of the sample and obtain the high-quality Brillouin spectra. The results show shear modulus at zero pressure G 0 = 121.960 ± 0.087 GPa and its pressure derivative G’ = 1.961 ± 0.009 for the NAL phase, and G 0 = 129.653 ± 0.059 GPa and G’ = 2.340 ± 0.004 for the CF phase. The zero-pressure shear velocities of the NAL and CF phases are obtained to be 5.601 ± 0.005 km/sec and 5.741 ± 0.001 km/sec, respectively. We also found that shear velocity increases by 2.5 % upon phase transition from NAL to CF at around 40 GPa.  相似文献   
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