Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments   总被引：1，自引：0，他引：1  

Pyeong-Koo Lee  Min-Ju Kang  Ho Young Jo  Sang-Hoon Choi 《Environmental Earth Sciences》2012,66(7):1909-1923

The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area.  相似文献   

Ensemble-based landslide susceptibility maps in Jinbu area, Korea   总被引：2，自引：2，他引：0  

Moung-Jin Lee  Jae-Won Choi  Hyun-Joo Oh  Joong-Sun Won  Inhye Park  Saro Lee 《Environmental Earth Sciences》2012,67(1):23-37

Ensemble techniques were developed, applied and validated for the analysis of landslide susceptibility in Jinbu area, Korea using the geographic information system (GIS). Landslide-occurrence areas were detected in the study by interpreting aerial photographs and field survey data. Landslide locations were randomly selected in a 70/30 ratio for training and validation of the models, respectively. Topography, geology, soil and forest databases were also constructed. Maps relevant to landslide occurrence were assembled in a spatial database. Using the constructed spatial database, 17 landslide-related factors were extracted. The relationships between the detected landslide locations and the factors were identified and quantified by frequency ratio, weight of evidence, logistic regression and artificial neural network models and their ensemble models. The relationships were used as factor ratings in the overlay analysis to create landslide susceptibility indexes and maps. Then, the four landslide susceptibility maps were used as new input factors and integrated using the frequency ratio, weight of evidence, logistic regression and artificial neural network models as ensemble methods to make better susceptibility maps. All of the susceptibility maps were validated by comparison with known landslide locations that were not used directly in the analysis. As the result, the ensemble-based landslide susceptibility map that used the new landslide-related input factor maps showed better accuracy (87.11% in frequency ratio, 83.14% in weight of evidence, 87.79% in logistic regression and 84.54% in artificial neural network) than the individual landslide susceptibility maps (84.94% in frequency ratio, 82.82% in weight of evidence, 87.72% in logistic regression and 81.44% in artificial neural network). All accuracy assessments showed overall satisfactory agreement of more than 80%. The ensemble model was found to be more effective in terms of prediction accuracy than the individual model.  相似文献   

Possible linkage between East Asian summer drought and North Pacific Oscillation   总被引：1，自引：0，他引：1  

Ki-Seon Choi  Su-Bin Oh  Hi-Ryong Byun  R. H. Kripalani  Do-Woo Kim 《Theoretical and Applied Climatology》2011,103(1-2):81-93

The May North Pacific Oscillation Index and the summer (May and June?CJuly?CAugust??JJA) Effective Drought Index have a strong negative correlation in the East Asian region, particularly in northern China, Korea, and the southwestern regions of Japan (here termed ??Northeast Asia??); this signifies an intensification of the summer drought during positive North Pacific Index (NPI) phase in this region, and the presence of such a phenomenon has been observed in this study. The low-south/high-north anomalous pressure pattern forming in all layers of the troposphere in Northeast Asian region has been a cause of drought. This unusual pressure pattern gives rise to a cold northeasterly and intensifies downward flow and reduces relative humidity. In addition, this cold northeasterly hinders the northward movement of the western North Pacific high and reduces the frequency of tropical cyclones passing through this region, thereby further intensifying drought.  相似文献   

Induction of tributyltin-binding protein type 2 in Japanese flounder, Paralichthys olivaceus, by exposure to tributyltin-d27     

Nassef M  Tawaratsumita T  Oba Y  Satone H  Nakayama K  Shimasaki Y  Honjo T  Oshima Y 《Marine pollution bulletin》2011,62(2):412-414

In this study, individual Japanese flounder were intraperitoneally injected with 2 μg tributyltin-d27 (TBT-d27) fish⁻¹. Blood samples were collected on day 7 after injection. TBT-binding protein types 1 and 2 (TBT-bp1, -bp2) in the blood serum were quantified by western blotting analysis. As a result, the concentration of TBT-bp2 in TBT-d27 treated group increased to 220% of that in the solvent control, whereas the TBT-bp1 concentration decreased to 65% of that in the solvent control. Additionally, a positive relationship between the concentrations of TBT-bp2 and TBT was observed in blood sera of wild and cultured flounder. We suggest that TBT-bp2 is produced in response to TBT exposure and may play an important role in fish physiology.  相似文献   

On the observational determination of climate sensitivity and its implications   总被引：2，自引：0，他引：2  

Richard S. Lindzen  Yong-Sang Choi 《Asia-Pacific Journal of Atmospheric Sciences》2011,47(4):377-390

We estimate climate sensitivity from observations, using the deseasonalized fluctuations in sea surface temperatures (SSTs) and the concurrent fluctuations in the top-of-atmosphere (TOA) outgoing radiation from the ERBE (1985–1999) and CERES (2000–2008) satellite instruments. Distinct periods of warming and cooling in the SSTs were used to evaluate feedbacks. An earlier study (Lindzen and Choi, 2009) was subject to significant criticisms. The present paper is an expansion of the earlier paper where the various criticisms are taken into account. The present analysis accounts for the 72 day precession period for the ERBE satellite in a more appropriate manner than in the earlier paper. We develop a method to distinguish noise in the outgoing radiation as well as radiation changes that are forcing SST changes from those radiation changes that constitute feedbacks to changes in SST. We demonstrate that our new method does moderately well in distinguishing positive from negative feedbacks and in quantifying negative feedbacks. In contrast, we show that simple regression methods used by several existing papers generally exaggerate positive feedbacks and even show positive feedbacks when actual feedbacks are negative. We argue that feedbacks are largely concentrated in the tropics, and the tropical feedbacks can be adjusted to account for their impact on the globe as a whole. Indeed, we show that including all CERES data (not just from the tropics) leads to results similar to what are obtained for the tropics alone — though with more noise. We again find that the outgoing radiation resulting from SST fluctuations exceeds the zerofeedback response thus implying negative feedback. In contrast to this, the calculated TOA outgoing radiation fluxes from 11 atmospheric models forced by the observed SST are less than the zerofeedback response, consistent with the positive feedbacks that characterize these models. The results imply that the models are exaggerating climate sensitivity.  相似文献   

A review on vegetation models and applicability to climate simulations at regional scale   总被引：1，自引：0，他引：1  

Boksoon Myoung  Yong-Sang Choi  Seon Ki Park 《Asia-Pacific Journal of Atmospheric Sciences》2011,47(5):463-475

The lack of accurate representations of biospheric components and their biophysical and biogeochemical processes is a great source of uncertainty in current climate models. The interactions between terrestrial ecosystems and the climate include exchanges not only of energy, water and momentum, but also of carbon and nitrogen. Reliable simulations of these interactions are crucial for predicting the potential impacts of future climate change and anthropogenic intervention on terrestrial ecosystems. In this paper, two biogeographical (Neilson’s rule-based model and BIOME), two biogeochemical (BIOME-BGC and PnET-BGC), and three dynamic global vegetation models (Hybrid, LPJ, and MC1) were reviewed and compared in terms of their biophysical and physiological processes. The advantages and limitations of the models were also addressed. Lastly, the applications of the dynamic global vegetation models to regional climate simulations have been discussed.  相似文献   

Effect of stress history on CPT and DMT results in sand     

Moon-Joo Lee  Sung-Kun Choi  Min-Tae Kim  Woojin Lee 《Engineering Geology》2011,117(3-4):259-265

In order to investigate the effect of stress history on in-situ test results in granular sediments, a series of CPTs and DMTs are performed on Busan sand prepared in the calibration chamber. K_D is found to be the most sensitive to the stress history among CPT and DMT measurements. E_D and q_c are observed to be similarly affected by the stress history and, therefore, the E_D–q_c relation appears to be almost independent of the stress history. The K_D–D_R relation established without considering the stress history is likely to overestimate the relative density of OC sand. It is shown that the existence of the pre-stress of the granular sediment can be indirectly recognized by an estimation of the relative density larger than 100% when using the K_D–σ_v′–D_R relation suggested for NC sand. Although q_c/σ_v′–K_D/K₀ and E_D/σ_v′–K_D/K₀ relations are heavily influenced by the stress history, q_c/σ_m′–K_D/K₀ and E_D/σ_m′–K_D/K₀ relations are observed to be independent of the stress history. Based on these relations, charts to evaluate the K₀ value from q_c and/or DMT indices are developed for both NC and OC sands. The design chart based on E_D/σ_m′–K_D/K₀ and E_D/σ_v′–K_D/K₀ relations is expected to be practically useful as the usage of this chart requires only DMT indices. The developed design charts are applicable to Busan sand but different sets of equations and charts may be developed for other sands.  相似文献   

Modeling and control of a 75 kW class variable liquid-column oscillator for highly efficient wave energy converter     

Byung-Hak Cho  Dong-Soon Yang  Shin-Yeol Park  Kyung-Shik Choi  Do-Hwan Lee  Seung-Hyun Byun  Hoon Jung 《Ocean Engineering》2011,38(2-3):436-443

The modeling and control of a variable liquid-column oscillator having a liquid filled U-tube with air chambers at its vertical columns are presented. As an ocean wave energy extracting device, the structure of the variable liquid-column oscillator (VLCO) is analogous to that of the tuned liquid-column damper used to suppress oscillatory motion in large structures like tall buildings and cargo ships. However, owing to an air spring effect caused by the dynamic pressure of air chambers, the amplitude of response of the VLCO becomes significantly amplified for a desired wave period. The governing equations for the motion of VLCO structure under wave excitation and the motion of liquid with an air spring effect caused by an air–liquid interaction are described by a series of nonlinear differential equations. A set of control parameters for extracting maximum power from various wave conditions is determined for the efficient operation of the VLCO. It is found that the effect of the air spring has an important role to play in making the oscillation of the VLCO match with the ocean wave. In this way, the VLCO provides the most effective mode for extracting energy from the ocean wave.  相似文献   

A review of coal properties pertinent to carbon dioxide sequestration in coal seams: with special reference to Victorian brown coals   总被引：2，自引：1，他引：1  

M. S. A. Perera  P. G. Ranjith  S. K. Choi  A. Bouazza  J. Kodikara  D. Airey 《Environmental Earth Sciences》2011,64(1):223-235

This paper presents reviews of studies on properties of coal pertinent to carbon dioxide (CO₂) sequestration in coal with specific reference to Victorian brown coals. The coal basins in Victoria, Australia have been identified as one of the largest brown coal resources in the world and so far few studies have been conducted on CO₂ sequestration in this particular type of coals. The feasibility of CO₂ sequestration depends on three main factors: (1) coal mass properties (chemical, physical and microscopic properties), (2) seam permeability, and (3) gas sorption properties of the coal. Firstly, the coal mass properties of Victorian brown coal are presented, and then the general variations of the coal mass properties with rank, for all types of coal, are discussed. Subsequently, coal gas permeability and gas sorption are considered, and the physical factors which affect them are examined. In addition, existing models for coal gas permeability and gas sorption in coal are reviewed and the possibilities of further development of these models are discussed. According to the previous studies, coal mass properties and permeability and gas sorption characteristics of coals are different for different ranks: lignite to medium volatile bituminous coals and medium volatile bituminous to anthracite coals. This is important for the development of mathematical models for gas permeability and sorption behavior. Furthermore, the models have to take into account volume effect which can be significant under high pressure and temperature conditions. Also, the viscosity and density of supercritical CO₂ close to the critical point can undergo large and rapid changes. To date, few studies have been conducted on CO₂ sequestration in Victorian brown coal, and for all types of coal, very few studies have been conducted on CO₂ sequestration under high pressure and temperature conditions.  相似文献   

Numerical simulation of nearshore circulation on field topography under random wave environment     

Junwoo Choi  Sung Bum Yoon 《Coastal Engineering》2011

In order to investigate surf zone hydrodynamics through two-dimensional numerical simulations of nearshore circulation under random wave environment, a nearshore circulation model, SHORECIRC, and a random wave model, SWAN, were combined and utilized. Using this combined model, a numerical simulation of the October 2, 1997 SandyDuck field experiment was performed. For this simulation, field topography and an input offshore spectrum were constructed using observed data sets synchronized with the experiment. The wave-breaking model in SWAN was modified by using breaker parameters varied according to bottom slope. The simulation results were compared with the experimental data, which revealed a well-developed longshore current, as well as with results using other combinations which were SHORECIRC and its original monochromatic wave-driver, and SHORECIRC and the default of SWAN. The results from the novel combined model agreed well with the experimental data. The results of the present simulation also indicate that alongshore field topography influences shear fluctuation of longshore currents.  相似文献