化探背景与异常划分中的C型转换法     

陈明  范继璋  矫希国 《吉林大学学报(地球科学版)》1996,(2)

化学背景与异常在统计学上的差异同时表现在浓度和变差两个方面。在划分背景与异常时,把这两方面信息提取出来并作显化处理,使背景与异常的差别更大,以利划分,这就是Ｃ型转换的基本思想。介绍了Ｃ型转换法的基本原理及其在条件模拟和实际金矿区中的应用。  相似文献   

Gold Solubility in SiO2—HCl—H2O System at 200℃：a Preliminary Assessment of the Implications of Silicification with Regard to Gold Mineralization     

Shengyuan Wang  Wenling Fan 《中国地球化学学报》1994,13(1):13-23

The complexation between gold and silica was experimentally, confirmed and calibrated at 200 °C: $$\begin{gathered} Au^ + + H_3 SiO_4^ - \rightleftharpoons AuH_3 SiO_4^0 \hfill \\ \log K_{(200^\circ C)} = 19.26 \pm 0.4 \hfill \\ \end{gathered} $$ Thermodynamic calculations show that AuH₃SiO ₄ ⁰ would be far more abundant than AuCl ₂ ^? under physicochemical conditions of geological interest, suggesting that silica is much more important than chloride as ligands for gold transport. In systems containing both sulfur and silica, AuH₃SiO ₄ ⁰ would be increasingly more important than Au (HS) ₂ ^? as the proportion of SiO₂ in the system increases. The dissolution of gold in aqueous SiO₂ solutions can be described by the reaction: $$\begin{gathered} Au + 1/4O_2 + H_4 SiO_4^0 \rightleftharpoons AuH_3 SiO_4^0 + 1/2H_2 O \hfill \\ log K_{(200^\circ C)} = 6.23 \hfill \\ \end{gathered} $$ which indicates that SiO₂ precipitation is an effective mechanism governing gold deposition, and thus explains the close association of silicification and gold mineralization.  相似文献   

Two-dimensional pH distributions and dynamics in bioturbated marine sediments   总被引：2，自引：0，他引：2  

Qingzhi Zhu  Yanzhen Fan 《Geochimica et cosmochimica acta》2006,70(19):4933-4949

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.  相似文献   

Fluid unmixing/immiscibility as an ore-forming process in the giant REE–Nb–Fe deposit, Inner Mongolian, China: Evidence from fluid inclusions     

Hong-Rui Fan  Fang-Fang Hu  Kui-Feng Yang  Kai-Yi Wang 《Journal of Geochemical Exploration》2006,89(1-3):104

The giant Bayan Obo REE–Nb–Fe deposit consists of replacement bodies hosted in dolomite marble made up of magnetite, REE fluorocarbonates, fluorite, aegirine, amphibole, calcite and barite. Two or three phase CO₂-rich, three phase hypersaline liquid–vapor–solid, and two phase liquid-rich inclusions have been recognized in mineralized fluorite and quartz samples. Microthermometry measurements indicate that the carbonic phase in CO₂-rich inclusions is nearly pure CO₂. Fluids involving in REE–Nb–Fe mineralization at Bayan Obo might be mainly of H₂O–CO₂–NaCl–(F–REE) system. Coexistences of brine inclusions and CO₂-rich inclusions with similar homogenization temperatures give evidence that immiscibility happened during REE mineralization. An unmixing of an original H₂O–CO₂–NaCl fluid probably derived from carbonatitic magma. The presence of REE-carbonates as an abundant solid in fluid inclusions shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo.  相似文献   

辽东栎萌生个体的地上生物量及其构件分配与生长参数的关系   总被引：1，自引：0，他引：1  

孟令彬  包维楷  张咏梅  庞学勇  孙凡 《山地学报》2006,24(2):202-208

选择岷江上游海拔2100-2300m地段的辽东栎萌生株个体69株，测定了每株生长参数（年龄、高度、基径、冠幅）、各器官生物量及地上总生物量，分析了各器官生物量及构件分配与生长参数的相互关系。结果表明，辽东栎萌生株构件分配的大小排序为：茎干〉枝〉皮〉叶：随径级增大。茎干、大枝生物量所占总生物量比例上升，其他器官所占比例减小。辽东栎年龄与高度呈S曲线关系，其他均表现出很好的幂指数函数关系；各构件器官生物量与生长参数大多也呈幂指数函数W=aD^h（D为基径）关系。基径为估测辽东栎萌生株地上各器官生物量及总生物量的最佳因子。  相似文献   

采矿引起的边坡倾倒滑移变形机理与变形安全性分析研究—以抚顺西露天矿边坡为例   总被引：1，自引：0，他引：1  

申力  纪玉石  刘大勇  祖国林  刘晶辉 《中国地质灾害与防治学报》2006,17(3):63-68

在矿山开发、水电建设过程中倾倒变形问题日渐突出。倾倒变形边坡一般具有反倾边坡结构,变形的过程和机理比较复杂、涉及的变形岩体范围较大、危害严重。论文以抚顺西露天矿边坡为例,通过岩体位移监测资料的跟踪分析、底面摩擦模拟试验,以岩体力学、松散介质力学原理为理论基础,探讨了采矿影响下边坡倾倒滑移体的变形机理,分析认为采矿引起的倾倒滑移变形问题是在特定的地质构造和采矿工程条件下产生的,并提出了岩体变形安全性分析方法。通过工程实例,验证了方法的实用性,并针对实际问题提出了变形整治对策。  相似文献   

邢台矿区山字型构造的发现及其地质意义   总被引：1，自引：0，他引：1  

张纪勋  范志平 《中国煤田地质》2006,18(4):18-21

邢台山字型构造位于河北省邯邢煤田内，其前弧向ES突出，脊柱呈ES-WN走向。分别分析了山字型构造脊柱及其东、西翼反射弧构造形迹特征，对研究区找矿具有重要意义。  相似文献   

淮北煤田孙庄勘探区煤层气赋存规律及影响因素分析     

樊爱英 《中国煤田地质》2006,18(5):25-27

通过对淮北煤田孙庄勘探区地质构造、沉积特征、煤层煤质及煤层气赋存特征的分析，研究认为有利于本区煤层气赋存的主要因素是较大的埋藏深度、较高的壳质组＋镜质组、较高的变质程度、较大的煤层厚度、低透气性的盖层、较缓的地层倾角和封闭性较好的构造条件，推测煤田深部可能具有一定工业价值的煤层气资源。  相似文献   

氢化物发生-原子荧光光谱法测定地球化学样品中痕量碲   总被引：4，自引：4，他引：4  

范凡 《岩矿测试》2005,24(3):225-228

采用焙烧富集分离地球化学样品中痕量Te,并用氢化物发生原子荧光光谱法测定。通过实验确定出方法的最佳实验条件,在此条件下获得的检出限为0.005μg/g,线性范围0.025~10μg/g,精密度(RSD,n=8)为5.03%~9.24%。方法已用于国家一级地球化学标准物质中痕量Te的测定,结果与标准值基本相符。  相似文献   

过硫酸铵氧化容量法测定矿石中锰方法的改进   总被引：5，自引：1，他引：5  

范福南 《岩矿测试》2005,24(3):235-236

采用过硫酸铵氧化容量法测定锰时,可在低酸度(0.18mol/LH2SO4、0.29mol/LH3PO4)和大体积(300mL)溶液中氧化Mn2 至Mn7 。所测得的结果十分稳定,回收率为100%。采用管理样分析验证方法,其结果与铋酸钠容量法结果一致。对于w(Mn)=11.36%的试样进行10次分析测定,RSD=0.33%。方法可测定w(Mn)≥0.01%的常见矿种样品。  相似文献