Investigating the Halogen Chemistry From High-Latitude Nighttime Stratospheric Measurements of OClO and NO2     

Emmanuel Damien Rivière  Michel Pirre  Gwenaël Berthet  Jean-Baptiste Renard  Franck Lefèvre 《Journal of Atmospheric Chemistry》2004,48(3):261-282

Two cases of simultaneous nighttime measurements of NO₂ and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO₂ at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO₂ profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO₂ and of BrONO₂ occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO₂ and ClOONO, and to BrONO₂ and BrOONO, necessary to reproduce both OClO and NO₂ is given and discussed.  相似文献   

Seismic image of the deep crust at the eastern margin of the Alps (Austria): indications for crustal extension in a convergent orogen     

H. Graßl  F. Neubauer  K. Millahn  F. Weber 《Tectonophysics》2004,380(1-2):105-122

A 39-km-long deep seismic reflection profile recorded during two field campaigns in 1996 and 2002 provides a first detailed image of the deep crust at the eastern margin of the Eastern Alps (Austria). The ESE–WNW-trending, low-fold seismic line crosses Austroalpine basement units and extends approximately from 20 km west of the Penninic window group of Rechnitz to 60 km SSE of the Alpine thrust front.The explosive-source seismic data reveals a transparent shallow crust down to 5 km depth, a complexly reflective upper crust and a highly reflective lowermost crust. The upper crust is dominated by three prominent west-dipping packages of high-amplitude subparallel reflections. The upper two of these prominent packages commence at the eastern end of the profile at about 5 and 10 km depth and are interpreted as low-angle normal shear zones related to the Miocene exhumation of the Rechnitz metamorphic core complex. In the western portion of the upper crust, east-dipping and less significant reflections prevail. The lowermost package of these reflections is suggested to represent the overall top of the European crystalline basement.Along the western portion of the line, the lower crust is characterised by a 6–8-km-thick band of high-amplitude reflection lamellae, typically observed in extensional provinces. The Moho can be clearly defined at the base of this band, at approximately 32.5 km depth. Due to insufficient signal penetration, outstanding reflections are missing in the central and eastern portion of the lower crust. We speculate that the result of accompanying gravity measurements and lower crustal sporadic reflections can be interpreted as an indication for a shallower Moho in the east, preferable at about 30.5 km depth.The high reflectivity of the lowermost part of the lower crust and prominent reflection packages in the upper crust, the latter interpreted to represent broad extensional mylonite zones, emphasises the latest extensional processes in accordance with eastward extrusion.  相似文献   

Does fish scale morphology allow the identification of populations at a local scale? A case study for rostrum dace Leuciscus leuciscus burdigalensis in River Viaur (SW France)   总被引：1，自引：0，他引：1  

Nicolas Poulet  Yorick Reyjol  Hélène Collier  Sovan Lek 《Aquatic Sciences - Research Across Boundaries》2005,67(1):122-127

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Late Palaeozoic to Triassic evolution of the Turan and Scythian platforms: The pre-history of the Palaeo-Tethyan closure   总被引：2，自引：4，他引：2  

Boris A. Natal'in  A.M. Cell engr 《Tectonophysics》2005,404(3-4):175-202

A number of en échelon-arranged, southwest-facing arc fragments of Palaeozoic to Jurassic ages, sandwiched between two fairly straight east-northeast trending boundaries, constitute the basement of the Scythian and the Turan platforms located between the Laurasian and Tethyside units. They have until now largely escaped detection owing to extensive Jurassic and younger cover and the inaccessibility of the subsurface data to the international geological community. These units are separated from one another by linear/gently-curved faults of great length and steep dip. Those that are exposed show evidence of strike-slip motion. The arc units originally constituted parts of a single “Silk Road Arc” located somewhere south of the present-day central Asia for much of the Palaeozoic, although by the late Carboniferous they had been united into a continental margin arc south of the Tarim basin and equivalent units to the west and east. They were stacked into their present places in northern Afghanistan, Turkmenistan, Caucasus and the northern Black Sea by large-scale, right-lateral strike-slip coastwise transport along arc-slicing and arc-shaving strike-slip faults in the Triassic and medial Jurassic simultaneously with the subductive elimination of Palaeo-Tethys. This gigantic dextral zone (“the Silk Road transpression”) was a trans-Eurasian structure and was active simultaneously with another, similar system, the Gornostaev keirogen and greatly distorted Eurasia. The late Palaeozoic to Jurassic internal deformation of the Dniepr–Donets aulacogen was also a part of the dextral strain in southern Europe. When the emplacement of the Scythian and Turan units was completed, the elimination of Palaeo-Tethys had also ended and Neo-Tethyan arcs were constructed atop their ruins, mostly across their southern parts. The western end of the great dextral zone that emplaced the Turan and Scythian units horsetails just east of north Dobrudja and a small component goes along the Tornquist–Teisseyre lineament.  相似文献   

Étude expérimentale de la réactivité du CO2 supercritique vis-à-vis de phases minérales pures. Implications pour la séquestration géologique de CO2     

Olivier Regnault  Vincent Lagneau  Hubert Catalette  Hélène Schneider 《Comptes Rendus Geoscience》2005,337(15):1331-1339

Carbon dioxide sequestration in deep aquifers and depleted oilfields is a potential technical solution for reducing green-house gas release to the atmosphere: the gas containment relies on several trapping mechanisms (supercritical CO₂, CO_2(sc), dissolution together with slow water flows, mineral trapping) and on a low permeability cap-rock to prevent CO_2(sc), which is less dense than the formation water, from leaking upwards. A leakproof cap-rock is thus essential to ensure the sequestration efficiency. It is also crucial for safety assessment to identify and assess potential alteration processes that may damage the cap-rock properties: chemical alteration, fracture reactivation, degradation of injection borehole seals, etc. The reactivity of the host-rock minerals with the supercritical CO₂ fluid is one of the potential mechanisms, but it is altogether unknown. Reactivity tests have been carried out under such conditions, consisting of batch reactions between pure minerals and anhydrous supercritical CO₂, or a two-phase CO₂/H₂O fluid at 200?°C and 105/160 bar. After 45 to 60 days, evidence of appreciable mineral-fluid reactivity was identified, including in the water-free experiments. For the mixed H₂O/CO₂ experiments, portlandite was totally transformed into calcite; anorthite displayed many dissolution patterns associated with calcite, aragonite, tridymite and smectite precipitations. For the anhydrous CO₂ experiments, portlandite was totally carbonated to form calcite and aragonite; anorthite also displayed surface alteration patterns with secondary precipitation of fibrous calcite. To cite this article: O. Regnault et al., C. R. Geoscience 337 (2005).  相似文献   

Numerical simulation of percussive drilling          下载免费PDF全文

Alexandre Depouhon  Vincent Denoël  Emmanuel Detournay 《国际地质力学数值与分析法杂志》2015,39(8):889-912

This paper presents a novel dynamical model to analyze the long‐term response of a percussive drilling system. This departs from existing approaches that usually consider a single activation and bit/rock interaction cycle for the analysis of the process performance. The proposed model integrates the axial dynamics of an elastic piston and an elastic drill bit, a motion‐dependent pressure law to drive the piston, and a generalized bit/rock interaction law representative of the dynamic indentation taking place at the bit/rock interface. It applies to down‐the‐hole percussive drilling as well as top‐hole, with minor modifications. The model does not account for the angular motion or the hole cleaning, however. The model is first formulated mathematically; then, a finite‐dimensional approximation is proposed for computations. Numerical analyses of the model response, for a low‐size down‐the‐hole percussive system, follow. The period‐1 stationary response for the reference configuration is studied in detail, and parametric analyses assessing the influence on the rate of penetration of the bit/rock interaction parameters, the feed force, and the percussive activation parameters are conducted. These analyses reveal that the multiscale nature of the process is well captured by the model and recover expected trends for the influence of the parameters. They also suggest that a significant increase of the penetration rate can be achieved by increasing the percussive frequency. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Importance of climate,forest fires and human population size in the Holocene boreal forest composition change in northern Europe          下载免费PDF全文

Niina Kuosmanen  Heikki Seppä  Teija Alenius  Richard H. W. Bradshaw  Jennifer l. Clear  Ludmila Filimonova  Maija Heikkilä  Hans Renssen  Miikka Tallavaara  Triin Reitalu 《Boreas: An International Journal of Quaternary Research》2016,45(4):688-702

The relative importance of climate, forest fires and human population size on long‐term boreal forest composition were statistically investigated at regional and local scales in Fennoscandia. We employ pollen data from lakes, reflecting regional vegetation, and small forest hollows, reflecting local vegetation, from Russia, Finland and Sweden to reconstruct the long‐term forest composition. As potential drivers of the Holocene forest dynamics we consider climate, generated from a climate model and oxygen isotope data, past forest fires generated from sedimentary charcoal data and human population size derived from radiocarbon dated archaeological findings. We apply the statistical method of variation partitioning to assess the relative importance of these environmental variables on long‐term boreal forest composition. The results show that climate is the main driver of the changes in Holocene boreal forest composition at the regional scale. However, at the local scale the role of climate is relatively small. In general, the importance of forest fires is low both at regional and local scales. The fact that both climate and forest fires explain relatively small proportions of variation in long‐term boreal vegetation in small forest hollow records demonstrates the complexity of factors affecting stand‐scale forest dynamics. The relative importance of human population size was low in both the prehistorical and the historical time periods. However, this is the first time that this type of data has been used to statistically assess the importance of human population size on boreal vegetation and the spatial representativeness of the data may cause bias to the analysis.  相似文献   

Facies analysis of the Middle and Late Quaternary sediment infill of the northern Weihe Basin,Central China          下载免费PDF全文

Daniël S. Rits  Maarten A. Prins  Simon R. Troelstra  Ronald T. van Balen  Yan Zheng  Christiaan J. Beets  Bin Wang  Xiaoqiang Li  Jie Zhou  Hongbo Zheng 《第四纪科学杂志》2016,31(2):152-165

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Challenges of tracking extratropical cyclones in regional climate models     

Hélène Côté  Kevin M. Grise  Seok-Woo Son  Ramón de Elía  Anne Frigon 《Climate Dynamics》2015,44(11-12):3101-3109

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Dynamics of the January 2013–June 2014 explosive-effusive episode in the eruption of Volcán de Colima,México: insights from seismic and video monitoring     

Vyacheslav M. Zobin  Raúl Arámbula  Mauricio Bretón  Gabriel Reyes  Imelda Plascencia  Carlos Navarro  Armando Téllez  Arnoldo Campos  Miguel González  Zoraida León  Alejandro Martínez  Carlos Ramírez 《Bulletin of Volcanology》2015,77(4):1-13

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