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The sequestration of CO2 occurs naturally in (ultra)‐mafic rocks by carbonation processes and is commonly noted in areas of the seafloor where mantle lithologies are exhumed. As well as carbonation, mantle exhumation is also responsible for rock brecciation. The relationship between carbonation and brecciation is not well constrained. A temporal evolution from syn‐ to post‐tectonic carbonation and brecciation is proposed in line with progressive mantle exhumation. Using a petrological study of brecciated material from IODP drill cores of the Iberia–Newfoundland conjugated margins, we relate crack–seal veins to tectonic brecciation, authigenic calcite with scalenohedral structure to hydraulic brecciation and reworked clasts within cement to (tectono)‐sedimentary processes. Oxygen isotope compositions reveal late‐staged < 50°C carbonate generation in the proximal part of the ocean–continent transition, which have followed an earlier phase of sub‐seafloor carbonate generation. The results are crucial to understand CO2 exchange within the reworked sub‐seafloor in passive margins and oceanic systems. 相似文献
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The geothermal site of Lavey-les-Bains, Switzerland is an Alpine deep flow system in fractured crystalline rocks. Groundwater analyses since 1973 reveal a mixing process between a deep warm component (68°C and TDS 1.4 g/L) and cold shallow water. The production rate of the new deep well P600, installed in 1997, has amplified this mixing process in well P201, for which a decline in temperature and TDS has been observed. Numerical hydrogeological two-dimensional and three-dimensional models of heat, flow and mass transport have been developed to reproduce the geothermal system and to forecast the long-term exploitation potential of the geothermal resource. The computed temperature of the deep inferred reservoir (100–130°C) is in agreement with the geothermometers, whereas the simulated thermal water flux (5,400–9,000 m3/day) is probably underestimated. Different fluid production scenarios can reproduce the decline and stabilization phases of temperatures in the geothermal field since 1997. For P201, the mixing ratio calculated before and during the exploitation of P600 is comparable with observed data; the modelled temperature tends towards stabilization in P201 at 56°C after 10–15 years of production at P600. Another proposed new well is likely to reduce the thermal output of the existing wells. 相似文献
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Fernandez JM Ouillon S Chevillon C Douillet P Fichez R Le Gendre R 《Marine pollution bulletin》2006,52(3):320-331
Open-cast mining for Ni, Cr and Co was conducted in the south-west part of New Caledonia during the 20th century. Abandoned mining and prospecting sites were severely affected by erosion, resulting in an increase in the load of terrigenous particles transported to the coral reef lagoon. This article assesses the impact of a typical small catchment area (La Coulée River, 85 km2 watershed) on two bays (Boulari and Sainte Marie) located near Noumea, New Caledonia's main city. This multi-disciplinary study combines geochemical, sedimentological, and hydrodynamic approaches. Ni and Cr concentrations contained in the geochemical matrix phase of the pelitic fraction were determined. The study of the geochemical signatures together with sedimentological data and 3D numerical simulations of the transport of non-settling particles throughout the lagoon demonstrated that terrigenous inputs from the Coulée River were mainly transported and deposited along the shoreline, reaching areas as distant as Sainte Marie Bay. Although quantitatively low (about 3% of the pelite mass of the bay sediments), the terrigenous inputs in Sainte Marie Bay originating from the Coulée River could be traced. The metal content in suspended matter was over 7000 mg kg(-1) for Ni and 4200 mg kg(-1) for Cr. 相似文献
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PAH transport by sinking particles in the open Mediterranean Sea: a 1 year sediment trap study 总被引：1，自引：0，他引：1
Bouloubassi I Méjanelle L Pete R Fillaux J Lorre A Point V 《Marine pollution bulletin》2006,52(5):560-571
One year time series of sinking particles were collected at two depths in the open Mediterranean Sea and analysed for polycyclic aromatic hydrocarbons (PAH). Average total PAH concentrations were 593+/-284 ng g(-1) at 250 m and 551 +/- 198 ng g(-1) at 2850 m. Total PAH fluxes averaged 73 +/- 58 ng m(-2) d(-1) at 250 m and 53 +/- 39 ng m(-2) d(-1) at 2850 m. Contamination levels and, thus, exposure of marine organisms to PAH are comparable in surface and deep waters. Deep waters appear as a significant, yet overlooked, PAH sink. PAH temporal patterns show noticeable seasonality. This is partly due to varying levels of specific components such as the winter increase of pyrolytic PAH. Downward transport processes and the nature of sinking particles also impact on PAH fluxes, as inferred during periods of increasing productivity. Different phase-associations and interactions with particulate organic carbon for low-MW fossil PAH and high-MW pyrolytic PAH influence their downward transport efficiency. 相似文献
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Exhumation of eclogite and blueschist (Cyclades,Greece): Pressure–temperature evolution determined by thermobarometry and garnet equilibrium modelling 
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下载免费PDF全文 Valentin Laurent Pierre Lanari Inès Naïr Romain Augier Abdeltif Lahfid Laurent Jolivet 《Journal of Metamorphic Geology》2018,36(6):769-798
High‐P rocks such as eclogite and blueschist are metamorphic markers of palaeo‐subduction zones, and their formation at high‐P and low‐T (HP–LT) conditions is relatively well understood since it has been the focus of numerous petrological investigations in the past 40 years. The tectonic mechanisms controlling their exhumation back to the surface are, however, diverse, complex and still actively debated. Although the Cycladic Blueschist Unit (CBU, Greece) is among the best worldwide examples for the preservation of eclogite and blueschist, the proposed P–T evolution followed by this unit within the Hellenic subduction zone is quite different from one study to another, hindering the comprehension of exhumation processes. In this study, we present an extensive petrological data set that permits refinement of the shape of the P–T trajectory for different subunits of the CBU on Syros. High‐resolution quantitative compositional mapping has been applied to support the thermobarometric investigations, which involve semi‐empirical thermobarometry, garnet equilibrium modelling and P–T isochemical phase diagrams. The thermodynamic models highlight the powerful use of reactive bulk compositions approximated from local bulk compositions. The results are also combined with Raman spectrometry of carbonaceous material (RSCM) to retrieve the metamorphic peak temperature distribution at the scale of the island. A major result of this study is the good agreement between all the independent thermobarometric methods, permitting reconstruction of the prograde and retrograde P–T trajectories. Garnet compositional zoning was used to retrieve prograde, peak and retrograde growth stages in line with the results of the P–T isochemical phase diagrams, RSCM temperature and peak‐pressure crystallization of the garnet–omphacite–phengite assemblage. Our results are consistent with previous thermobarometric estimates from other occurrences of CBU rocks (Tinos, Andros), suggesting a multistage exhumation process with (1) early syn‐orogenic exhumation within the subduction channel, (2) isobaric heating at mid‐crustal depths (~10–12 kbar) following thermal re‐equilibration of the lithosphere from a cold syn‐orogenic regime in the subduction zone to a warmer post‐orogenic regime in the back‐arc domain and (3) exhumation and cooling related to a post‐orogenic phase of extension following slab retreat. Expanding to the general aspects of subduction zones, we suggest that such metamorphic evolution of HP–LT units should be regarded as a characteristic feature of exhumation driven by slab rollback. 相似文献
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Constraining a Flow Model with Field Measurements to Assess Water Transit Time Through a Vadose Zone
The modeling of thick vadose zones is particularly challenging because of difficulties in collecting a variety of measured sediment properties, which are required for parameterizing the model. Some models rely on synthetic data, whereas others are simplified by running as homogeneous sediment domains and relying on a single set of sediment properties. Few studies have simulated flow processes through a thick vadose zone using real and comprehensive data sets comprising multiple measurements. Here, we develop a flow model for a 7-m-thick vadose zone. This model, combining the numerical codes CTRAN/W with SEEP/W, includes the measured sediment hydraulic properties of the investigated vadose zone and incorporates the actual climate and subsurface conditions of the study site (precipitations, water-table elevations, and stable isotope data). The model is calibrated by fitting the simulated and measured vertical profiles of water content. Our flow model calculates a transit time of 1 year for the travel of water through the 7-m vadose zone; this estimate matches stable isotope-based results obtained previously for this site. A homogeneous sediment domain flow model, which considers only a single set of sediment properties, produces a transit time that is approximately half the duration of that of the heterogeneous flow model. This difference highlights the importance of assuming heterogeneous material within models of thick vadose zones and testifies to the advantage gained when using real sediment hydraulic properties to parametrize a flow model. 相似文献
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