Cold curation of pristine astromaterials: Insights from the Tagish Lake meteorite          下载免费PDF全文

Christopher D. K. Herd  Robert W. Hilts  Aaron W. Skelhorne  Danielle N. Simkus 《Meteoritics & planetary science》2016,51(3):499-519

The curation and handling of volatile‐bearing astromaterials is of prime importance in current and future plans for sample return missions to targets containing organic compounds, ices, or other volatile components. We report on the specific curation constraints required for the preservation of the Tagish Lake meteorite, a C2 ungrouped chondrite that contains significant concentrations of organic matter, including compounds of prebiotic interest or volatile in character, and which was recovered from a frozen lake surface a few days after its fall. Here, we review the circumstances of the meteorite's handling, its complement of intrinsic and contaminant organic compounds, and an unusual reaction between some of the specimens and the Al foil in which they were enclosed. From our results, we derive the requirements for curation of the meteorite, and describe a specialized facility that enables its curation and handling. The Subzero Facility for Curation of Astromaterials consists of a purified Ar glove box enclosed within a freezer chamber, and enables investigations relevant to curation of samples at or below ?10 °C. We provide several recommendations based on insights obtained from the commissioning and initial use of the facility that are relevant to collection of freshly fallen meteorites, curation of volatile‐bearing meteorites and other astromaterials, and planning and implementation of curation plans for future sample return missions to volatile‐bearing targets.  相似文献   

Stable isotopes of water reveal differences in plant – soil water relationships across northern environments     

Doerthe Tetzlaff  James Buttle  Sean K. Carey  Matthew J. Kohn  Hjalmar Laudon  James P. McNamara  Aaron Smith  Matthias Sprenger  Chris Soulsby 《水文研究》2021,35(1):e14023

We compared stable isotopes of water in plant stem (xylem) water and soil collected over a complete growing season from five well-known long-term study sites in northern/cold regions. These spanned a decreasing temperature gradient from Bruntland Burn (Scotland), Dorset (Canadian Shield), Dry Creek (USA), Krycklan (Sweden), to Wolf Creek (northern Canada). Xylem water was isotopically depleted compared to soil waters, most notably for deuterium. The degree to which potential soil water sources could explain the isotopic composition of xylem water was assessed quantitatively using overlapping polygons to enclose respective data sets when plotted in dual isotope space. At most sites isotopes in xylem water from angiosperms showed a strong overlap with soil water; this was not the case for gymnosperms. In most cases, xylem water composition on a given sampling day could be better explained if soil water composition was considered over longer antecedent periods spanning many months. Xylem water at most sites was usually most dissimilar to soil water in drier summer months, although sites differed in the sequence of change. Open questions remain on why a significant proportion of isotopically depleted water in plant xylem cannot be explained by soil water sources, particularly for gymnosperms. It is recommended that future research focuses on the potential for fractionation to affect water uptake at the soil-root interface, both through effects of exchange between the vapour and liquid phases of soil water and the effects of mycorrhizal interactions. Additionally, in cold regions, evaporation and diffusion of xylem water in winter may be an important process.  相似文献   

Using isotopes to understand landscape-scale connectivity in a groundwater-dominated,lowland catchment under drought conditions     

Lukas Kleine  Doerthe Tetzlaff  Aaron Smith  Tobias Goldhammer  Chris Soulsby 《水文研究》2021,35(5):e14197

The Demnitzer Millcreek catchment (DMC), is a 66 km² long-term experimental catchment located 50 km SE of Berlin. Monitoring over the past 30 years has focused on hydrological and biogeochemical changes associated with de-intensification of farming and riparian restoration in the low-lying landscape dominated by rain-fed farming and forestry. However, the hydrological function of the catchment, which is closely linked to nutrient fluxes and highly sensitive to climatic variability, is still poorly understood. In the last 3 years, a prolonged drought period with below-average rainfall and above-average temperatures has resulted in marked hydrological change. This caused low soil moisture storage in the growing season, agricultural yield losses, reduced groundwater recharge, and intermittent streamflows in parts of an increasingly disconnected channel network. This paper focuses on a two-year long isotope study that sought to understand how different parts of the catchment affect ecohydrological partitioning, hydrological connectivity and streamflow generation during drought conditions. The work has shown the critical importance of groundwater storage in sustaining flows, basic in-stream ecosystem services and the dominant influence of vegetation on groundwater recharge. Recharge was much lower and occurred during a shorter window of time in winter under forests compared to grasslands. Conversely, groundwater recharge was locally enhanced by the restoration of riparian wetlands and storage-dependent water losses from the stream to the subsurface. The isotopic variability displayed complex emerging spatio-temporal patterns of stream connectivity and flow duration during droughts that may have implications for in-stream solute transport and future ecohydrological interactions between landscapes and riverscapes. Given climate projections for drier and warmer summers, reduced and increasingly intermittent streamflows are very likely not just in the study region, but in similar lowland areas across Europe. An integrated land and water management strategy will be essential to sustaining catchment ecosystem services in such catchment systems in future.  相似文献   

A comparison of two models to predict soil moisture from remote sensing data of RADARSAT II     

Jawad Al-Bakri  Ayman Suleiman  Aaron Berg 《Arabian Journal of Geosciences》2014,7(11):4851-4860

This study investigates the performance of empirical and semiempirical models to predict soil moisture from the data of RADARSAT II synthetic aperture radar (SAR) for the Yarmouk basin in Jordan. Data of SAR were obtained for May and June 2010 and were processed to obtain backscatter (σ ^o ) data for the study area. Results showed significant correlations between soil moisture content (m _v ) and horizontally polarized σ ^o , with coefficient of determination (R ²) of 0.64. The root mean square error for the SAR volumetric soil moisture content was 0.09 and 0.06 m³/m³ for the empirical and semiempirical regression models, respectively. Both models had different clustering patterns in the soil moisture maps in the study area. The spatial agreement between maps of soil moisture was in the range of 55 to 65 % when the maps were reclassified based on intervals of 5 % m _v for both models. In terms of soil moisture interval, both models showed that most of soil moisture changes between the two images (dates) were in the range of ±5 %. Some high differences in ?m _v were observed between the two models. These were mainly attributed to the non-inverted pixels in the soil moisture maps produced by the semiempirical model. Therefore, this model may be applied for a limited range of soil moisture prediction. The use of regression model could predict a wider range for soil moisture when compared with the semiempirical model. However, more work might be needed to improve the empirical model before scaling it up to the whole study area.  相似文献   

Rising powers: the evolving role of BASIC countries     

Karl Hallding  Marie Jürisoo  Marcus Carson  Aaron Atteridge 《Climate Policy》2013,13(5):608-631

The exponential growth in global populations, economic activity and resource utilization means it is becoming increasingly difficult to satisfy global demand for a number of fundamental resources, while some key ecosystems services are under stress. The likelihood of future resource scarcities have begun to influence the positions taken within international climate change negotiations by fast-growing developing countries. When Brazil, South Africa, India, and China formed the BASIC group it took many by surprise. The coordination needed to align this heterogeneous group of countries cannot simply be understood in terms of a set of shared interests around climate policy. How the BASIC group emerged and the nature of its cooperation on climate change are examined within the broader context in which these increasingly powerful countries came to join forces. Although traditionally aligned with the G77 group of developing countries, recent strategising as a group of emerging economies reflects their realization that there are insufficient global resources available to follow the same development pathway as industrialized countries. Hence, they must seek alternative growth pathways, which requires establishing common ground while also keeping track of each others' positions on important global issues like climate change.  相似文献   

Nonsingular vectorial reformulation of the short-period corrections in Kozai’s oblateness solution     

Izzo  Paolo  Dell’Elce  Lamberto  Gurfil  Pini  Rosengren  Aaron J. 《Celestial Mechanics and Dynamical Astronomy》2022,134(2):1-83

We present fully three-dimensional equations to describe the rotations of a body made of a deformable mantle and a fluid core. The model in its essence is similar to that used by INPOP19a (Integration Planétaire de l’Observatoire de Paris) Fienga et al. (INPOP19a planetary ephemerides. Notes Scientifiques et Techniques de l’Institut de Mécanique Céleste, vol 109, 2019), and by JPL (Jet Propulsion Laboratory) (Park et al. The JPL Planetary and Lunar Ephemerides DE440 and DE441. Astron J 161(3):105, 2021. doi:10.3847/1538-3881/abd414), to represent the Moon. The intended advantages of our model are: straightforward use of any linear-viscoelastic model for the rheology of the mantle; easy numerical implementation in time-domain (no time lags are necessary); all parameters, including those related to the “permanent deformation”, have a physical interpretation. The paper also contains: (1) A physical model to explain the usual lack of hydrostaticity of the mantle (permanent deformation). (2) Formulas for free librations of bodies in and out-of spin-orbit resonance that are valid for any linear viscoelastic rheology of the mantle. (3) Formulas for the offset between the mantle and the idealised rigid-body motion (Peale’s Cassini states). (4) Applications to the librations of Moon, Earth, and Mercury that are used for model validation.

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Race,Space, and Struggles for Mobility: Transportation Impacts on African Americans in Oakland and the East Bay     

Aaron Golub  Richard A. Marcantonio  Thomas W. Sanchez 《Urban geography》2013,34(5):699-728

Abstract

A long history of overt discrimination left an enduring racialized imprint upon the geography of the East Bay. While the benefits of a metropolitan decentralization of jobs, housing, and public investment fell to Whites, discrimination in employment and housing trapped African Americans in urban neighborhoods burdened by infrastructure encroachment and divestment. By circa 1970, overt discrimination succumbed to new, racially neutral, legal, and administrative forms, including regional planning processes. Using an environmental racism framework, we show that these new forms reproduced the existing racialized geography by means of new inequalities in representation and transportation service provision. These new regional transportation policies, like those challenged by a 2005 civil rights lawsuit, favored the mobility needs of more affluent suburbanites over those of African American East Bay bus riders. These policies, layered onto an existing racialized geography, reinforced existing inequalities by failing to address racial barriers to opportunity in the built environment. [Key words: transportation, race, segregation, Oakland]  相似文献   

How to overcome inter-electrode variability and instability to quantify dissolved oxygen, Fe(II), mn(II), and S(?II) in undisturbed soils and sediments using voltammetry     

Slowey AJ  Marvin-Dipasquale M 《Geochemical transactions》2012,13(1):6-20

Background

Although uniquely capable of measuring multiple redox constituents nearly simultaneously with no or minimal sample pretreatment, voltammetry is currently underutilized in characterizing redox conditions in aquatic and terrestrial systems. Investigation of undisturbed media such as pore water requires a solid-state electrode, and such electrodes can be difficult to fabricate reproducibly. An approach to determine the concentrations of electroactive constituents using indirectly calibrated electrodes has been developed, but the protocol for and accuracy of this approach??the pilot ion method??has not been documented in detail.

Results

A detailed procedure for testing electrode quality is provided, and the application and limitations of the pilot ion method have been documented. To quantify Fe(II) and Mn(II), subtraction of non-linear baseline functions from voltammetric signals produced better calibration curves than did linear baselines, enabled lower detection limits and reliable deconvolution of overlapping signals, and was successfully applied to sediment pore water signals. We observed that electrode sensitivities often vary by tens of percent, and that the sensitivity declines over time. The ratio of calibration slopes of Mn(II) to Fe(II) varied by no more than 11% from one Hg/Au electrode to another and Fe(II) concentrations predicted by the Mn(II) pilot ion were, on average, 13% different from their actual values. However, concentration predictions by the pilot ion method were worse for less than 15???M Fe(II) (46% different on average). The ratio of calibration slopes of Mn(II) to S(?II) varied by almost 20% from one Hg/Au electrode to another, and S(?II) predicted concentrations were as much as 58% different from their actual values. These predictions of Fe(II) and S(?II) concentrations indicate that the accuracy of the pilot ion method depends on how independent calibration slope ratios are from the electrode used. At medium-to-high concentration for the ocean, naturally derived dissolved organic carbon did not significantly affect the baseline-corrected electrode response of Mn(II) and Fe(II), but did significantly affect the response of S(?II).

Conclusions

Despite their intrinsic variability, Hg/Au electrodes fabricated by hand can be used to quantify O₂, S(?II), Fe(II), and Mn(II) without calibrating every electrode for every constituent of interest. The pilot ion method can achieve accuracies to within 20% or less, provided that the underlying principle??the independence of slope ratios??is demonstrated for all voltammetric techniques used, and effects of the physicochemical properties of the system on voltammetric signals are addressed through baseline subtraction.  相似文献   

Platelet development in cuboid diamonds: insights from micro-FTIR mapping   总被引：1，自引：1，他引：0  

D. Howell  C. J. O’Neill  K. J. Grant  W. L. Griffin  S. Y. O’Reilly  N. J. Pearson  R. A. Stern  T. Stachel 《Contributions to Mineralogy and Petrology》2012,164(6):1011-1025

Fourier transform infrared mapping of diamonds can reveal detailed information on impurities, with a spatial context. We apply this technique, combined with in situ isotopic analysis of carbon, to the study of cuboid diamond growth in a sample that exhibits some mixed-habit growth. While there has been some uncertainty in the literature regarding sectoral differences in nitrogen aggregation and subsequent platelet development, the data from this study appear far more conclusive. We show that despite nitrogen being concentrated in octahedral sectors, there is no detectable difference in the concentration-adjusted rate of nitrogen aggregation within octahedral and cuboid sectors. However, the resultant platelet development is significantly reduced in cuboid sectors compared to contemporaneously formed octahedral sectors. This finding has significant implications for the classification of diamonds using the relationship between their platelet intensity and the absorption caused by B centres. It means that cuboid diamonds naturally fall below the linear relationship that has been termed regular, which would lead to them being incorrectly interpreted as having experienced heating or deformation. The data also support earlier suggestions that large hydrogen concentrations in the diamond-forming fluid may be required for cuboid growth. We further suggest that high nitrogen and hydrogen concentrations are required for mixed-habit diamond growth, which might be the product of specific fluid chemistries that occur in reducing mantle environments.  相似文献   

Identifying scale-location specific control on vegetation distribution in mountain-hill region   总被引：1，自引：0，他引：1  

QIU Bing-wen  ZENG Can-ying  TANG Zheng-hong  LI Wei-jiao  Aaron HIRSH 《山地科学学报》2013,10(4):541-552

The scale-location specific control on vegetation distribution was investigated through continuous wavelet transforms approaches in subtropical mountain-hill region, Fujian, China. The Normalized Difference Vegetation Index (NDVI) was calculated as an indicator of vegetation greenness using Chinese Environmental Disaster Reduction Satellite images along latitudinal and longitudinal transects. Four scales of variations were identified from the local wavelet spectrum of NDVI, with much stronger wavelet variances observed at larger scales. The characteristic scale of vegetation distribution within mountainous and hilly regions in Southeast China was around 20 km. Significantly strong wavelet coherency was generally examined in regions with very diverse topography, typically characterized as small mountains and hills fractured by rivers and residents. The continuous wavelet based approaches provided valuable insight on the hierarchical structure and its corresponding characteristic scales of ecosystems, which might be applied in defining proper levels in multilevel models and optimal bandwidths in Geographically Weighted Regression.  相似文献