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In this work, we use Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (13C NMR) data to quantify the changes of major chemical compound classes (carboxylic acid, amide, ester, aliphatic, aromatic and carbohydrate) in high molecular weight (HMW, >1 kDa) dissolved organic matter (DOM) isolated along a transect through the Elizabeth River/Chesapeake Bay system to the coastal Atlantic Ocean off Virginia, USA. Results show that carboxylic acids and aromatic compounds are lost along the transect, while HMW DOC becomes enriched in carbohydrate moieties that could have a mid-transect source, perhaps the intensive red tide bloom (Choclodinium polykrikoides) which occurred during our sampling period. Taking the second derivative of the FTIR spectra resolved three pools of de-protonated carboxylic acids at our Dismal Swamp site (used to represent terrestrial organic matter in this area): one carboxylic acid pool, complexed with iron, seems to be lost between the Dismal Swamp and river sites; the second appears biogeochemically active throughout the riverine transect, disappearing in the coastal ocean sample; the third seems refractory, with the potential to be transported to and to accumulate within the open ocean. Five-member ring esters (γ-lactones) were the major ester form in the Dismal Swamp; aliphatic and acetate esters were the dominant esters in the estuary/marine DOM. No amide groups were detectable in Dismal Swamp DOM; secondary amides were present at the estuarine/marine sites. Coupling FTIR with 13C NMR provides new insights into the biogeochemical roles of carboxylic acid, amide and ester compounds in aquatic ecosystems. 相似文献
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和田河夏季流量对区域0℃层高度变化的响应 总被引：1，自引：0，他引：1
利用和田市气象站的0℃层高度,和田河上游乌鲁瓦提和同古孜洛克水文站的实测流量资料,以及NCEP/NCAR 500 hPa月平均温度资料,分析了和田河夏季流量的变化、同期流域内0℃层高度情况以及500 hPa温度的特征。结果显示：1961-2004年,和田河夏季流量、和田站0℃层高度均呈不显著的线性下降趋势,在1979年分别出现了由丰到枯、由高到低的突变。和田河夏季流量典型偏丰、偏枯年同期500 hPa温度距平场有显著差异。在年代际和年际尺度上,和田河夏季流量对流域内0℃层高度变化都有明显的响应。 相似文献