Identification and occurrence of novel C₃₆–C₅₄ 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments     

M.E.L. Kohnen  T.M. Peakman  J.S.Sinninghe Damste  J.W. de Leeuw 《Organic Geochemistry》1990,16(4-6)

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.  相似文献   

Geophysical investigations of the Platanares geothermal site, Honduras, Central America     

Carlos L. Aiken  Mark E. Ander  Mauricio F. de la Fuente 《Journal of Volcanology and Geothermal Research》1991,45(1-2)

Geophysical studies were carried out in Platanares in Western Honduras, as part of an investigation of the geothermal resource potential of Honduras by Los Alamos National Laboratory in cooperation with the Honduran government and the U.S. Geological Survey. Geological and geochemical studies later followed by exploratory bore-holes indicate this area of rugged topography has the best geothermal potential in Honduras. In order to better understand the geology of the area, gravity, audiomagnetotelluric and telluric surveys were carried out. The site is in a graben of Tertiary volcanics and Cretaceous red beds, with numerous hot springs along faults in the center of the graben. Gravity mapped the thickness of low-density tuffs and the position of associated normal faults. It also indicated the presence of persuasive, shallow, highly silicified, high-density tuffs and gravels. The electrical surveys mapped shallow, high-resistivity silicified zones and faults as low-resistivity zones. The red beds below the tuffs are considered to contain the geothermal reservoir, but their maximum thickness could not be determined by these surveys due to the lack of density contrast and the high surface electrical conductivities. Three geologic cross-sections constructed by others have been re-evaluated using gravity modeling and analysis of eletrical anomalies, showing general agreement but in detail significant differences.  相似文献   

Andesite and dacite genesis via contrasting processes: the geology and geochemistry of El Valle Volcano,Panama   总被引：3，自引：0，他引：3  

Mare J. Defant  Lee F. Clark  Robert H. Stewart  Mark S. Drummond  Jelle Z. de Boer  René C. Maury  Hervé Bellon  Thomas E. Jackson  Juan F. Restrepo 《Contributions to Mineralogy and Petrology》1991,106(3):309-324

The easternmost stratovolcano along the Central American arc is El Valle volcano, Panama. Several andesitic and dacitic lava flows, which range in age 5–10 Ma, are termed the old group. After a long period of quiescence (approximately 3.4 Ma), volcanic activity resumed approximately 1.55 Ma with the emplacement of dacitic domes and the deposition of dacitic pyroclastic flows 0.9–0.2 Ma. These are referred to as the young group. All of the samples analyzed are calc-alkaline andesites and dacites. The mineralogy of the two groups is distinct; two pyroxenes occur in the old-group rocks but are commonly absent in the young group. In contrast, amphibole has been found only in the young-group samples. Several disequilibrium features have been observed in the minerals (e.g., oscillatory zoning within clinopyroxenes). These disequilibrium textures appear to be more prevalent among the old- as compared with the young-group samples and are most likely the result of magma-mixing, assimilation, and/or polybaric crystallization. Mass-balance fractionation models for major and trace elements were successful in relating samples from the old group but failed to show a relationship among the young-group rocks or between the old- and young-group volcanics. We believe that the old-group volcanics were derived through differentiation processes from basaltic magmas generated within the mantlewedge. The young group, however, does not appear to be related to more primitive magmas by differentiation. The young-group samples cannot be related by fractionation including realistic amounts of amphibole. Distinctive geochemical features of the young group, including La/Yb ratios〉15, Yb〈1, Sr/Y〉150, and Y〈6, suggest that these rocks were derived from the partial melting of the subducted lithosphere. These characteristics can be explained by the partial melting of a source with residual garnet and amphibole. Dacitic material with the geochemical characteristics of subducted-lithosphere melting is generated apparently only where relatively hot crust is subducted, based on recent work. The young dacite-genesis at El Valle volcano is related to the subduction of relatively hot lithosphere.  相似文献   

Influence of basement structures on the evolution of the major sedimentary basins of Brazil: A case of tectonic heritage     

B.B. de Brito Neves  R.A. Fuck  U.G. Cordani  A. Thomaz F 《Journal of Geodynamics》1984,1(3-5)

The present study deals with the correlation between the geotectonic features of the basement and the internal structure, shape, geologic evolution, etc. of the major sedimentary basins of the South American platform. The Paraná, Parnaíba and Amazonas basins occupy an area of the order of 3.6 × 10⁶ km², and their sedimentary cratonic sequences were deposited from Silurian to Triassic times. Subsidence rates are estimated around 15 m/Ma in the main depocenters.A geologic study was carried out along the basement features in the surroundings of such basins in order to identify the major structural, geotectonic and geochronological discontinuities. The extension of these basement characteristics towards the interior of the basins are examined. Basement core samples from deep wells were investigated through petrological and geochronological analyses, and pre-existing geophysical and structural maps of those basins were taken again into consideration.It can be concluded that many of the identified basement discontinuities display a direct influence on the depositional history of the basins as well as on their internal subdivisions and external outlines. Basement structures generated during the late Precambrian Brasiliano Cycle turned out to be particularly important.The Paraná and Parnaíba basins are considered to represent cratonic basins, located on rigid lithosphere, tectonically stabilized in the latest Precambrian/early Palaeozoic, and their subsidence is attributed to the establishement of some initial rifted grabens. The Amazonas basin is more complex and includes three large sub-basins with distinct evolutions, each located on a different tectonic segment of the basement.  相似文献   

Carbohydrates in recent marine sediments—II. Occurrence and fate of carbohydrates in a recent stromatolitic deposit: Solar Lake,Sinai     

J. Klok  H.C. Cox  M. Baas  J.W. de Leeuw  P.A. Schenck 《Organic Geochemistry》1984,7(2):101-109

In a study on the diagenesis of carbohydrates in a recent stromatolitic deposit (Solar Lake, Sinai) monosaccharides are quantitated after mild acid hydrolysis and gas chromatographic analysis as alditol acetates. From the depth profiles of the individual monosaccharides relative to the total organic carbon three categories of carbohydrates can be distinguished. The behaviour of the various categories upon burial is discussed in terms of their potential to become a part of the organic matter that survives geological periods. The distribution patterns of especially the mono-O-methyl monosaccharides at various depths are characteristics for the bacterial communities present in the corresponding parts of the sediment column.  相似文献   

Belowground productivity of roots and rhizomes in a giant cordgrass marsh     

Courtney T. Hackney  Armando A. de la Cruz 《Estuaries and Coasts》1986,9(2):112-116

Belowground production of roots and rhizomes in the top 20 cm of soil was 2.2 kg m^?2 yr^?1 based on a maximum minus minimum estimation procedure in a giant cordgrass (Spartina cynosuroides (L.) Roth) marsh in Mississippi. Approximately 1.9 kg m^?2 (86%) of this production occurred in late spring-summer and 0.3 kg m^?2 in late fall. This estimate ignores any production below 20 cm depth and is thus an underestimate. Production values increased to 4.0 kg m^?2 yr^?1 using Smalley’s technique and accounting for decomposition. Aboveground tissues (leaves and stems) were depleted in nitrogen in July which corresponded to peaks in both above- and belowground biomass. The low root/shoot ratio (2.6) on this marsh does not suggest that growth is nutrient limited. Indeed, total productivity (above- and belowground) for this marsh was high (between 4.4 and 6.2 kg m^?2 yr^?1).  相似文献   

Variations of solar EUV,UV and ionospheric foF2 related to the solar rotation period     

R. P. Kane  E. R. de Paula  N. B. Trivedi 《Annales Geophysicae》1995,13(7):717-723

Spectral analysis of daily values of various solar indices viz. sunspot number, 10.7-cm flux, H Lyman-<alpha> and -<beta>, specific He, Fe and Mg lines and solar X-rays was carried out for two selected intervals. During interval A (May-August 1978, 123 days) the solar indices showed a prominent periodicity near 27 days, while during interval B (January-May 1979, 151 days) the solar indices showed a prominent periodicity near 13 days. For the same intervals, foF2 (max) and foF2 (average) during 1000–1500 LT were similarly analysed for the locations Cachoeira Paulista, SP, Brazil (23○S, 45○W), and Okinawa (26○N, 128○E) and Kokubunji (36○N, 139○E) in Japan. The 27-day and 13-day periodicities in solar indices were reflected in the foF2 series, but in different relative proportions at the three locations, probably due to the interference of local aerodynamical effects. Some other periodicities were common to solar indices and foF2, while some others were present in the solar indices but not in foF2, or vice versa.  相似文献   

Seasonal expansion and contraction of stream networks in shallow groundwater systems     

J. J. de Vries 《Journal of Hydrology》1995,170(1-4):15-26

Surface water and groundwater are normally closely connected in areas with shallow aquifer systems. Stream systems can thus be considered as the outcrops of associated groundwater flows in areas with a shallow groundwater table and a previous subsurface. This situation prevails in sandy lowland areas where almost all rainfall percolates into the subsurface so that the surplus over evapotranspiration becomes part of a groundwater drainage system before it reappears at the surface in a stream. The stream network, being the interface with the groundwater system, must have the capacity to release the seasonally dependent precipitation surplus through the continuum of ground and surface waters. A river network therefore consists of a hierarchical system of different order and incision depth, of which the discharge-contributing component contracts and expands with the seasonal fluctuation in recharge and water table depth.

Coupling the mathematical expressions for groundwater drainage and stream flow enables development of a conjunctive model which relates the properties of a seasonally contracting and expanding stream network and related groundwater level fluctuation to the seasonal rainfall character for given geological and geomorphological conditions. This model further allows for assessment of drainage network response to a changing environment.  相似文献   

A study of objective methods for water mass analysis,applied to the Iceland Basin     

de Boer  Cathy J.  van Aken  Hendrik M. 《Ocean Dynamics》1995,47(1):5-22

Ocean Dynamics - Cluster analysis and principal component analysis have been applied to multi-parameter hydrographic data from the Iceland Basin. The results indicate that both objective methods...  相似文献   

Sulphur-containing compounds in sulphur-rich crude oils from hypersaline lake sediments and their geochemical implications   总被引：1，自引：0，他引：1  

Guoying Sheng  Jiamo Fu  S. C. Brassell  A. P. Gowar  G. Eglinton  Jaap S. Sinninghe Damste  Jan W. de Leeuw  P. A. Schenck 《中国地球化学学报》1987,6(2):115-126

Three sulphur-rich commercial crude oils have been studied, which contain sulphur as high as up to 4–12%. These samples were collected from Tertiary hypersaline lake sediments of the Jianghan Basin, Hubei Province at different depths, but above the oil generation threshold (2200m). FPD-GC and GC-MS data show that aromatic fractions of the crude oils are composed of different homologues of sulphur-containing compounds, including long-chain normal alkyl-thiophenes and-thiolanes, long-chain isoprenoid-thiophenes and -thiolanes, and benzothiophenes. It is worth noting that the distribution patterns of long-chain alkyl-thiophenes and -thiolanes from two shallow-seated crude oils are quite similar to those of normal alkanes showing marked even-odd predominance. It seems that the even-odd predominance of sulphur-containing compounds decreases with increasing burial depth of the crude oils. The major component of aliphatic fraction is phytane, and similarly the major peaks of aromatic fractions also represent C₂₀ isoprenoid thiophenes. Some preliminary conclusions have been drawn from the above discussion: (1) Abundant sulphur-containing compounds may be used as an indicator of low mature or immature crude oils produced from hypersaline lake sediments; (2) Sulphur-containing compounds are considered to be early diagenetic products of reactions between elemental sulphur or sulfides and alkanes or their precursors (phytols, fatty acids, alcohols, etc.), or of bacterial activities, but not direct inputs of organisms.  相似文献