Polycyclic aromatic hydrocarbons, polychlorinated biphenyls and organochlorine pesticides in urban air of Konya, Turkey     

Senar Ozcan  Mehmet Emin Aydin   《Atmospheric Research》2009,93(4):715-722

Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were determined in urban air samples of Konya, Turkey between August 2006 and May 2007. The concentrations of pollutants in both the gas and particulate phase were separately analysed. The average total (gas + particulate) concentrations of PAHs, PCBs and OCPs were determined as 206 ng m^− 3, 0.106 ng m^− 3, 4.78 ng m^− 3 respectively. All of the investigated target compounds were dominantly found in the gas phase except OCPs. Higher air concentrations of PAHs were found at winter season while the highest concentrations of PCBs were determined in September. The highest OCPs were detected in October and in March. In urban air of Konya, PCB 28 and PCB 52 congeners represent 46% and 35% of total PCBs while Phenanthrene, Fluoranthene, Pyrene accounted for 29%, 13%, 10% of total PAHs. HCH compounds (α + β + γ + δ-HCH), total DDTs (p,p′-DDE, p,p′-DDD, p,p′-DDT), Endosulfan compounds (Endosulfan I, Endosulfan II, Endosulfan sulfate) were dominantly determined as 30%, 21%, 20% of total OCPs respectively. Considering the relation between these compounds with temperature, there was no significant correlation observed. Despite banned/restricted use in Turkey, some OCPs were determined in urban air. These results demonstrated that they are either illegally being used in the course of agricultural activity and gardens in Konya or they are residues of past use in environment. According to these results, it can be suggested that Konya is an actively contributing region to persistent organic pollutants in Turkey.  相似文献   

Generation of the Early Cenozoic adakitic volcanism by partial melting of mafic lower crust,Eastern Turkey: Implications for crustal thickening to delamination     

Orhan Karsli  Abdurrahman Dokuz  İbrahim Uysal  Faruk Aydin  Raif Kandemir  Jan Wijbrans 《Lithos》2010,114(1-2):109-120

Early Cenozoic (48–50 Ma) adakitic volcanic rocks from the Eastern Pontides, NE Turkey, consist of calc-alkaline and high-K calc-alkaline andesite and dacite, with SiO₂ contents ranging from 56.01 to 65.44 wt.%. This is the first time that Early Eocene volcanism and adakites have been reported from the region. The rocks are composed of plagioclase, amphibole, quartz, and Mg-rich biotite. They have high and low-Mg# values ranging from 55 to 62 and 13 to 42, respectively. High-Mg# rocks have higher Ni and Co contents than low-Mg# samples. The rocks exhibit enrichments in large ion lithophile elements including the light rare earth elements, depletions in Nb, Ta and Ti and have high La/Yb and Sr/Y ratios. Their relative high I_Sr (0.70474–0.70640) and low ε_Nd (50 Ma) values (? 2.3 to 0.8) are inconsistent with an origin as partial melts of a subducted oceanic slab. Combined major- and trace element and Sr–Nd isotope data suggest that the adakitic magmas are related to the unique tectonic setting of this region, where a transition from a collision to an extension stage has created thickening and delamination of the Pontide mafic lower crust at 50 Ma. The high-Mg adakitic magmas resulted from partial melting of the delaminated eclogitic mafic lower crust that sank into the relatively hot subcrustal mantle, and its subsequent interaction with the mantle peridotite during upward transport, leaving garnet as the residual phase, elevates the MgO content and Mg# of the magmas, whereas low-Mg# magmas formed by the melting of newly exposed lower crustal rocks caused by asthenospheric upwelling, which supplies heat flux to the lower crust. The data also suggest that the mafic lower continental crust beneath the region was thickened between the Late Cretaceous and the Late Paleocene and delaminated during Late Paleocene to Early Eocene time, which coincides with the initial stage of crustal thinning caused by crustal extensional events in the Eastern Pontides and rules out the possibility of an extensional regime before ~ 50 Ma in the region during the Late Mesozoic to Early Cenozoic.  相似文献   

Nucleation and growth of strike-slip faults in limestones from Somerset, U.K.     

Emanuel J.M. Willemse  David C.P. Peacock  Atilla Aydin 《Journal of Structural Geology》1997,19(12):1461-1477

Small-scale structures along strike-slip fault zones in limestones exposed around the Bristol Channel, U.K., suggest that pressure solution plays a key role during fault nucleation and growth. Incipient shear zones consist of enéchelon veins. The first generation of solution seams form due to bending of the intact rock (bridge) between overlapping veins. As the bridge rotates, slip occurs along the seams, linking the veins, causing cm-scale calcite-filled pull-apart structures to form and allowing fault displacement to increase. A second generation of solution seams forms at the tip of the sliding seams. As displacement increases further, causing larger rotation, slip also can occur along these second-generation solution seams, producing the third generation of solution seams as well as tail cracks (pinnate veins) at their tips. These three generations of solution seams all contribute to the formation of individual fault segments. Fourth and fifth generations of solution seams occur within larger-scale contractional oversteps between side-stepping fault segments. The oversteps are breached by slip along these localized solution seams, eventually leading to the formation of a distinct through-going fault with several metres of displacement.The initial enéchelon veins, solution seams of various generations and tail cracks progressively fragment the fault-zone material as fault slip accumulates. Slip planes nucleate on these pre-existing discontinuities, principally along the clay-enriched, weaker solution seams. This can be observed at a variety of scales and suggests that Mode II shear fracturing does not occur as a primary fracture mechanism, but only as a macroscopic phenomenon following Mode I (veins and tail cracks) and anti-mode I (solution seams) deformation. It appears that solution seams can play a similar role to microcracks in localizing a through-going slip plane. This micromechanical model of faulting may be applicable to some other faults and shear zones in host rocks which are prone to pressure solution.  相似文献   

Petrophysical Constraints on Deformation Styles in Aztec Sandstone, Southern Nevada, USA     

E. Flodin  M. Prasad  A. Aydin 《Pure and Applied Geophysics》2003,160(9):1589-1610

— Adjacent stratigraphic units that have undergone an identical deformation history often show variability with regard to deformation style. We present one such example and attribute the variability in deformation to variations in host rock properties. The Aztec sandstone of southern Nevada has two distinct zones of deformation style, the Lower and Upper structural domains. The Lower domain has deformed predominantly by opening mode fractures, whereas the Upper domain has deformed predominantly by deformation band faulting. Within a Transitional domain, deformation band abundance increases toward the Upper domain. We use petrophysical data (ultrasonic velocity, elastic moduli, grain and bulk density, helium porosity, and gas permeability) to distinguish among the host rocks of the differently deformed domains. The laboratory results of 29 samples of Upper, Transitional, and Lower domain Aztec sandstone impart the following petrophysical distinctions among the structural domains: (1) the Lower and Transitional domains show similarly high VP and VS and are both well cemented; (2) the Transitional and Upper domains show similarly high porosity and permeability; and, (3) the Upper domain is poorly cemented. We demonstrate that: (1) the nature of intergranular cement controls VP and VS; and, (2) based on the petrophysical properties we have examined, deformation style is controlled by porosity.  相似文献   

A comparison of community and trophic structure in five marine ecosystems based on energy budgets and system metrics   总被引：1，自引：1，他引：0  

Sarah Gaichas  Georg Skaret  Jannike Falk-Petersen  Jason S. Link  William Overholtz  Bernard A. Megrey  Harald Gjster  William T. Stockhausen  Are Dommasnes  Kevin D. Friedland  Kerim Aydin 《Progress in Oceanography》2009,81(1-4):47

  相似文献   

Stakeholder's views on fisheries compliance: An Australian case study     

Shekar Bose  Adnan Crees-Morris 《Marine Policy》2009

This study presents the results of a field survey that focused on the views of Tasmanian abalone fishery stakeholders (commercial and non-commercial divers, processor, enforcement agency and management) with regards to non-compliance in the abalone fishery. The primary data was collected through 22 face-to-face interviews with stakeholders and the Wilcoxon's signed-rank test was used to determine if significant differences existed between the means of responses from primary and secondary stakeholders. It was found that there is no significant difference in mean responses of primary and secondary stakeholders in regard to the factors that have the potential in influencing the non-compliance in the fishery. The similarity of views between the regulators and resource users on the source and nature of non-compliance in the fishery would form the basis for improved compliance strategies.  相似文献   

A minor outburst during the quiescent period of the symbiotic star CH Cygni     

Margherita Hack  Cemal Aydin 《Astrophysics and Space Science》1992,194(2):215-224

We have studied a few optical spectra of the symbiotic star CH Cygni obtained in the period January 1990-June 1991, which indicate that a mild increase of activity occurred between July and December 1990. This increase of activity is confirmed by the IUE observations made in the same period. In fact, in this period of time, we have observed an increase of intensity of all the emission lines both in the optical and ultraviolet ranges and of the continuous ultraviolet flux.Based on observations obtained at the Observatory of Haute Provence (OHP) and on observations by the International Ultraviolet Explorer (IUE) collected at the Villafranca Satellite Tracking Station.  相似文献   

C, O, S and Sr isotope studies on the genesis of Fe-carbonate and barite mineralizations in the Attepe iron district (Adana, Southern Turkey)     

uayip Küpeli  M. Muzaffer Karadag  Ahmet Ayhan  Adnan Dyen  Fetullah Ar&#x;k 《Chemie der Erde / Geochemistry》2007,67(4):313-322

The Attepe district consists of Precambrian, Lower–Middle Cambrian, Upper Cambrian–Lower Ordovician and Mesozoic formations. It contains several iron deposits and occurrences. Three types of iron-mineralizations can be distinguished in the area; (i) Sedimentary Fe-sulfide in Precambrian bituminous metapelitic rocks, and Fe-oxides in Precambrian metasandstones (SISO), (ii) vein-type Fe-carbonate and oxides composed of mainly siderite, ankerite and hematite including barite in Lower–Middle Cambrian metacarbonates of the Çaltepe Formation (HICO), (iii) karstic Fe-oxides and hydroxides essentially in the Lower–Middle Cambrian metacarbonates and the unweathered Fe-carbonates (KIO). The latter type is more widespread and located at the upper parts of the most important mineable iron deposits like Attepe deposit.

Oxygen-, carbon-, sulfur- and strontium-isotope studies have been performed on siderites and barites in the vein-type ores, and on calcites in the recrystallized Çaltepe Limestones to investigate the sources and formation mechanism of primary ore-forming constituents. The δ¹³C values of siderites and calcites in limestones of the Çaltepe Formation range from −10.10‰ to −8.20‰, and from −0.8‰ to 2.30‰. Both carbonate minerals show δ¹⁸O values between 17.50–18.30‰ and 16.20–23.00‰, respectively. The δ¹³C and δ¹⁸O isotopic variations do not indicate any direct or linear relations between siderites and limestones. However, it is possible that the carbon and oxygen isotopic compositions of carbonate minerals could be changed to some extent, when limestones were subjected to hydrothermal processes or thermal alterations during metamorphism.

The isotopic values of barites display 32.40–38.30‰ for δ³⁴S and 12.20–14.70‰ for δ¹⁸O. The strontium isotope ratios (0.717169–0.718601) of barites and the sulfur isotope compositions of barites and pyrites suggest that there are no direct linkages of ore-forming compounds neither with a magmatic source nor with sedimentary pyrite formations in the Precambrian bituminous shales of the Attepe formation.

According to the field observations and the stable isotope data, siderites and ankerites should be formed by interaction between iron-rich hydrothermal fluids and Çaltepe limestones, whereas isotope ratios of barites indicate that they were formed by mixing of sulfur-rich meteoric waters and deeply circulated hydrothermal solutions.  相似文献   

A field application for lime stabilization   总被引：2，自引：0，他引：2  

Aydın Kavak  Adnan Akyarlı 《Environmental Geology》2007,51(6):987-997

This study presents the improvements achieved as a result of the lime stabilization application conducted by the joint effort of the Turkish Association of Lime Industrialists and the General Directorate of Rural Services on the 200 m long section of the Ankara Province Yukar? Yurtçu Village road where green and brown clays are dominant. The study also numerically demonstrates the impacts of these improvements on the road section based on the results of various laboratory and field tests. The lime stabilization in field conditions was performed with 5% lime for both clays and was applied as a 30 cm thick single layer. In the soaked California bearing-ratio (CBR) tests conducted in the laboratory, increases that reach up from 16 and 21 times compared to initial soaked CBR values were observed in green and brown clays, respectively, at the end of 28 days. The high increases observed in soaked CBR values would reduce the upper layer thickness of the roads. The similar improvements are also achieved in unconfined compression and plate loading tests. The comparisons performed with the plate loading tests clearly demonstrated the behavior of the surface to lime and its cure impact.  相似文献   

Mineralogy and composition of the chromitites and their platinum-group minerals from Ortaca (Muğla-SW Turkey): evidence for ophiolitic chromitite genesis     

I. Uysal  M. B. Sadiklar  M. Tarkian  O. Karsli  F. Aydin 《Mineralogy and Petrology》2005,83(3-4):219-242

Summary A large number of podiform chromitite bodies of massive, disseminated and nodular type have been located in ultramafic units, composed of depleted mantle harzburgite and dunite of the Marmaris Peridotite from Ortaca (Mula, SW Turkey). The chromite ore bodies are surrounded by dunite envelopes of variable thickness, exhibiting transitional boundaries to harzburgite host rocks. Chromitites, containing a large number of inclusions, i.e. silicates, base metal sulphides and alloys, and platinum-group minerals (PGM) have a wide range of chemical composition. The Cr# [Cr/(Cr+Al)] values of most chromitites are high (0.61–0.81) and Mg# [Mg/(Mg+Fe²⁺)] values range between 0.65 and 0.71 with TiO₂ content lower than 0.24wt.%, which may reflect the crystallization of chromites from boninitic magmas in supra-subduction setting environment.Platinum-group minerals (PGM) such as laurite, erlichmanite and Os–Ir alloys, silicates such as olivine, clinopyroxene and amphibole, and base metal sulphides (BM-S), alloys (BM-A) and arsenides (BM-As) are found as inclusions in chromite or in the serpentine matrix. Platinum-group element (PGE) concentrations of the Ortaca chromitites (OC) are low in all samples. Total PGE (Ir+Ru+Rh+Pt+Pd) ranges from 63ng/g to 266ng/g and Pd/Ir ratios range between 0.23 and 4.75. PGE content is higher and the Pd/Ir ratio lower in Cr-rich chromitites compared to Al-rich ones. There is a strong negative correlation between the Cr# and Pd/Ir ratios (r=–0.930). The PGE patterns show a negative slope from Ru to Pt and a positive slope from Pt to Pd. The low PGE content in the majority of the OC may reflect a lack of sulphur saturation during an early stage of their crystallization. The laurite compositions show a wide range of Ru–Os substitution caused by relatively low temperature and increasing f(S₂) during the chromite crystallization. The high Cr# of and hydrous silicate mineral inclusions in chromite imply that chromite crystallized in a supra-subduction setting.  相似文献