New chelating resin for preconcentration and determination of molybdenum by inductive couple plasma atomic emission spectroscopy     

H. Sid Kalal Ph.D.  H. Ahmad Panahi Ph.D.  N. Framarzi  E. Moniri Ph.D.  A. Naeemy  H. Hoveidi Ph.D.  A. Abhari 《International Journal of Environmental Science and Technology》2011,8(3):501-512

A chelating resin is prepared by condensation polymerization of aniline with formaldehyde and characterized by Fourier transform infrared spectrometer, elemental analysis and thermogravimetric analysis and studied for the preconcentration and determination of trace Molybdate ion from environmental water sample using inductive couple plasma atomic emission spectroscopy. The optimum pH value for sorption of the metal ion was 5. The sorption capacity of functionalized resin is 3.1 mg/g. The chelating sorbent can be reused for 20 cycles of sorption-desorption without any significant change in sorption capacity. The best desorption of the metal ions from resin was obtained by 0.5 mol/L nitric acid as eluting agent. The profile of molybdenum uptake on this sorbent reflects good accessibility of the chelating sites in the aniline-formaldehyde. Scatchard analysis revealed that the homogeneous binding sites were formed in the polymers. The equilibrium adsorption data of Molybdate ion modified resin were analyzed by five isotherm models such as Langmuir, Freundlich and Temkin. Langmuir isotherm parameters obtained from the four Langmuir linear equations by using linear method. Based on the Langmuir isotherm analysis, the monolayer adsorption capacity was determined to be 4.03 mg/g at 20 °C. The method was applied for molybdenum ions determination from river water sample.  相似文献   

Towards enabling geographies: ‘Disabled’ bodies and minds in society and space – Edited by Vera Chouinard,Edward Hall and Robert Wilton     

Laura Wilkinson‐Meyers 《New Zealand geographer》2011,67(1):64-65

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Correction to “New constraints on the Messinian sealevel drawdown from 3D seismic data of the Ebro Margin,western Mediterranean”     

Roger Urgeles  Angelo Camerlenghi  Daniel Garcia‐Castellanos  Ben De Mol  Miquel Garcés  Jaume Vergés  Ian Haslam  Martin Hardman 《Basin Research》2011,23(3):376-376

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ETHNOBURB: The New Ethnic Community in Urban America. By Wei Li.     

Andrew K. Sandoval‐Strausz 《Geographical review》2011,101(2):289-290

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The domestic divide: Access to the Internet in New Zealand     

Jeremy Greenbrook‐Held  Philip S. Morrison 《New Zealand geographer》2011,67(1):25-38

We use unit records of the 2006 census to show that access to the Internet in the home varies geographically in New Zealand primarily as a result of demographic and socio‐economic differences among individuals. Of particular significance is the much lower rates of domestic access experienced by Māori and Pacific Island individuals even after controlling for differences in their age, gender, education, income, occupation and settlement type. While differences in Internet access by ethnicity has been noted before, it is the magnitude and persistence of this difference in New Zealand after controlling for correlated factors that renders this study unique. Our results have important implications in an education environment increasingly reliant on Web access, but they also raise questions about the extent of access to the Internet outside the home.  相似文献   

Varved sediments of Lake Yoa (Ounianga Kebir,Chad) reveal progressive drying of the Sahara during the last 6100 years   总被引：1，自引：0，他引：1  

Pierre Francus  Hans von Suchodoletz  Michael Dietze  Reik V. Donner  Frédéric Bouchard  Ann‐Julie Roy  Maureen Fagot  Stefan Kröpelin 《Sedimentology》2013,60(4):911-934

The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.  相似文献   

Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones     

Thomas Götte  Karl Ramseyer  Thomas Pettke  Monika Koch‐Müller 《Sedimentology》2013,60(5):1111-1127

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).  相似文献   

An empirical model of subcritical bedform migration     

Chan‐Yi Martin Lin  Jeremy G. Venditti 《Sedimentology》2013,60(7):1786-1799

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.  相似文献   

The microstructural properties and deformation environments of the Kugarchi folded complex,Southern Urals     

E. A. Shmonova  Al. V. Tevelev  Ark. V. Tevelev 《Moscow University Geology Bulletin》2013,68(6):345-355

The Kugarchi folded complex is located on the western slope of the Southern Urals; it is a region of complex disharmonic folding in the Lower Carboniferous limestones. We revealed and studied two systems of mineral veins and accompanying veinlets in limestones. The microstructural analysis was used to recognize several deformation stages and orientations of the principal strain directions. This folded complex is interpreted to have formed under conditions close to uniaxial compression accompanied by a progressive change in the extensional strain direction from vertical to horizontal.  相似文献   

Clay mineralogy as a tool for integrated sequence stratigraphic and palaeogeographic reconstructions: Late Oligocene–Early Aquitanian western internal South Iberian Margin,Spain     

F. J. Alcal  A. Lpez‐Galindo  M. Martín‐Martín 《Geological Journal》2013,48(4):363-375

The different hydrodynamic behaviour of detrital clay minerals in the marine depositional environment allows assessment of relative sea‐level variations in the sedimentary record. Comparison of smectite and kaolinite:illite (S+K:I) changes with the global sea‐level curves and with the third‐order cycles of the eustatic curve for European basins allows assessment of the influence of global eustasy and local tectonics on sequence stratigraphy. In the South Iberian Margin, sedimentation took place both on open‐marine platforms and in deeper water areas. On this margin during the Late Oligocene to Early Aquitanian, the variations in sedimentation were caused not only by global eustasy but also by compressive tectonics. Correlations were made between the S+K:I cycles and the third‐order cycles for European basins, enabling the definition of four third‐order sedimentary sequences (here called C1, C2, C3, and A1) and two lower‐order sequences within C3 and A1 (here called C3a, C3b, A1a, and A1b) related to tectonic movements. High S+K:I values were observed during episodes of maximum flooding in each sequence and lower‐order sequence and in each succession, enabling changes in palaeocoastal morphology to be considered. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献