Emulating the OPAL equation of state     

Hsiao-Hsuan Lin  Werner Däppen 《Astrophysics and Space Science》2010,328(1-2):175-178

The equation of state for the structure of the Sun and stars has to be precise to allow comparisons with observations, i.e., helioseismic inversions of thermodynamic quantities. Among the two of the most popular formalisms are (1) the OPAL equation of state developed at Livermore and (2) the Mihalas-Hummer-Däppen (MHD) equation of state. While OPAL has a solid theoretical foundation, and matches the observational data better, the MHD formalism is more intuitive, easy to realize, and has the possibility of adjustable parameters. Furthermore, it an open-source product in contrast to the proprietary OPAL. Recently a version of MHD has been obtained by including the so-called “Plank-Larkin partition function” and by adding scattering-state terms. The resulting formalism matches OPAL rather well. Here, we report on the next logical step, the implementation of this MHD upgrade into the simple and popular CEFF equation of state. Such an implementation will make it a flexible and convenient tool, allowing an approximative on-line implementation of OPAL in solar and stellar models.  相似文献   

EC 11481–2303—a peculiar subdwarf OB star revisited     

Thomas Rauch  Klaus Werner  Jeffrey W. Kruk 《Astrophysics and Space Science》2010,329(1-2):133-139

EC?11481–2303 is a peculiar, hot, high-gravity pre-white dwarf. Previous optical spectroscopy revealed that it is a sdOB star with T _eff=41?790 K, log?g=5.84, and He/H = 0.014 by number. We present an on-going spectral analysis by means of non-LTE model-atmosphere techniques based on high-resolution, high-S/N optical (VLT-UVES) and ultraviolet (FUSE, IUE) observations.We are able to reproduce the optical and UV observations simultaneously with a chemically homogeneous NLTE model atmosphere with a significantly higher effective temperature and lower He abundance (T _eff=55?000 K, log?g=5.8, and He/H=0.0025 by number). While C, N, and O appear less than 0.15 times solar, the iron-group abundance is strongly enhanced by at least a factor of ten.  相似文献   

Models of the REE distribution in the black shale Bazhenov Formation of the West Siberian marine basin,Russia     

Yuri N. Zanin  Vika G. Eder  Al’bina G. Zamirailova  Vladimir O. Krasavchikov 《Chemie der Erde / Geochemistry》2010,70(4):363-376

Rare-earth elements abundance in black shales of the Upper Jurassic (Tithonian Stage)–Lower Cretaceous (Berriassian Stage) Bazhenov Formation is discussed. This formation is the principal oil source rocks of West Siberia. The deposits within the formation can be subdivided into two main marine groups: (a) moderately hemipelagic deposits (clayey-siliceous, including phosphatic and carbonate rocks) and low-density distal clayey turbidites (argillites), both are considered as normal and (b) silty argillites and clayey-silt rocks, which are channel deposits and considered as anomalous. The hemipelagic rocks of normal sections, which are enriched in the rare-earth elements (REE), accumulated under both slow rates of sedimentation (clayey-siliceous rocks) and faster rates of sedimentation (argillites). The channel deposits of anomalous sections, which are impoverished in the REE, accumulated exclusively under fast rates of sedimentation.Within the hemipelagic group the rate of sedimentation of the argillites was faster than of the clayey-siliceous rocks, but the REE concentration in the former rocks (140.4 ppm) is higher than in the latter group (97.4 ppm). The argillites are more than twice enriched in clayey material than clayey-siliceous rocks. It is likely that the clay fraction was the main carrier of REE in these rocks. In the channel group of rocks, the REE abundance in clayey-silt rocks (21.2 ppm) is lower than in the silty argillite (84.6 ppm), in which the clay content is elevated.With respect to redox potential the Bazhenov Formation rocks can be subdivided further into three groups, based on the degree of pyritization index (DOP): (1) the highly reducing clayey-siliceous rocks of normal sections, with high DOP; (2) the substantially reducing argillites and carbonate rocks of normal sections, with intermediate DOP; (3) the moderately reducing rocks of anomalous sections with low DOP. The rocks with the high DOP (group 1) are characterized by ΣLREE/Σ(M+H)REE ratios between 7.37 and 7.5, whereas the rocks with the lower DOP (group 2 and 3) are characterized by ΣLREE/Σ(M+H)REE ratios between 12.8 and 13.5. Negative Ce anomalies are either small or absent in all deposits, which is typical for reducing conditions.Thus, the Bazhenov Formation exemplifies the complex depositional conditions that influence the REE concentration in black shale. However, it is this very complexity that has contributed to the development of six separate depositional models (REE contents in ppm are given in brackets). (1) Phosphatic clayey-siliceous rocks of normal sections (367.95); (2) argillites of normal sections (130.73); (3) clayey-siliceous rocks of normal sections (85.97); (4) carbonate rocks, largely dolomites of normal sections (23.23); (5) silty argillites of anomalous sections (78.7) and (6) clayey-silt rocks of anomalous sections (19.66).  相似文献   

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia     

Christian Timm  Kaj Hoernle  Reinhard Werner  Folkmar Hauff  Paul van den Bogaard  James White  Nick Mortimer  Dieter Garbe-Schönberg 《Earth》2010,98(1-2):38-64

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.  相似文献   

‘Unionising’ the new spaces of the new economy? Alternative labour organising in India’s IT Enabled Services-Business Process Outsourcing industry     

Al James  Bhaskar Vira 《Geoforum》2010,41(3):364-376

This paper explores the lived experiences and aspirational social constructions of call centre work and employment in India’s high profile IT Enabled Services-Business Process Outsourcing (ITES-BPO) industry; the ways in which they differ from those previously documented amongst call centre workers in the Global North (specifically the UK); and the consequences of that geographical reconfiguration of offshored call centre work for the replicability in India of workplace collective bargaining strategies successfully developed in some UK call centres. These issues are analysed using new empirical evidence from a regional survey of 511 non-unionised ITES-BPO workers and 42 in-depth interviews in India’s National Capital Region. Based on this analysis, the paper then discusses the operation, outcomes and ongoing challenges faced by the newly formed ‘Union for ITES Professionals’ (UNITES Pro) in developing an alternative occupational organising model better suited to the particular needs, motivations and preferences of India’s young, mobile, call centre workers. The empirical analysis presented in the paper is located, therefore, within wider debates on the role of geographical context in shaping possibilities for organising white-collar service workers at different ends of global service chains in the new economy.  相似文献   

Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon   总被引：4，自引：4，他引：0  

Y. B. Onundi M.Sc.  A. A. Mamun Ph.D.  M. F. Al Khatib Ph.D.  Y. M. Ahmed M.Sc. 《International Journal of Environmental Science and Technology》2010,7(4):751-758

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.  相似文献   

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest     

Kesang WANGCHUK  András DARABANT  Prem Bahadur RAI  Maria WURZINGER  Werner ZOLLITSCH  Georg GRATZER 《山地科学学报》2014,11(5):1182-1191

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.  相似文献   

Potential use of faujasite–phillipsite and phillipsite–chabazite tuff in purification of treated effluent from domestic wastewater treatment plants     

Reyad A. Al Dwairi  Khalil M. Ibrahim  Hani N. Khoury 《Environmental Earth Sciences》2014,71(12):5071-5078

Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.  相似文献   

Mapping groundwater conditions in different geological environments in the northern area of UAE using 2D earth resistivity imaging survey   总被引：1，自引：1，他引：0  

A. M. Ebraheem  M. M. Al Mulla  M. M. Sherif  O. Awad  S. F. Akram  N. B. Al Suweidi  A. Shetty 《Environmental Earth Sciences》2014,72(5):1599-1614

A water resources database was developed and used to characterize the geological and hydrogeological settings of groundwater aquifers in the northern part of the United Arab Emirates. An intensive 2D Earth Resistivity Imaging (ERI) survey was conducted in selected areas to assess the available groundwater resources and delineate the salt-water intrusion. Drilling information of the existing monitoring wells as well as their records of water table elevations and groundwater salinity were used to measure the horizontal and vertical variations in lithology, degree of saturation, and groundwater salinity and thus to improve the interpretation of ERI data. The results of the chemical analyses of water samples collected from the wells along with the 2D ERI survey profiles were used to obtain an empirical relationship between the inferred earth resistivity and the amount of total dissolved solids. This relationship was used along with the true resistivity sections resulting from the inversion of 2D ERI data to identify and map three zones of water-bearing formation (fresh, brackish, and salt-water zones) in the coastal areas. The results indicated that the depth to the fresh-brackish interface exceeded 50 m at the upstream of the wadies and was in the order of 10 m or less in the vicinity of shoreline. Because of the high resistivity contrast between dry and water saturated fractured rocks; this method was very successful in detecting water-filled fractures and cavities in the carbonate aquifer. The application of this method was unsuccessful in clayey aquifers as it was not possible to isolate lenses of gravel and/or saturated with saline or brackish water from the surrounding clayey materials.  相似文献   

A new physically based stochastic event catalog for hail in Europe     

H. J. Punge  K. M. Bedka  M. Kunz  A. Werner 《Natural Hazards》2014,73(3):1625-1645

Hailstorms represent one of the major sources of damage and insurance loss to residential, commercial, and agricultural assets in several parts of Central Europe. However, there is little knowledge of hail risk across Europe beyond local historical damage reports due to the relative rarity of severe hail events and the lack of uniform detection methods. Here we present a new stochastic catalog of hailstorms for Europe. It is based on satellite observations of overshooting cloud tops (OT) that indicate very strong convective updrafts and hail reports from the European Severe Weather Database (ESWD). Historic hail events are defined based on OT detections from satellite infrared brightness temperatures between 2004 and 2011 for the warm seasons (April–September). The satellite-based historical event properties are complemented by hailstone observations from ESWD to stochastically simulate more than 1 million individual events with an event footprint resolution of 10 km. The final hail event catalog presented in this paper is the first one with a spatial event distribution that is based on a single homogeneous observation source over Europe. Areas of high hail probability or hail risk are found over Central and Southern Europe, including mountainous regions such as the Alps or the Pyrenees. Another region of relatively high hail risk is present over central Eastern Europe.  相似文献