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971.
The viscosity of a series of six synthetic dacitic liquids, containing up to 5.04 wt% dissolved water, was measured above the glass transition range by parallel-plate viscometry. The temperature of the 1011 Pa s isokom decreases from 1065 K for the anhydrous liquid, to 864 K and 680 K for water contents of 0.97 and 5.04 wt% H2O. Including additional measurements at high temperatures by concentric-cylinder and falling-sphere viscometry, the viscosity (η) can be expressed as a function of temperature and water content w according to: where η is in Pa s, T is temperature in K, and w is in weight percent. Within the conditions of measurement, this parameterization reproduces the 76 viscosity data with a root-mean square deviation (RMSD) of 0.16 log units in viscosity, or 7.8 K in temperature. The measurements show that water decreases the viscosity of the dacitic liquids more than for andesitic liquids, but less than for rhyolites. At low temperatures and high water contents, andesitic liquids are more viscous than the dacitic liquids, which are in turn more viscous than rhyolitic liquids, reversing the trend seen for high temperatures and low water contents. This suggests that the relative viscosity of different melts depends on temperature and water content as much as on bulk melt composition and structure. At magmatic temperatures, rhyolites are orders of magnitude more viscous than dacites, which are slightly more viscous than andesites. During degassing, all three liquids undergo a rapid viscosity increase at low water contents, and both dacitic and andesitic liquids will degas more efficiently than rhyolitic liquids. During cooling and differentiation, changing melt chemistry, decreasing temperature and increasing crystal content all lead to increases in the viscosity of magma (melt plus crystals). Under closed system conditions, where melt water content can increase during crystallization, viscosity increases may be small. Conversely, viscosity increases are very abrupt during ascent and degassing-induced crystallization.  相似文献   
972.
The mid‐Cretaceous Spences Bridge Group (SBG) comprises a series of basaltic to rhyolitic lavas and related volcaniclastic rocks (Pimainus Formation) overlain by a succession of mainly amygdaloidal andesites (Spius Formation) related to the closure of the Methow–Tyaughton basin and accretion of the Insular terrane in the North American Cordillera. Geochemical variation in the SBG is related primarily to metasomatic processes in the mantle wedge. Pimainus lavas include low‐ to high‐K, tholeiitic and calc‐alkaline types, and have isotopic compositions (εNd(100Ma) = + 5.2 to + 7.0, εSr(100Ma) = − 10 to − 20, 206Pb/204Pb = 18.82 to 18.91, 207Pb/204Pb = 15.55 to 15.60, 208Pb/204Pb = 38.24 to 38.43) between the ranges for primitive arcs and accreted terrane crust. Crustal sources are identified only for some low–medium K dacite and rhyolite compositions. The occurrence of intermediate compositions with high MgO contents (up to 6 wt%) and the presence of adakitic trace element features in medium–high K felsic lavas attests to metasomatism of the mantle wedge by slab melts during Pimainus volcanism. Spius lavas have comparable K2O and Pb isotopic compositions to the Pimainus, even higher MgO (up to 9.2 wt%), and display a mild intraplate character in having up to 0.6 wt% P2O5, 15 ppm Nb, and 240 ppm Zr. Spius Nd−Sr isotopic compositions (εNd(100Ma) = + 5.3 to + 6.9, εSr(100Ma) = − 14 to − 25) define an array extending from Pimainus to alkaline seamount compositions. The low εSr values, elevated high field strength element contents, and moderate silica contents suggest Spius volcanism was related to the introduction of small melt fractions from the asthenosphere into the mantle wedge which had previously generated Pimainus melts. The range of compositional types in the Pimainus Formation constrains tectonic scenarios to include an elevated slab thermal regime, likely from approach of an ocean ridge system toward the continental margin. Spius volcanism may have been generated by asthenospheric upwelling triggered by slab window development or slab‐hinge roll‐back on closure of the Methow–Tyaughton basin. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
973.
Automatic calibration of complex subsurface reaction models involves numerous difficulties, including the existence of multiple plausible models, parameter non-uniqueness, and excessive computational burden. To overcome these difficulties, this study investigated a novel procedure for performing simultaneous calibration of multiple models (SCMM). By combining a hybrid global-plus-polishing search heuristic with a biased-but-random adaptive model evaluation step, the new SCMM method calibrates multiple models via efficient exploration of the multi-model calibration space. Central algorithm components are an adaptive assignment of model preference weights, mapping functions relating the uncertain parameters of the alternative models, and a shuffling step that efficiently exploits pseudo-optimal configurations of the alternative models. The SCMM approach was applied to two nitrate contamination problems involving batch reactions and one-dimensional reactive transport. For the chosen problems, the new method produced improved model fits (i.e. up to 35% reduction in objective function) at significantly reduced computational expense (i.e. 40–90% reduction in model evaluations), relative to previously established benchmarks. Although the method was effective for the test cases, SCMM relies on a relatively ad-hoc approach to assigning intermediate preference weights and parameter mapping functions. Despite these limitations, the results of the numerical experiments are empirically promising and the reasoning and structure of the approach provide a strong foundation for further development.  相似文献   
974.
Beach profile data, collected twice per year at 19 stations over a 25 km length of coastline in Tremadoc Bay, have been analysed to quantify the inter-annual variability in beach levels over a 7 year period and the results compared against the output of a numerical model. Using hourly wind data as forcing, the morphological development of northern Tremadoc Bay was simulated by wave, tidal, longshore transport, total transport and bed level change models. The modelling methodology was efficient and innovative, allowing realistic simulations of long duration with a time step of 1 h, hence capturing the high frequency nature of wind events. The model was run for each of the 7 autumn/winter periods (generally November–April) and the modelled net change in beach levels compared with the data from all 19 stations. The model results had reasonable agreement with the beach profile surveys. However, the observed magnitude of bed level change in the bay lagged the model output by 1 year, indicating that sediment processes acting over a larger area are important in a relatively localised study of inter-annual variability.  相似文献   
975.
Artificial recharge through a thick, heterogeneous unsaturated zone   总被引:2,自引:0,他引:2  
Thick, heterogeneous unsaturated zones away from large streams in desert areas have not previously been considered suitable for artificial recharge from ponds. To test the potential for recharge in these settings, 1.3 x 10(6) m(3) of water was infiltrated through a 0.36-ha pond along Oro Grande Wash near Victorville, California, between October 2002 and January 2006. The pond overlies a regional pumping depression 117 m below land surface and is located where thickness and permeability of unsaturated deposits allowed infiltration and saturated alluvial deposits were sufficiently permeable to allow recovery of water. Because large changes in water levels caused by nearby pumping would obscure arrival of water at the water table, downward movement of water was measured using sensors in the unsaturated zone. The downward rate of water movement was initially as high as 6 m/d and decreased with depth to 0.07 m/d; the initial time to reach the water table was 3 years. After the unsaturated zone was wetted, water reached the water table in 1 year. Soluble salts and nitrate moved readily with the infiltrated water, whereas arsenic and chromium were less mobile. Numerical simulations done using the computer program TOUGH2 duplicated the downward rate of water movement, accumulation of water on perched zones, and its arrival at the water table. Assuming 10 x 10(6) m(3) of recharge annually for 20 years, a regional ground water flow model predicted water level rises of 30 m beneath the ponds, and rises exceeding 3 m in most wells serving the nearby urban area.  相似文献   
976.
为了解胶州湾浮游原生生物时空分布特征及与环境因子间的关系,自2007年6月~2008年5月,对青岛胶州湾内5个站点表层水的浮游原生生物丰度及环境因子进行了累计24次的周年采样调查及定性、定量分析.结果显示:(1) 浮游原生生物周年变动具有2个高峰,分别出现在4月和8月;(2) 浮游硅藻、鞭毛藻和纤毛虫的丰度周年变动均为双峰型:春节(4月)高峰、秋节(8月)高峰;(3) 浮游原生生物丰度与叶绿素a和溶解氧呈显著性相关,而其群落结构的变化与盐度、溶解氧、硝态氮和亚硝态氮的组合呈显著性相关.本工作为进一步探讨富营养化的内湾型近岸水体内原生生物生态学结构与功能提供了一份必要的基础资讯.  相似文献   
977.
It is often of interest to model the incidence and duration of threshold exceedance events for an environmental variable over a set of monitoring locations. Such data arrive over continuous time and can be considered as observations of a two-state process yielding, sequentially, a length of time in the below threshold state followed by a length of time in the above threshold state, then returning to the below threshold state, etc. We have a two-state continuous time Markov process, often referred to as an alternating renewal process. The process is observed over a truncated time window and, within this window, duration in each state is modeled using a distinct cumulative intensity specification. Initially, we model each intensity over the window using a parametric regression specification. We extend the regression specification adding temporal random effects to enrich the model using a realization of a log Gaussian process over time. With only one type of renewal, this specification is referred to as a Gaussian process modulated renewal process. Here, we introduce Gaussian process modulation to the intensity for each state. Model fitting is done within a Bayesian framework. We clarify that fitting with a customary log Gaussian process specification over a lengthy time window is computationally infeasible. The nearest neighbor Gaussian process, which supplies sparse covariance structure, is adopted to enable tractable computation. We propose methods for both generating data under our models and for conducting model comparison. The model is applied to hourly ozone data for four monitoring sites at different locations across the United States for the ozone season of 2014. For each site, we obtain estimated profiles of up-crossing and down-crossing intensity functions through time. In addition, we obtain inference regarding the number of exceedances, the distribution of the duration of exceedance events, and the proportion of time in the above and below threshold state for any time interval.  相似文献   
978.
Zhao  Xinwei  Zhou  Jing  Ma  Fang  Ji  Jianqing  Deino  Alan 《中国科学:地球科学(英文版)》2020,63(5):662-673
Reconstruction of Quaternary environments, late Cenozoic geodynamics and evaluation of volcanic hazards, all depend on the precise delineation of eruptive stages. In recent years, laser ~(40)Ar/~(39)Ar dating methods have been widely used for dating young volcanic rocks, given their stable automated testing process, very low background level and high sensitivity, which meet the requirements for precise dating of young samples. This paper applied high-precision laser ~(40)Ar/~(39)Ar dating to the main volcanic units in the Tengchong area and obtained ages in the range of 0.025–5.1 Ma using conventional data processing methods. However, conventional dating highlighted issues related to very low radiogenic ~(40)Ar content, accidental errors and poor data stability, which led to huge age deviations. Moreover, lacking a unified timescale, conventional methods were unable to strictly define the stages of the Tengchong volcanic eruptions, leading to ongoing controversy. In this study, we applied a Gaussian mathematical model to deal with all 378 original ages from 13 samples. An apparent age-probability diagram,consisting of three independent waveforms, have been obtained. The corresponding isochron ages of these three waveforms suggest there were three volcanic eruptive stages, namely during the Pliocene(3.78±0.04 Ma), early Middle Pleistocene(0.63±0.03 Ma) and late Middle Pleistocene to early Late Pleistocene(0.139±0.005 Ma). These results accurately define eruptive stages in the Tengchong area.  相似文献   
979.
A primary goal of earthquake engineering is to protect society from the possible negative consequences of future earthquakes. Conventionally, this goal has been achieved indirectly by reducing seismic damage of the built environment through better building codes, or more comprehensibly, by minimizing seismic risk. However, the effect that building damage has on occupants is not explicitly taken into account while designing infrastructure. Consequently, this paper introduces a conceptual framework and numerical algorithm to assess earthquake risk on building occupants during seismic events, considering the evacuation process of the structure. The framework combines probabilistic seismic hazard analysis, inelastic structural response analysis and damage assessment, and couples these results with the response of evacuating agents. The results are cast as probability distributions of variables that measure the overall performance of the system (e.g., evacuation times, number of injured people, and repair costs) for specific time windows. As a testbed, the framework was applied to the response of a reinforced concrete frame building that exemplifies the use of all steps of the methodology. The results suggest that this seismic risk evaluation framework of structural systems that combine the response of a physical model with human agents can be extended to a wide variety of other situations, including the assessment of mitigation actions in communities and people to improve their earthquake resilience. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
980.
In the context of the current review of New Zealand's National Certificate of Educational Achievement (NCEA), the paper reflects on the nature and relevance of geography in education, life and work. The context of school geography programmes is critically examined, and a checklist of points for further consideration and action is presented.  相似文献   
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