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191.
Natural organochlorine (Clorg) is ubiquitous in soil humus, but the distribution and cycling of different Cl species during the humification of plant material is poorly understood. Our X-ray spectromicroscopic studies indicate that the distributions of Clorg and inorganic Cl−(Clinorg) in oak leaf material vary dramatically with decay stage, with the most striking changes occurring at the onset of weathering. In healthy or senescent leaves harvested from trees, Clinorg occurs in sparsely distributed, highly localized “hotspots” associated with trichomes as well as in diffuse concentration throughout the leaf tissue. The Clinorg associated with trichomes exists either in H-bonded form or in a solid salt matrix, while the Clinorg in diffuse areas of lower Cl concentration appears exclusively in H-bonded form. Most solid phase Clinorg leaches from the leaf tissue during early weathering stages, whereas the H-bonded Clinorg appears to leach away slowly as degradation progresses, persisting through advanced weathering stages. In unweathered leaves, aromatic and aliphatic Clorg were found in rare but concentrated hotspots. In weathered leaves, by contrast, aromatic Clorg hotspots are prevalent, often coinciding with areas of elevated Fe or Mn concentration. Aromatic Clorg is highly soluble in leaves at early weathering stages and insoluble at more advanced stages. These results, combined with optical microscopy, suggest that fungi play a role in the production of aromatic Clorg in weathering leaf material. Aliphatic Clorg occurs in concentrated hotspots in weathered leaves as well as in diffuse areas of low Cl concentration. The distribution and speciation of Cl in weathering oak leaves depicted by this spectromicroscopic study provides new insight into the formation and cycling of Clorg during the decay of natural organic matter. 相似文献
192.
Alessandra Borghi Daniela Carrion Giovanna Sona 《Geophysical Journal International》2007,171(2):539-549
An up to date determination of a high-resolution geoid requires the use of best available databases concerning digital terrain model (DTM), bathymetry, global geopotential model and gravity field. The occasion to revisit methods to validate and merge different data sets has been created by a new project for the determination of a new European Geoid.
Since the computation of the latest European geoid and quasi-geoid model (EGG97), significant new or improved data sets have become available, such as new global geopotential models from CHAMP and GRACE missions, new national and global DTMs and new or upgraded gravity data sets.
In the context of the new European Gravity and Geoid Project (EGGP), within the IAG Commission 2, some data validation tests have been performed in the Italian zone.
In the area 19°× 17° wide, covering Italy, three kinds of tests have been performed: comparison among different DTMs in order to choose the best one to be used; comparisons in terms of geoid computation in some coastal areas, to evaluate bathymetry effects, and the validation of the EIGEN-CG01C and EIGEN-CG03C new global models up to degree and order 360.
These preliminary tests lead to the choice of SRTM DTM (integrated in no-data holes), with an added bathymetry derived by the Italian 1:25 000 official cartography near the coasts and the NOAA bathymetry in high seas. The validation of the new global models and the comparison with EGM96 model show that, in terms of geoid computation, the EGM96 yields better results. Moreover, the validation of new available land gravity data and the cross-validation of two sets of gravity data on sea have been completed. 相似文献
Since the computation of the latest European geoid and quasi-geoid model (EGG97), significant new or improved data sets have become available, such as new global geopotential models from CHAMP and GRACE missions, new national and global DTMs and new or upgraded gravity data sets.
In the context of the new European Gravity and Geoid Project (EGGP), within the IAG Commission 2, some data validation tests have been performed in the Italian zone.
In the area 19°× 17° wide, covering Italy, three kinds of tests have been performed: comparison among different DTMs in order to choose the best one to be used; comparisons in terms of geoid computation in some coastal areas, to evaluate bathymetry effects, and the validation of the EIGEN-CG01C and EIGEN-CG03C new global models up to degree and order 360.
These preliminary tests lead to the choice of SRTM DTM (integrated in no-data holes), with an added bathymetry derived by the Italian 1:25 000 official cartography near the coasts and the NOAA bathymetry in high seas. The validation of the new global models and the comparison with EGM96 model show that, in terms of geoid computation, the EGM96 yields better results. Moreover, the validation of new available land gravity data and the cross-validation of two sets of gravity data on sea have been completed. 相似文献
193.
The performance of the self-exciting threshold autoregressive moving average model in forecasting river flow data is investigated. Multi-step forecasts of two daily time series are generated through three different nonlinear predictors. The model adequacy to capture the main features of the data under study and its forecasting performance are analysed and discussed. 相似文献
194.
Janaina L. Oliveira Alessandra Eugênio Júlio C. Rodrigues de Azevedo Jorge Nozaki 《洁净——土壤、空气、水》2006,34(4):383-388
The sediment of Lagoa dos Patos‐MS, Brazil, was investigated to verify the influence of metal sulfides and oxyhydroxides of Mn and Fe on the heavy metal availability. The spectrophotometric method of methylene blue was used, with 8 interlinked tubes containing the samples with SnCl2, where N2 was introduced to release the H2S extracted with 6.0 mol L–1 HCl, and trapped in 0.05 M NaOH solution. The influence of SO42–, Mn(IV) and Fe(III) oxyhydroxides was investigated with samples constituted by a mixture of MnO2; Na2SO4; FeCl3, and sediments. The presence of SnCl2 was very important to avoid the interferences of iron and manganese oxyhydroxides. The method of standard addition was applied and the efficiency was (100.8 ± 9.4)%. The ratio among the quantities of metals potentially available and the acid volatile sulfide (AVS) indicate that the system presents small metals availability to the benthic community, by the existence of sulfide capable to immobilize the metal as insoluble sulfide. 相似文献
195.
Intercomparison of Boron Isotope and Concentration Measurements. Part II: Evaluation of Results 总被引:3,自引:1,他引:3
Roberto Gonfiantini Sonia Tonarini Manfred Grning Alessandra Adorni‐Braccesi Assad S. Al‐Ammar Marcus Astner Sebastien Bchler Ramon M. Barnes Randy L. Bassett Alain Cocherie Annette Deyhle Andrea Dini Giorgio Ferrara Jrme Gaillardet Judith Grimm Catherine Guerrot Urs Krhenbühl Graham Layne Damien Lemarchand Anette Meixner D. Jack Northington Maddalena Pennisi Eva Reitznerov Ilia Rodushkin Naoji Sugiura Regina Surberg Sabine Tonn Michael Wiedenbeck Samuel Wunderli Yingkai Xiao Thomas Zack 《Geostandards and Geoanalytical Research》2003,27(1):41-57
The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories - virtually all those performing geochemical boron isotope analyses in the world -which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ11 B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution. 相似文献
196.
197.
Luigi Marini Valeria Chiappini Roberto Cioni G. Cortecci E. Dinelli Claudia Principe Giorgio Ferrara 《Bulletin of Volcanology》1998,60(3):187-194
Sulfur contents and δ34S values of Somma-Vesuvius magmas are consistent with syneruptive, open-system degassing at temperatures of 800–850°C for
Plinian pumices and 1100–1200°C for lavas. The extent of degassing appears to be greater in lavas than in pumices. The key
parameter controlling the 34S/32S ratio of Somma-Vesuvius volcanics is the average magma oxidation state, which generally varies from 0.85 to 1.20 Δ NNO units
for lavas and from 1.20 to 1.40 Δ NNO units for pumices. Consequently, S contents and δ34S values of magmas constitute a potentially valuable tool in estimating their average redox conditions. The results of this
study may help in risk mitigation when the Vesuvius magmatic system evolves toward eruptive conditions.
Received: 20 January 1998 / Accepted: 5 May 1998 相似文献
198.
199.
Sara Picone Francesca Alvisi Enrico Dinelli Caterina Morigi Alessandra Negri Mariangela Ravaioli Carmela Vaccaro 《第四纪科学杂志》2008,23(5):489-501
Sedimentological, geochemical and micropalaeontological data from sediment cores in the northwestern Adriatic Sea were obtained to reconstruct the stratigraphic framework and palaeogeographic setting during the last post‐glacial sea‐level rise (14000–6000 yr BP). Four lithostratigraphic units were identified: (a) distal plain deposits (>14000 yr BP), submerged during the first phases of marine ingression; (b) coastal lagoon system; (c) barrier‐lagoon system, which is dated back to between 10019 ± 61 and 10228 ± 174 cal. yr BP from 14C dating on peat and shell remains; (d) marine prodelta deposits (<5500 yr BP). Geochemical data allow the identification of three distinct sediment sources: River Po, River Adige and Eastern Alpine rivers characterised by decreasing Ni/Mg ratios (50–70, 8–15 and 5–10, respectively) and Ba/Al ratios of 45–55, 55–65 and 35–45, respectively. The three sources display different relative abundances in time. During the Lateglacial, the Po is the main sediment source for the southern cores, whereas the Eastern Alps and the River Adige are the main sediment sources for the northern cores. This suggests a northern position of the Po River bed compared to previous studies. Coastal drowning led to a homogenization of the provenance signal within the sediments. Only after the marine transgression does a River Po signal appear in the northern cores. At the same time, in the southern cores the signal of Eastern Alpine rivers becomes stronger. Transgressive barrier‐lagoon and recent sediments do not display a predominant signal for provenance indicators. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献