Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters   总被引：2，自引：0，他引：2  

Jacinta Enzweiler  Maria Aparecida Vendemiatto 《Geostandards and Geoanalytical Research》2004,28(1):103-112

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.  相似文献   

Major changes in volcano behaviour after a sector collapse: insights from Stromboli, Italy   总被引：1，自引：0，他引：1  

Alessandro Tibaldi 《地学学报》2004,16(1):2-8

In recent years, increasing numbers of volcanoes are being recognized as having undergone large sector collapses. How far such events can change the succeeding behaviour of the volcano is poorly known, despite the importance for natural hazards and economic applications. By analysing the last 100‐kyr geological history of Stromboli (Italy), which has involved multiple collapses, this paper illuminates the feedback effect between sector collapse and magma upwelling and emplacement. The collapsed zone of Stromboli is episodically unbuttressed, draining magma preferentially with formation of eruptive centres in the collapse amphitheatre and dyking along the collapse shoulders. After a collapse, there were no further linear eruptions across the cone on opposing middle–lower slopes, but these occurred again after rebuilding of the cone. The time‐averaged eruption rate increased immediately before the first collapse and remained higher during the succeeding period of frequent collapses.  相似文献   

Magnetic fabrics and rock magnetism of Proterozoic dike swarm from the southern São Francisco Craton, Minas Gerais State, Brazil     

Maria Irene Bartolomeu Raposo  Alexandre O. Chaves  Paulo Lojkasek-Lima  Manoel Souza D'Agrella-Filho  Wilson Teixeira   《Tectonophysics》2004,378(1-2):43-63

Magnetic fabric and rock magnetism studies were performed on 32 mafic dikes of a Proterozoic dike swarm from the southern São Francisco Craton (SFC; Minas Gerais State, SE Brazil). Magnetic anisotropies were determined by applying anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of remanent magnetization (ARM). The latter was performed imposing both anhysteretic (total (AAR) and partial pAAR)) and isothermal remanence magnetizations (AIRM). Partial anhysteretic remanence anisotropy was performed based on remanent coercivity spectra from a pilot specimen of each site. In most sites, AMS is dominantly carried by ferromagnetic minerals, however, in some sites, the paramagnetic contribution exceeds 70% of bulk susceptibility. Rock magnetism and thin section analysis allow classifying the dikes as non-hydrothermalized and hydrothermalized. Magnetic measurement shows that the mean magnetic susceptibility is usually lower than 5×10⁻³ (SI). Ti-poor titanomagnetites up to pure magnetite pseudo-single-domain (PSD) grain sizes carry the majority of magnetic fabrics for non-hydrothermalized dikes whereas coarse to fine grained Ti-poor titanomagnetites carry the majority of magnetic fabrics for hydrothermalized dikes.Three primary AMS fabrics are recognized which are coaxial with ARM fabric, except for two dikes, from both non-hydrothermalized and hydrothermalized dikes. Normal AMS fabric surprisingly is not dominant (31%). The parallelism between AMS, pAAR_0–30, pAAR_30–60 and pAAR_60–90 fabrics in the hydrothermalized dikes indicates that magnetic grains formed due to late-stage crystallization or to remobilization of iron oxides due to hydrothermal alteration after dike emplacement have acquired a mimetic fabric coaxial with the primary fabric given by coarse-grained early crystallized Ti-poor titanomagnetites. This fabric is interpreted as magma flow in which the analysis of K_max inclination permitted the inference that the dikes were fed by horizontal or subhorizontal fluxes (K_max<30°). Intermediate AMS fabric is the most important (41%) in the investigated swarm. It is interpreted as due to vertical compaction of a static magma column with the minimum stress along the dike strike. ARM determinations for these sites also remained intermediate except for two dikes. In one of them, AIRM fabric resulted in normal AMS fabric while for the other AAR fabric resulted in inverse AMS fabric. A combination of AMS and ARM fabrics suggest that magmatic fabric for both dikes were overprinted by some late local event, probably related to Brasiliano orogenic processes after dike emplacement. InverseInverse AMS fabric is a minority (four dikes). ARM determinations also remained inverse suggesting a primary origin for inverse AMS fabric.  相似文献   

From in-situ coal to fly ash: a study of coal mines and power plants from Indiana     

Maria Mastalerz  James C Hower  Agnieszka Drobniak  Sarah M Mardon  Grzegorz Lis   《International Journal of Coal Geology》2004,59(3-4):171-192

This paper presents data on the properties of coal and fly ash from two coal mines and two power plants that burn single-source coal from two mines in Indiana. One mine is in the low-sulfur (<1%) Danville Coal Member of the Dugger Formation (Pennsylvanian) and the other mines the high-sulfur (>5%) Springfield Coal Member of the Petersburg Formation (Pennsylvanian). Both seams have comparable ash contents (11%). Coals sampled at the mines (both raw and washed fractions) were analyzed for proximate/ultimate/sulfur forms/heating value, major oxides, trace elements and petrographic composition. The properties of fly ash from these coals reflect the properties of the feed coal, as well as local combustion and post-combustion conditions. Sulfur and spinel content, and As, Pb and Zn concentrations of the fly ash are the parameters that most closely reflect the properties of the source coal.  相似文献   

Occurrence of the Indian genus Hemibos (Bovini, Bovidae, Mammalia) at the Early–Middle Pleistocene transition in Italy     

Bienvenido Martínez-Navarro  Maria Rita Palombo 《Quaternary Research》2004,61(3):314-317

The morphology of the horn-core structure and section shape of the Bos galerianus type specimen, as well as the general anatomy of the frontal and occipital areas of the skull, suggest that the skull is better attributed to the Indian genus Hemibos. This finding contributes to our understanding of faunal dispersal patterns into Europe at the Early–Middle Pleistocene transition.  相似文献   

Local pattern of stress field and seismogenic sources in the Pergola–Melandro basin and the Agri valley (Southern Italy)     

Luigi Cucci  Silvia Pondrelli  Alberto Frepoli  Maria Teresa Mariucci  Marco Moro 《Geophysical Journal International》2004,156(3):575-583

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Shear and objective stress rates in hypoplasticity by D. Kolymbas and I. Herle. Author's Reply to Discussion by A. Beghini and Z. P. Bazant,R. Chambon and A. Niemunis of ‘Shear and objective stress rates in hypoplasticity’     

Alessandro Beghini  Zdeněk P. Bažant  R. Chambon  D. Kolymbas  I. Herle 《国际地质力学数值与分析法杂志》2004,28(4):365-372

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Magnetic properties of the profiles of polluted and non-polluted soils. A case study from Ukraine   总被引：7，自引：0，他引：7  

Maria Jele&#;ska  Agata Hasso-Agopsowicz  Barbara Kopcewicz  Anatoliy Sukhorada  Ksenija Tyamina  Magdalena K&#;dzia&#;ko-Hofmokl  Zhanna Matviishina 《Geophysical Journal International》2004,159(1):104-116

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An approach for quantifying geomorphological impacts for EIA of transportation infrastructures: a case study in northern Spain   总被引：2，自引：0，他引：2  

Jaime Bonachea  Viola Maria Bruschi  Juan Remondo  Alberto Gonzlez-Díez  Luis Salas  Jurjen Bertens  Antonio Cendrero  Csar Otero  Cecilia Giusti  Andrea Fabbri  Jos Ramn Gonzlez-Lastra  Jos María Aramburu 《Geomorphology》2005,66(1-4):95

A methodological proposal for the assessment of impacts due to linear infrastructures such as motorways, railways, etc. is presented. The approach proposed includes a series of specific issues to be addressed for each geomorphological feature analysed—both ‘static’ and ‘dynamic’—as well as a series of steps to be followed in the process.Geomorphic characteristics potentially affected were initially identified on the basis of a conceptual activities/impacts model that helps to single out geomorphic impacts related to environmental concerns for the area. The following issues were addressed for each individual impact: nature of potential effects; indicators that can be used to measure impacts; criteria of ‘geomorphologic performance’; procedure for measurement/prediction of changes; translation of geomorphologic impacts into significant terms from the viewpoint of human concerns; possible mitigation and/or compensation measures.The procedure has been applied to a case study corresponding to a new motorway in the Basque Country, northern Spain. Geomorphological impacts considered in this analysis included: (1) consumable resources; (2) sites of geomorphological interest; (3) land units with high potential for use, high productivity or value for conservation; (4) visual landscape; (5) slope instability processes. The procedure has been designed for implementation in a Geographic Information System (GIS) environment. Details are given on the application of the method to each individual impact analysed and results are presented in both numerical and map form.Impacts assessed were initially expressed by means of heterogeneous magnitudes, depending on the geomorphological feature considered. Those geomorphological impacts were then translated into significant terms and homogeneous magnitudes. Integration was carried out on the basis of impact values thus obtained. Final integrated results were also expressed in numerical and map form.The method proposed enables comparison of alternatives as well as ‘prediction’ and assessment of impacts in terms directly related to geomorphic characteristics. It also facilitates the expression of those impacts in terms that allow integration with other types of environmental impacts.  相似文献   

Optical properties of pseudovitrinite; implications for its origin     

Maria Mastalerz  Agnieszka Drobniak 《International Journal of Coal Geology》2005,62(4):250-258

A set of Pennsylvanian coals from the North American coal basins, ranging in vitrinite reflectance from 0.65% to 1.75%, was examined, with special emphasis on the optical properties of pseudovitrinite. The results suggest that pseudovitrinite originates from the same material as telocollinite. Slits in the pseudovitrinite seem to have originated in situ due to low-temperature oxidation of woody material; their opening might have been facilitated by devolatilization during coalification. The dominant orientation of the slits is perpendicular to bedding. The intensity and orientation of the slits in pseudovitrinite could be important factors in predicting coalbed gas extraction from coal.  相似文献