Geochemistry of suspended matter from the Baltic Sea 2. Results of bulk trace metal analysis by AAS     

Lutz Brügmann  Paul C. Bernard  Rene van Grieken 《Marine Chemistry》1992,38(3-4)

In 1984, on a transect covering the whole Baltic Sea and parts of the adjacent North Sea, 160 water samples were taken and analysed for their concentrations of particulate and dissolved metals. In addition, the suspended materials were investigated for their elemental bulk composition.The particulate fractions represented from about 5% (Cd, Cu and Ni) to 50% (Fe and Pb) of the total (particulate plus dissolved) concentrations. For some elements (Ba, Cd, Cu, Pb and Zn), the particulate matter from the surface microlayer was enriched with respect to those suspended materials taken from 0.2 m depth. This could reflect the atmospheric input of metal-rich aerosols. In anoxic deep waters, maximum contents of Zn (6400 μg g⁻¹), Cu (1330 μg g⁻¹) and Cd (12 μg g⁻¹) were observed in the particulate matter, indicating sulphidic forms. On the other hand, under oxic conditions the distribution coefficients (K_d) decreased with the water depth (Cd, Fe and Pb).Relative to global background levels, the particulate matter contained metal “excesses” amounting to more than 90% of the total contents (Cd, Mn, Pb and Zn). Automated electron probe X-ray microanalysis (EPXMA) revealed that the elemental composition of sediments is mainly governed by post-depositional processes of early diagenesis and is only weakly related to the composition of suspended matter in the overlying water body. For instance, in relation to surface mud sediments of the central Baltic net-sedimentation basins, Zn, Cd, Cu and Mn had 30–100% higher levels in the suspended materials. The general pattern of metal contents of particulate matter taken from 10 m depth on a transect between the Bothnian Bay and the North Sea were—possibly as a result of anthropogenic inputs—rather similar for Pb, Zn and Cu. For Fe and Mn, the distribution patterns along the transect were probably governed by the natural loading characteristics and by the biogeochemistry of those elements.  相似文献   

Reproductive variability in North Sea plaice, sole, and cod   总被引：4，自引：1，他引：4  

Rijnsdorp  A. D.; Daan  N.; van Beek  F. A.; Heessen  H. J. L. 《ICES Journal of Marine Science》1991,47(3):352-375

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“Coastal dynamics and human impact: south-eastern North Sea”, an overview     

Christian Winter  Alexander Bartholomä 《Geo-Marine Letters》2006,26(5):303-303

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Improving communication from managers to fishers in Europe and the US     

van Densen  Wim L. T.; McCay  Bonnie J. 《ICES Journal of Marine Science》2007,64(4):811-817

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Measurement of the signal to noise ratio in seismic profiling     

Kees Rutten  Mathée Valeton  Theo van Grunsven 《Marine Geophysical Researches》1972,1(4):445-450

The measurement of the signal to noise ratio in continuous seismic profiling systems is carried out by means of a small general purpose digital computer equipped with an analog to digital converter. The computer is programmed to compute and compare the power spectrum of a sample of noise to the power spectrum of a sample of noise plus an echo. Power spectra of some twenty to fifty shots are averaged to yield reliable estimates of the signal to noise ratio as a function of frequency. The observed spectra agree well with spectra calculated from signals measured near to an air-gun. This measurement of signal to noise ratio as a function of frequency provides unambiguous information for the adjustment of the necessary band-pass filter thus improving the operation of a continuous seismic profiler.  相似文献   

GPS signal acquisition using the repeatability of successive code phase measurements     

Zhen Zhu  Frank van Graas  Janusz Starzyk 《GPS Solutions》2008,12(1):43-53

This paper introduces a new method for GPS signal acquisition, which is based on the repeatability of successive code phase measurements and the M-of-N search algorithm. The performance of the proposed method in terms of probability of signal detection is similar to that of traditional methods, except that the calculation of the probability of detection does not rely on the noise distribution or the Carrier-to-Noise ratio (C/N₀). The code phase repeatability-based method is presented along with equations for probability of detection and probability of false detection. If the distribution of the noise is known, it also provides an estimate of the C/N₀. The proposed method is illustrated for coherent and non-coherent acquisition and C/N₀ estimation.  相似文献   

Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh     

Jerome Métral  Laurent Charlet  Sara Bureau  Sukumar Basu Mallik  Sudipta Chakraborty  Kazi M Ahmed  MW Rahman  Zhongqi Cheng  Alexander van Geen 《Geochemical transactions》2008,9(1):1

Background  

The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh.  相似文献   

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime     

Alexander V. Soloviev  Peter Schlüssel 《Boundary-Layer Meteorology》1996,77(1):45-68

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.  相似文献   

Particle acceleration and the decay of soft X-ray non-thermal line broadening in solar flares     

David Alexander  Sarah A. Matthews 《Solar physics》1994,154(1):157-175

The relationship between the production of -ray emitting particles and non-thermal soft X-ray line broadening is investigated. A model of particle acceleration via the stochastic interaction with MHD turbulence is assumed and the time development of the wave energy density derived under the condition of energy conservation between waves and particles. The inferred numbers and energy distribution of accelerated protons for four -ray flares are used to define the wave energy density and its temporal development. The presence of Alfvén wave turbulence is considered as the source of the non-thermal motions in the ambient plasma. These motions are observed as excess widths in the soft X-ray line emission from these events. The decay of the waves via the particle acceleration process is compared with the observed decays of this non-thermal line broadening. Our results show that both the -ray emission and excess soft X-ray line widths in these flares can be explained by the single physical phenomenon of Alfvén wave turbulence.  相似文献   

Cu 2p absorption spectroscopy as a probe for the site occupancy of (ZnxCu1−x)WO4 solid solution     

P. F. Schofield  C. M. B. Henderson  S. A. T. Redfern  G. van der Laan 《Physics and Chemistry of Minerals》1993,20(6):375-381

The solid solution sanmartinite (ZnWO₄)—cuproscheelite (CuWO₄) has been studied using Cu 2p X-ray absorption spectroscopy. While a single L₃ absorption peak is observed for CuWO₄, two distinct L₃ absorption peaks with a separation of ～0.8 eV are observed for the intermediate samples in the solid solution. The two peaks represent distinct Cu sites: one with all CuO₆ next nearest neighbours in the (Cu,Zn)O₆ chains, another having at least one ZnO₆ next nearest neighbour. Both sites show a linear increase in covalency as a function of increasing Cu-content. The relative intensities of the two absorption peaks is dependent upon the Cu-content and has been used to model the site occupancies. The results reveal that the local structural effects can be associated with a composition-dependent structural phase transition from P2/c (ZnWO₄) to P $\bar 1$ (CuWO₄). Deviations from a single-site model are explained in terms of the local environments, and evidence for site preferences and local clustering are explored.  相似文献