Mercury in itabirite-hosted soft hematite ore in the Quadrilátero Ferrífero of Minas Gerais     

Alexandre Raphael Cabral  Orlando Garcia Rocha Filho  Richard David Jones 《Journal of Geochemical Exploration》2008,96(1):69-76

Mercury contents in Precambrian banded iron formation-hosted hematite ores are virtually unknown. In an attempt to provide information on the abundance and distribution of Hg in Fe ore, we present analyses for Hg in samples of high-grade soft hematite ore from Gongo Soco, Minas Gerais, Brazil. Bulk samples contain from <  5 to 25  ppb Hg without obvious correlation with major elements. Granulometric fractions of follow-up samples have amounts of Hg from 6 to 48  ppb and display positive linear correlations with total Mn as MnO (r = 0.87), LOI (r = 0.87) and SiO₂ (r = 0.76), as well as a negative linear correlation with total Fe as Fe₂O₃ (r = −  0.87). The correlations suggest that Hg is associated with a hydrated ferruginous groundmass bearing residual Mn, Al and Si, which replaced gangue minerals in itabirite in the process of formation of the Gongo Soco soft hematite ore.  相似文献   

Metal-silicate partitioning and constraints on core composition and oxygen fugacity during Earth accretion     

Alexandre Corgne  Shantanu Keshav  Bernard J. Wood  Yingwei Fei 《Geochimica et cosmochimica acta》2008,72(2):574-589

We present the results of new partitioning experiments between metal and silicate melts for a series of elements normally regarded as refractory lithophile and moderately siderophile and volatile. These include Si, Ti, Ni, Cr, Mn, Ga, Nb, Ta, Cu and Zn. Our new data obtained at 3.6 and 7.7 GPa and between 2123 and 2473 K are combined with literature data to parameterize the individual effects of oxygen fugacity, temperature, pressure and composition on partitioning. We find that Ni, Cu and Zn become less siderophile with increasing temperature. In contrast, Mn, Cr, Si, Ta, Nb, Ga and Ti become more siderophile with increasing temperature, with the highly charged cations (Nb, Ta, Si and Ti) being the most sensitive to variations of temperature. We also find that Ni, Cr, Nb, Ta and Ga become less siderophile with increasing pressure, while Mn becomes more siderophile with increasing pressure. Pressure effects on the partitioning of Si, Ti, Cu and Zn appear to be negligible, as are the effects of silicate melt composition on the partitioning of divalent cations. From the derived parameterization, we predict that the silicate Earth abundances of the elements mentioned above are best explained if core formation in a magma ocean took place under increasing conditions of oxygen fugacity, starting from moderately reduced conditions and finishing at the current mantle-core equilibrium value.  相似文献   

Problems in the interpretation of Brazilian archaeofaunas: Different contexts and the important role of taphonomy     

Albrico Nogueira De Queiroz  Olivia Alexandre De Carvalho 《Quaternary International》2008,180(1):75

Studies on Brazilian archaeofauna from prehistoric and historic sites have attempted to explain human settlement and cultural trajectories in different geographical regions. However, only since 1999 have taphonomical criteria been developed during Brazilian zooarchaeological investigations. Wide ecosystem diversity results in the differential preservation of faunal remains. Until the end of the 20th century, many zooarchaeological studies presented insufficient information on complex predator–prey interaction systems in many regions, mostly from the Amazonian lowlands and the highlands of the Central Plateau. Animal remains might have been the result of natural predation, and they are often found mixed within anthropic material that could distort interpretation of deposits. Thus, there are major problems in defining diagnostic criteria to distinguish natural from cultural marks.Taphonomic analyses are needed to explain faunal remains in order to understand the particularities of human–animal relationships in Brazilian prehistory. Zooarchaeological and taphonomical data are presented from five human occupation sites dating from 9000 to 1000 BP to verify human–fauna relationships and natural deposits in three different regions of Brazil. These sites illustrate both natural and anthropic contexts.  相似文献   

Seasonal Variations in Drag Coefficient over a Sastrugi-Covered Snowfield in Coastal East Antarctica     

Charles Amory  Hubert Gallée  Florence Naaim-Bouvet  Vincent Favier  Etienne Vignon  Ghislain Picard  Alexandre Trouvilliez  Luc Piard  Christophe Genthon  Hervé Bellot 《Boundary-Layer Meteorology》2017,164(1):107-133

The surface of windy Antarctic snowfields is subject to drifting snow, which leads to the formation of sastrugi. In turn, sastrugi contribute to the drag exerted by the snow surface on the atmosphere and hence influence drifting snow. Although the surface drag over rough sastrugi fields has been estimated for individual locations in Antarctica, its variation over time and with respect to drifting snow has received little attention. Using year-round data from a meteorological mast, seasonal variations in the neutral drag coefficient at a height of 10 m \((C_{{ DN}10})\) in coastal Adelie Land are presented and discussed in light of the formation and behaviour of sastrugi based on observed aeolian erosion patterns. The measurements revealed high \(C_{{ DN}10} \) values \((\ge \) 2 \(\times \) 10\(^{-3})\) and limited drifting snow (35% of the time) in summer (December–February) versus lower \(C_{{ DN}10} \) values \((\approx \) 1.5 \(\times \) \(10^{-3})\) associated with more frequent drifting snow (70% of the time) in winter (March–November). Without the seasonal distinction, there was no clear dependence of \(C_{{ DN}10} \) on friction velocity or wind direction, but observations revealed a general increase in \(C_{{ DN}10} \) with rising air temperature. The main hypothesis defended here is that higher temperatures increase snow cohesion and the development of sastrugi just after snow deposition while inhibiting the sastrugi streamlining process by raising the erosion threshold. This increases the contribution of the sastrugi form drag to the total surface drag in summer when winds are lighter and more variable. The analysis also showed that, in the absence of erosion, single snowfall events can reduce \(C_{{ DN}10} \) to \(1\,\times \,10^{-3}\) due to the burying of pre-existing microrelief under newly deposited snow. The results suggest that polar atmospheric models should account for spatial and temporal variations in snow surface roughness through a dynamic representation of the sastrugi form drag.  相似文献   

Platinum-Group Elements and Gold Determination in NiS Fire Assay Buttons by UV Laser Ablation ICP-MS     

Alexandre P.de S. Jorge  Jacinta Enzweiler  Elisa K. Shibuya  Jorge E.S. Sarkis  Ana Maria G. Figueiredo 《Geostandards and Geoanalytical Research》1998,22(1):47-55

The direct analysis of nickel sulfide fire assay buttons by UV laser ablation ICP-MS was used to determine the platinum-group elements and gold in the following reference materials: UMT-1, WPR-1, WMG-1, GPt-4, GPt-6 and CHR-Bkg. The instrument was calibrated with buttons prepared using quartz doped with the appropriate standard solutions. Analytical precision (RSD) was generally better than 10%, although occasional higher RSDs may infer local heterogeneities within nickel sulfide buttons. Good or excellent agreement was observed between analysed and reference material values except Rh in UMT-1 and WMG-1, which suffered an interference from copper. Detection limits calculated as 10 s quantitation limits were Au (1.7 ng g⁻¹), Pd (3.3 ng g⁻¹), Pt (8.3 ng g⁻¹), Os (1.3 ng g⁻¹), Rh (1 ng g⁻¹), Ru (5 ng g⁻¹) and Ir (0.7 ng g⁻¹).  相似文献   

Simulation of SPOT Satellite Imagery for Charting Shallow-Water Benthic Communities in the Mediterranean     

Thomas  Belsher  Alexandre  Meinesz  Jean Robert  Lefevre Charles-François  Boudouresque 《Marine Ecology》1988,9(2):157-165

Abstract. In order to simulate SPOT-typc satellite imagery, remote sensing of the Bay of San Cyprianu (Corsica) was carried out using a radiation sensor mounted in an aircraft. The resulting simulated image was calibrated using a chart of the benthos produced by SCUBA diving. We show that remote sensing by satellite should be able to resolve certain bottom types and benthic communities in water down to a depth of 12 m.  相似文献   

Cyclic Changes along Posidonia oceanica Rhizomes (Lepidochronology): Present State and Perspectives     

Gérard Pergent  Charles-François Boudouresque  Alain Crouzet  Alexandre Meinesz 《Marine Ecology》1989,10(3):221-230

Abstract. Leaf sheaths in the seagrass Posidonia oceanica can persist for millcnia and they show, according to their insertion rank, cyclic variations in parameters such as thickness and tissue structure. The principal cycles are always annual, but pluriannual cycles can also be detected. Annual cycles may be changed by environmental parameters such as light, temperature, or water movement. In a fashion analogous to the study of annual tree rings (dendrochronology), the study of cyclic changes in Posidonia oceanica sheaths is thus a technique allowing the study of past yearly changes in the near-shore environment.  相似文献   

C- and S-rich molten alloy immiscibility and core formation of planetesimals     

Alexandre Corgne  Bernard J. Wood 《Geochimica et cosmochimica acta》2008,72(9):2409-2416

We present the results of melting experiments to 7.7 GPa and 2200 °C on a synthetic ‘chondrite-like’ composition suitable to model early planetesimal differentiation. Our principal observation is that two immiscible liquid alloys coexist to about 5.5 GPa in Fe-Ni-S-C-O compositional space, with one liquid alloy being enriched in S and the other enriched in C. The chemical distinctions between the two liquid alloys progressively weaken as pressure increases. This is related to the contraction of the miscibility gap with increasing pressure. With the moderately C- and S-depleted composition used in this study, we observed closure of the miscibility gap at about 5.5 GPa. Our results have implications for core formation on planetary bodies that have undergone extensive melting. Because of the characteristics of the immiscibility region, core formation and differentiation histories would have been largely dependent on the size of these bodies and their C and S contents. Our results indicate that relatively small bodies with elevated S and C contents would have likely experienced significant core stratification.  相似文献   

Assessing debris flow activity in a changing climate     

Thea Turkington  Alexandre Remaître  Janneke Ettema  Haydar Hussin  Cees van Westen 《Climatic change》2016,137(1-2):293-305

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Climate change in the Iberian Upwelling System: a numerical study using GCM downscaling     

Ana Cordeiro Pires  Rita Nolasco  Alfredo Rocha  Alexandre M. Ramos  Jesus Dubert 《Climate Dynamics》2016,47(1-2):451-464

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