MGS TES observations of the water vapor above the seasonal and perennial ice caps during northern spring and summer     

Alexey A. Pankine  Leslie K. Tamppari 《Icarus》2010,210(1):58-71

We report on new retrievals of water vapor column abundances from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data. The new retrievals are from the TES nadir data taken above the ‘cold’ surface areas in the North polar region (T_surf < 220 K, including seasonal frost and permanent ice cap) during spring and summer seasons, where retrievals were not performed initially. Retrievals are possible (with some modifications to the original algorithm) over cold surfaces overlaid by sufficiently warm atmosphere. The retrieved water vapor column abundances are compared to the column abundances observed by other spacecrafts in the Northern polar region during spring and summer and good agreement is found. We detect an annulus of water vapor growing above the edge of the retreating seasonal cap during spring. The formation of the vapor annulus is consistent with the previously proposed mechanism for water cycling in the polar region, according to which vapor released by frost sublimation during spring re-condenses on the retreating seasonal CO₂ cap. The source of the vapor in the vapor annulus, according to this model, is the water frost on the surface of the CO₂ at the retreating edge of the cap and the frost on the ground that is exposed by the retreating cap. Small contribution from regolith sources is possible too, but cannot be quantified based on the TES vapor data alone. Water vapor annulus exhibits interannual variability, which we attribute to variations in the atmospheric temperature. We propose that during spring and summer the water ice sublimation is retarded by high relative humidity of the local atmosphere, and that higher atmospheric temperatures lead to higher vapor column abundances by increasing the water holding capacity of the atmosphere. Since the atmospheric temperatures are strongly influenced by the atmospheric dust content, local dust storms may be controlling the release of vapor into the polar atmosphere. Water vapor abundances above the residual polar cap also exhibit noticeable interannual variability. In some years abundances above the cap are lower than the abundances outside of the cap, consistent with previous observations, while in the other years the abundances above the cap are higher or similar to abundances outside of the cap. We speculate that the differences may be due to weaker off-cap transport in the latter case, keeping more vapor closer to the source at the surface of the residual cap. Despite the large observed variability in water vapor column abundances in the Northern polar region during spring and summer, the latitudinal distribution of the vapor mass in the atmosphere is very similar during the summer season. If the variability in vapor abundances is caused by the variability of vapor sources across the residual cap then this would mean that they annually contribute relatively little vapor mass to significantly affect the vapor mass budget. Alternatively this may suggest that the vapor variability is caused by the variability of the polar atmospheric circulation. The new water vapor retrievals should be useful in tuning the Global Circulation Models of the martian water cycle.  相似文献   

Pressure solution creep under cyclic loading     

Vladimir Traskine  Zoya Skvortsova  Alexey Muralev  Dmitry Zubov 《Mineralogy and Petrology》2009,97(3-4):265-274

Pressure solution creep was studied on sodium chloride, calcium carbonate and ammonium nitrate in respective saturated aqueous solutions under static loading and cyclic unloading. Ball indentation and powder compaction curves show that each transition from static to cyclic regime produces an increase—sometimes manifold—in creep rate which lasts over the whole time of cyclic impact. After returning to static regime, the initial creep rate reappears. Over longer-term tests, both in static and cyclic regime, the creep gradually slows down. Increasing impact frequency enhances the effect. Any noticeable changes in strain rate are absent in a pure inert medium (paraffin oil). Possible mechanisms of the cyclic unloading effect are discussed.  相似文献   

Uranium Behavior in the Process of Primary Pitchblende Ores Alteration by the Post‐ore Hydrothermal Solutions: An Application to Assessment of Uranium Migration from Underground Spent Nuclear Fuel Repositories     

Nikolay P. Laverov  Vasily I. Velichkin  Ai Fujiwara  Naotatsu Shikazono  Alexey P. Aleshin  Enver E. Asadulin  Vyacheslav N. Golubev  Tatiana L. Krylova  Alexander A. Pek  Igor V. Chernyshev 《Resource Geology》2009,59(4):342-358

It has been shown that the main uranium ore mineral, pitchblende (uranium dioxide), is a natural analog of synthetic uraninite (also uranium dioxide), which constitutes 96% of spent nuclear fuel (SNF). Geochronological studies of the U‐Pb isotope systems in unaltered pitchblende from the orebodies reveal that these systems remained completely closed over the entire period (approximately 135 Ma) since the formation of the deposits. The bulk of the primary uranium ores within the Streltsovskoye ore field was influenced to various degrees by post‐ore hydrothermal solutions that led to pitchblende spherulites being replaced by pseudomorphs of an amorphous phase with a U‐Si composition; this phase also re‐precipitated in veinlets proximal to the pitchblende pseudomorphs. A technique specially developed by the authors was used to carry out quantitative counts of the abundance of uranium minerals by calculating the uranium mass balance in one of the orebodies subjected to hydrothermal alteration. The calculations reveal minimal uranium loss from the orebody. Uranium liberated in the process of the pseudomorphic replacement of pitchblende was immediately fixed, in situ, in the newly formed coffinite‐like amorphous U‐Si phase as a result of the development of an efficient geochemical barrier that prevented the long‐distance migration of uranium. In assessing the long‐term safety of underground SNF repositories, the results of the present study give us confidence that SNF uraninite, in terms of the preservation of its integrity as a mineral phase, provides for the reliable long‐term isolation of uranium, transuranium elements, and fission products that are “sealed” in the uraninite matrix. In the case of the mineral transformation of the uraninite matrix by hydrothermal solutions, the liberated uranium would be efficiently immobilized by the newly formed amorphous U‐Si phase.  相似文献   

Protocol for Quantitative Detection of Elemental Sulfur and Polysulfide Zero-Valent Sulfur Distribution in Natural Aquatic Samples     

Alexey Kamyshny Jr.    Clemens G. Borkenstein  Timothy G. Ferdelman 《Geostandards and Geoanalytical Research》2009,33(3):415-435

A HPLC-based protocol has been developed for the determination of zero-valent sulfur (ZVS) speciation, including solid, colloidal elemental sulfur and individual inorganic polysulfides in natural aquatic samples. The protocol includes four experimental procedures: (1) determination of polysulfide speciation by rapid single-phase derivatisation with methyl trifluoromethanesulfonate; (2) determination of the sum of polysulfide and colloidal sulfur by reaction with hydrogen cyanide (cyanolysis); (3) determination of total zero-valent sulfur by treatment with zinc chloride followed by extraction with chloroform; and (4) chromatographic determination of polythionates without sample pre-treatment. With proper sampling and preservation techniques in the field or on board ship, this combination of methods allowed the quantitative determination of: (a) individual polysulfide species; (b) dispersed colloidal sulfur; (c) dispersed solid elemental sulfur; and (d) tetra-, penta- and hexathionates. With minor modification, the method could be expanded to include other polythionates. Sixteen various wet chemical and liquid chromatographic methods were tested on nine synthetic reference samples (including solid elemental sulfur, colloidal elemental sulfur, inorganic polysulfides and polythionates) to establish the optimal protocol. The protocol was further evaluated by analysing the zero-valent sulfur content in microbially-produced sulfur and in sulfur from two natural samples of sulfide-rich seawater from tidal flats pools of the Wadden Sea (Germany).  相似文献   

Surface studies of water isotopes in Antarctica for quantitative interpretation of deep ice core data     

Amaelle Landais  Mathieu Casado  Frédéric Prié  Olivier Magand  Laurent Arnaud  Alexey Ekaykin  Jean-Robert Petit  Ghislain Picard  Michel Fily  Bénédicte Minster  Alexandra Touzeau  Sentia Goursaud  Valérie Masson-Delmotte  Jean Jouzel  Anaïs Orsi 《Comptes Rendus Geoscience》2017,349(4):139-150

Polar ice cores are unique climate archives. Indeed, most of them have a continuous stratigraphy and present high temporal resolution of many climate variables in a single archive. While water isotopic records (δD or δ¹⁸O) in ice cores are often taken as references for past atmospheric temperature variations, their relationship to temperature is associated with a large uncertainty. Several reasons are invoked to explain the limitation of such an approach; in particular, post-deposition effects are important in East Antarctica because of the low accumulation rates. The strong influence of post-deposition processes highlights the need for surface polar research programs in addition to deep drilling programs. We present here new results on water isotopes from several recent surface programs, mostly over East Antarctica. Together with previously published data, the new data presented in this study have several implications for the climatic reconstructions based on ice core isotopic data: (1) The spatial relationship between surface mean temperature and mean snow isotopic composition over the first meters in depth can be explained quite straightforwardly using simple isotopic models tuned to d-excess vs. δ¹⁸O evolution in transects on the East Antarctic sector. The observed spatial slopes are significantly higher (～ 0.7–0.8‰·°C^?1 for δ¹⁸O vs. temperature) than seasonal slopes inferred from precipitation data at Vostok and Dome C (0.35 to 0.46‰·°C^?1). We explain these differences by changes in condensation versus surface temperature between summer and winter in the central East Antarctic plateau, where the inversion layer vanishes in summer. (2) Post-deposition effects linked to exchanges between the snow surface and the atmospheric water vapor lead to an evolution of δ¹⁸O in the surface snow, even in the absence of any precipitation event. This evolution preserves the positive correlation between the δ¹⁸O of snow and surface temperature, but is associated with a much slower δ¹⁸O-vs-temperature slope than the slope observed in the seasonal precipitation. (3) Post-deposition effects clearly limit the archiving of high-resolution (seasonal) climatic variability in the polar snow, but we suggest that sites with an accumulation rate of the order of 40 kg.m^?2.yr^?1 may record a seasonal cycle at shallow depths.  相似文献   

Sheared peridotite xenolith from the V. Grib kimberlite pipe,Arkhangelsk Diamond Province,Russia: Texture,composition, and origin     

Alexey Vladimirovich Kargin  Lyudmila Vyacheslavovna Sazonova  Anna Andreevna Nosova  Vladimir Anatolievich Pervov  Elena Vladimirovna Minevrina  Vladimir Anatolievich Khvostikov  Zhanna Petrovna Burmii 《地学前缘(英文版)》2017,8(4):653-669

The petrography and mineral composition of a mantle-derived garnet peridotite xenolith from the V. Grib kimberlite pipe (Arkhangelsk Diamond Province, Russia) was studied. Based on petrographic characteristics, the peridotite xenolith reflects a sheared peridotite. The sheared peridotite experienced a complex evolution with formation of three main mineral assemblages: (1) a relict harzburgite assemblage consist of olivine and orthopyroxene porphyroclasts and cores of garnet grains (Gar1) with sinusoidal rare earth elements (REE) chondrite C1 normalized patterns; (2) a neoblastic olivine and orthopyroxene assemblage; (3) the last assemblage associated with the formation of clinopyroxene and garnet marginal zones (Gar2). Major and trace element compositions of olivine, orthopyroxene, clinopyroxene and garnet indicate that both the neoblast and clinopyroxene-Gar2 mineral assemblages were in equilibrium with a high Fe-Ti carbonate-silicate metasomatic agent. The nature of the metasomatic agent was estimated based on high field strength elements (HFSE) composition of olivine neoblasts, the garnet-clinopyroxene equilibrium condition and calculated by REE-composition of Gar2 and clinopyroxene. All these evidences indicate that the agent was a high temperature carbonate-silicate melt that is geochemically linked to the formation of the protokimberlite melt.  相似文献   

Reflection and transmission responses of layered transversely isotropic viscoelastic media     

Alexey Stovas  Bjorn Ursin 《Geophysical Prospecting》2003,51(5):447-477

We consider a layered heterogeneous viscoelastic transversely isotropic medium with a vertical symmetry axis (a viscoelastic TIV medium) and parameters that depend on depth only. This takes into account intrinsic attenuation, anisotropy and thin layering. The seismic wavefield is decomposed into up- and downgoing waves scaled by the vertical energy flux. This scaling gives important symmetry relationships for both reflection and transmission (R/T) responses. For a stack of homogeneous layers, the exact reflection response can be computed in a numerically stable way by a simple layer-recursive algorithm. We derive exact plane-wave R/T coefficients and several linear and quadratic approximations between two viscoelastic TIV media, as functions of the real-valued horizontal slowness. The approximations are valid for pre- and post-critical values of horizontal slowness provided that the proper complex square roots are used when computing the vertical slowness. Numerical examples demonstrate that the quadratic approximations can be used for large differences in medium parameters, while the linear approximations can be used for small differences. For weak anisotropy it is sufficient to use an isotropic background medium, while for strong anisotropy it is necessary to use a weak TIV or TIV background medium. We also extend the O'Doherty–Anstey formula to the P- and SV-wave transmission responses of a stack of viscoelastic TIV layers, taking into account intrinsic attenuation, anisotropy and thin layering.  相似文献   

Evolution of Multipath Error Reduction with Signal Processing   总被引：1，自引：0，他引：1  

Zhdanov  Alexey  Zhodzishsky  Mark  Veitsel  Victor  Ashjaee  Javad 《GPS Solutions》2002,5(3):19-28

GPS Solutions - The described method of code and carrier multipath error reduction is a refinement of the strobe method of pseudo random noise (PRN) signal processing. This method utilizes as a...  相似文献   

Ray theory of modulated body waves in inhomogeneous viscoelastic media     

Alexey P. Kiselev 《Pure and Applied Geophysics》1993,140(4):629-640

Ray theory based upon real rays is presented for high frequencyP andS waves in continuously inhomogeneous isotropic linear media. Simple explicit formulae for the polarization anomalies described by higher order terms of the ray asymptotic expansions are considered.  相似文献   

The protolith nature of diamondiferous metamorphic rocks of the Kokchetav Massif     

Vladislav Shatsky  Emil Jagoutz  Olga Kozmenko  Alexey Ragozin  Sergei Skuzovatov  Nikolai Sobolev 《《地质学报》英文版》2018,92(Z1):173-173

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