Leachability of trace elements from two stabilized low lime Indian fly ashes   总被引：1，自引：0，他引：1  

Puvvadi V. Sivapullaiah  M. Arif Ali Baig 《Environmental Earth Sciences》2010,61(8):1735-1744

Fly ash is a waste by-product obtained from the burning of coal by thermal power plants for generating electricity. When bulk quantities are involved, in order to arrest the fugitive dust, it is stored wet rather than dry. Fly ash contains trace concentrations of heavy metals and other substances in sufficient quantities to be able to leach out over a period of time. In this study an attempt was made to study the leachabilities of a few selected trace metals: Cd, Cu, Cr, Mn, Pb and Zn from two different types of class F fly ashes. Emphasis is also laid on developing an alternative in order to arrest the relative leachabilities of heavy metals after amending them with suitable additives. A standard laboratory leaching test for combustion residues has been employed to study the leachabilities of these trace elements as a function of liquid to solid ratio and pH. The leachability tests were conducted on powdered fly ash samples before and after amending them suitably with the matrices lime and gypsum; they were compacted to their respective proctor densities and cured for periods of 28 and 180 days. A marked reduction in the relative leachabilities of the trace elements was observed to be present at the end of 28 days. These relative leachability values further reduced marginally when tests were performed at the end of 180 days.  相似文献   

Geochemical constraints on the genesis of the volcanic rocks in the southeast of Isfahan area, Iran     

Mahnaz Khodami  Moussa Noghreyan  Ali Reza Davoudian 《Arabian Journal of Geosciences》2010,3(3):257-266

Late Miocene–Pliocene to Quaternary calc-alkaline lava flows and domes are exposed in southeast of Isfahan in the Urumieh Dokhtar magmatic belt in the Central Iran structural zone. These volcanic rocks have compositions ranging from basaltic andesites, andesites to dacites. Geochemical studies show these rocks are a medium to high K calc-alkaline suite and meta-aluminous. Major element variations are typical for calc-alkaline rocks. The volcanic rocks have SiO₂ contents ranging between 53.8% and 65.3%. Harker diagrams clearly show that the dacitic rocks did not form from the basaltic andesites by normal differentiation processes. They show large ion lithophile elements- and light rare earth elements (LREE)-enriched normalized multielement patterns and negative Nb, Ti, Ta, and P. Condrite-normalized REE patterns display a steep decrease from LREE to light rare earth elements without any Eu anomaly. These characteristics are consistent with ratios obtained from subduction-related volcanic rocks and in collision setting. The melting of a heterogeneous source is possible mechanism for their magma genesis, which was enriched in incompatible elements situated at the upper continental lithospheric mantle or lower crust. The geochemical characteristics of these volcanic rocks suggested that these volcanic rocks evolved by contamination of a parental magma derived from metasomatized upper lithospheric mantle and crustal melts.  相似文献   

Synsedimentary deformations in member 2 of the Mila Formation in the Central Alborz Mountains,Northern Iran     

Abas Kangi  Ali Asgar Aryaei  Abolghasem Maasoomi 《Arabian Journal of Geosciences》2010,3(1):33-39

In Alborz Mountains, the thickness of sediments in Member 2 of the Mila Formation (Middle Cambrian) underwent dramatic and abrupt deformations, which were accompanied by normal and reverse faults and asymmetrical folds. These deformed sediments are covered by parallel beds both in the upper and lower sides. The existence of such extension and compression structures adjacent to each other indicates the influence of non-tectonic factors in their evolution. These deformations induced by downslope gliding of sediment packages are fully compatible with the dislocation model of Farrell (J Struct Geol 6:727–736, 1984) and Farrell and Eaton (1987). Moreover, the occurrence of synsedimentary deformations in a vast area in Alborz Mountains reinforces the probability of the impact of seismic shocks in their formation. In fact, incessant seismic events in the Middle Cambrian led to numerous submarine slumpings in the sediments of Member 2 of the Mila Formation.  相似文献   

Valuation of socio-economic indicators for progressing urban sustainability under distinctive rubrics     

Ambreen Ghalib  Sahar Mirza  Danish Raza  Ainnee Rafi  Farhan Ali 《Transactions in GIS》2023,27(5):1318-1337

The key objective of the study is to collect the factors which play an important role in the city's sustainability and implementation advantages for the development of cities in future. This article develops an urban sustainability assessment framework by giving GIS-based decision support tools to guide cities toward sustainability. Multicriteria analysis was used as the decision support system and provides an analytical framework for assessing differences in the level of criteria and ranking decision options. It has the capability for assessment of urban sustainability because it brings sustainability criteria from three pillars of sustainability, environmental, social, and economic, which provide an integrated approach for assessment of urban sustainability. The GIS-based multicriteria analysis serves as a sustainability support system that maps urban sustainability and the underlying environmental, social, and economic conditions. The results from the study show that the four cities - Faisalabad, Lahore, Gujranwala, and Multan - have better economic conditions while only Lahore and Faisalabad showed social progress and the remaining cities showed less suitability. For the environmental index, none of the cities attained high suitability. Lahore, Faisalabad, and Rawalpindi showed better conditions than Gujranwala and Multan. It is demonstrated that Punjab cities have made progress in economic condition and improvement in social condition but have poor environmental condition. In the study, the environmental dimension has indicators which have more impact on the urban sustainability. Environmental degradation is observed in all selected regions and not a single region showed suitability toward its environmental condition and due to this none of the cities gained suitable scores for urban sustainability. Consequently, urban sustainability is a multidimensional and dynamic process that needs regular evaluation and monitoring. Thus, this article contends that the tools help to highlight and emphasize those areas that need guidance in achieving urban sustainability.  相似文献   

Estimation of the Land Surface Emissivity in the Hinterland of Taklimakan Desert   总被引：3，自引：2，他引：1  

LIU Yong-qiang  Ali MAMTIMIN  HUO Wen  YANG Xing-hua  LIU Xin-chun  MENG Xian-yong  HE Qing 《山地科学学报》2014,(6):1543-1551

An accurate accounting of land surface emissivity(ε) is important both for the retrieval of surface temperatures and the calculation of the longwave surface energy budgets.Since ε is one of the important parameterizations in land surface models(LSMs),accurate accounting also improves the accuracy of surface temperatures and sensible heat fluxes simulated by LSMs.In order to obtain an accurate emissivity,this paper focuses on estimating ε from data collected in the hinterland of Taklimakan Desert by two different methods.In the first method,ε was derived from the surface broadband emissivity in the 8–14 μm thermal infrared atmospheric window,which was determined from spectral radiances observed by field measurements using a portable Fourier transform infrared spectrometer,the mean ε being 0.9051.The second method compared the observed and calculated heat fluxes under nearneutral atmospheric stability and estimated ε indirectly by minimizing the root-mean-square difference between them.The result of the second method found a mean value of 0.9042,which is consistent with the result by the first method.Although the two methods recover ε from different field experiments and data,the difference of meanvalues is 0.0009.The first method is superior to the indirect method,and is also more convenient.  相似文献   

Geomorphological analysis of the morphometric characteristics that determine the volume of sediment yield of Wadi Al-Arja,South Jordan     

Ali Hamdi ABU SALIM 《地理学报》2014,24(3):457-474

This study addresses the morphometric variables that determine the sediment yield in Wadi Al-Arja through the analysis of the impact of different morphometric characteristics along the course of the valley on its sediment yield, as well as the analysis of spatial and formal dimensions and morphologies of the basin and its relationship to the sediment yield. The study also addresses the size of variation in the volume of sediment yield of the river tributaries that make up the water network of the valley under the differences of its morphometric and hydrological characteristics. The study found several results, most notably: The classification of Wadi Al-Arja basin according to the hypsometric integral value (72.1%) within an uneven topography, which increases the force of the erosive activity and the size of the sediment yield if the basin was exposed to moist climatic periods. The study also showed the presence of convergence in the intra-spaces between the river tributaries in the water network. This increases the volume of water flows when these tributaries meet with each other and thus increasing their erosive ability and sediment yield.The study also showed the presence of marked variation in the sediment yield of the river tributaries depending on the differences in its morphometric characteristics. The results of the step-wise regression analysis confirmed the importance of the morphometric and hydrological variables, and plant coverage in interpreting the variation in the size of the sediment yield of the river tributaries of different stream order in Wadi Al-Arja basin, where these variables interpreted 43% of the total variation, with statistical significance less than 0.05.  相似文献   

A study of aerosol properties over Lahore (Pakistan) by using AERONET data     

Muhammad Ali  Salman Tariq  Khalid Mahmood  Asim Daud  Adila Batool  Zia-ul-Haq 《Asia-Pacific Journal of Atmospheric Sciences》2014,50(2):153-162

It is well established that aerosols affect the climate in a variety of ways. In order to understand these effects, we require an insight into the properties of aerosols. In this paper we present a study of aerosol properties such as aerosol optical depth (AOD), single scattering albedo (SSA) and aerosol radiative forcing (ARF) over mega city of Lahore (Pakistan). The data from Aerosol Robotic Network (AERONET) have been used for the period December 2009 to October 2011. The seasonal average values of AOD, asymmetry parameter (ASY) and volume size distribution in coarse mode were observed to be highest in summer. On the other hand, the average values of Angstrom exponent (AE) and imaginary part of refractive index (RI) were found to be maximum in winter. The average value of real part of RI was found to be higher in spring than in all other seasons. The SSA exhibited an increasing trend with wavelength in the range 440 nm–1020 nm in spring, summer and fall indicating the dominance of coarse particles (usually dust). However, a decreasing trend was found in winter in the range 675 nm–1020 nm pointing towards the dominance of biomass and urban/industrial aerosols. As far as aerosol radiative forcing (ARF) is concerned, we have found that during the spring season ARF was lowest at the surface of Earth and highest at top of the atmosphere (TOA). This indicates that the atmosphere was warmer in spring than in all the remaining seasons.  相似文献   

Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran     

Azam Zahedi  Mohammad Boomeri  Kazuo Nakashima  Mohammad Ali Mackizadeh  Masao Ban  David R. Lentz 《Resource Geology》2014,64(3):209-232

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.  相似文献   

Mixed precision parallel preconditioner and linear solver for compositional reservoir simulation     

Ali Reza Khaz’ali  Mohammad Reza Rasaei  Jamshid Moghadasi 《Computational Geosciences》2014,18(5):729-746

Reservoir simulation role in value creation and strategic management decisions cannot be over emphasized. Simulation of complex challenging reservoirs with millions of grid blocks especially in compositional mode is very time-consuming even with fast modern computers. On the other hand, high price of cluster supercomputers prevents them for being commonly used for fast simulation of such reservoirs. In recent years, the development of many-core processors like cell processors, DSPs, and graphical processing units (GPUs) has provided a very cost-effective hardware platform for fast computational operations. However, programming for such processors is much more difficult than conventional CPUs, and new parallel algorithm design and special parallel implementation methods are needed. Using the computational power of CPUs, GPUs, and/or any other processing unit, Open Computing Language (OpenCL) provides a framework for programming for heterogeneous platforms. In this paper, OpenCL is used to employ the computational power of a GPU to build a preconditioner and solve the linear system arising from compositional formulation of multiphase flow in porous media. The proposed parallel preconditioner is proved to be quite effective, even in heterogeneous porous media. Using data-parallel modules on GPU, the preconditioner/solver runtime reduced at least 1 order of magnitude compared to their serial implementation on CPU.  相似文献   

Removal of lead (II) from synthetic and batteries wastewater using agricultural residues in batch/column mode     

J. Singh  A. Ali  V. Prakash 《International Journal of Environmental Science and Technology》2014,11(6):1759-1770

The present article explores the ability of five different combinations of two adsorbents (Arachis hypogea shell powder and Eucalyptus cameldulensis saw dust) to remove Pb(II) from synthetic and lead acid batteries wastewater through batch and column mode. The effects of solution pH, adsorbent dose, initial Pb(II) concentration and contact time were investigated with synthetic solutions in batch mode. The Fourier transform infrared spectroscopy study revealed that carboxyl and hydroxyl functional groups were mostly responsible for the removal of Pb(II) ions from test solutions. The kinetic data were found to follow pseudo-second-order model with correlation coefficient of 0.99. Among Freundlich and Langmuir adsorption models, the Langmuir model provided the best fit to the equilibrium data with maximum adsorption capacity of 270.2 mg g^?1. Column studies were carried out using lead battery wastewater at different flow rates and bed depths. Two kinetic models, viz. Thomas and Bed depth service time model, were applied to predict the breakthrough curves and breakthrough service time. The Pb(II) uptake capacity (q _e = 540.41 mg g^?1) was obtained using bed depth of 35 cm and a flow rate of 1.0 mL min^?1 at 6.0 pH. The results from this study showed that adsorption capacity of agricultural residues in different combinations is much better than reported by other authors, authenticating that the prepared biosorbents have potential in remediation of Pb-contaminated waters.  相似文献