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191.
We developed a new semi-analytical source zone depletion model (SZDM) for multicomponent light nonaqueous phase liquids (LNAPLs) and incorporated this into an existing screening model for estimating cleanup times for chemical spills from railroad tank cars that previously considered only single-component LNAPLs. Results from the SZDM compare favorably to those from a three-dimensional numerical model, and from another semi-analytical model that does not consider source zone depletion. The model was used to evaluate groundwater contamination and cleanup times for four complex mixtures of concern in the railroad industry. Among the petroleum hydrocarbon mixtures considered, the cleanup time of diesel fuel was much longer than E95, gasoline, and crude oil. This is mainly due to the high fraction of low solubility components in diesel fuel. The results demonstrate that the updated screening model with the newly developed SZDM is computationally efficient, and provides valuable comparisons of cleanup times that can be used in assessing the health and financial risk associated with chemical mixture spills from railroad-tank-car accidents.  相似文献   
192.
Predicting global climate change is a great challenge and must be based on a thorough understanding of how the climate system components behave. Precipitable water vapor (PWV) is one of the key components in determining and predicting the global climate system. It is well known that the local surface temperature and pressure have a direct influence on the production of PWV. However, the influence of solar activity on atmospheric dynamics and their physical mechanisms is still an open debate, where past studies are focused at mid-latitude regions. A new method of determining and quantifying the solar influence on PWV based on GPS observations to correlate the GPS PWV and total electron content (TEC) variations is proposed. Observed data from Scott Base (SBA) and McMurdo (MCM) stations from 2003 to 2005 have been used to study the response of PWV to solar activity. In the analysis, the effects of local conditions (wind speed and relative humidity) on the distribution of PWV are investigated. Results show significant correlation between PWV and solar activity for four geomagnetic storms, with correlation coefficients of 0.74, 0.77, 0.64 and 0.69, which are all significant at the 95% confidence level. There was no significant correlation between TEC and PWV changes during the absence of storms. On a monthly analysis, a strong relationship exists between PWV and TEC during storm-affected days, with correlation coefficients of 0.83 and 0.89 (99% confidence level) for SBA and MCM respectively. These indicate a statistically significant seasonal signal in the Antarctic region, which is very active (higher) during the summer and inactive (lower) for the winter periods.  相似文献   
193.
The conjugacy effects of the GPS scintillation activities during the geomagnetic storms of October 2003, November 2003 and July 2004 have been investigated at the approximately geomagnetically conjugate stations: Scott Base, Antarctica (SBA) and Resolute Cornwallis Island (RESO) in the high Arctic region. The measurements aim at investigation of the similarities and differences of the scintillation activities occurring at the conjugate points in the polar regions under storm conditions and examine the relationship between the Storm Enhanced Density (SED) and scintillation activity. The measurements of the scintillation activities obtained from total scintillation index during these storm periods at both hemispheres showed asymmetry in the ionospheric scintillation occurrence at the conjugate points. Pronounced scintillation activity was observed at the nightside hemisphere with the total scintillation index higher than at the dayside hemisphere. The results also show that the durations of severe scintillation activity were longer at the nightside hemisphere. The measurements showed that the intense scintillation periods were corresponding to the presence of the SED events where more pronounced SED events were observed over the nightside hemisphere.  相似文献   
194.
This paper attempts to establish a method for analysing the relationship between the polar and equatorial climate of the Northern Hemisphere. The Arctic Oscillation (AO) is known to have no direct relationship with the monsoon over the Maritime Continent (MC). Thus, an index called the Siberian High(SH~Maritime Continent(MC) Index (SHMCI) is developed to represent the mean sea level pressure difference between the SH and the warm pool over the MC. This index indicates a strong link with the monsoon circulation. A positive (strong) value of the SHMCI is associated with strong meridional winds and intense and frequent cold surge events over the South China Sea. The correlation between the AO index and the SHMCI is -0.39, which is medium but statistically significant; however, it is not sufficiently conclusive to infer direct correlation. Nevertheless, the SHMCI can be used as a tool to relate the AO with the monsoon over the MC because of the influence demonstrated by the AO towards the SH. Further analysis on the convergence and divergence anomalies over the MC reveals an impact discernible only from the SHMCI. This implies that the SHMCI manifests clearly the relationship between the Arctic and equatorial climate.  相似文献   
195.
Glyphosate is globally a widely used herbicide, yet there is little information on their toxicity to marine fishes. Java medaka, a small tropical fish native to coastal areas in several Southeast Asian countries, is viewed as a suitable candidate for toxicity test and thus was used for this study. Java medaka adults were cultured in the laboratory and the fertilized eggs of the F2 generation were exposed to different concentrations of glyphosate-based herbicide (100, 200, 300, 400 and 500 ppm) until they hatched. The survival and hatching rates of the embryos, changes in the heart rate and morphological impairments were recorded. Generally, survival and hatching percentage decreased as glyphosate concentration increased. Absence of pectoral fin(s) and cornea, permanently bent tail, irregular shaped abdomen, and cell disruption in the fin, head and abdomen are among the common teratogenic effects observed. Furthermore, risk factor also increased with the increased in glyphosate concentrations.  相似文献   
196.
The use of antifouling paints to the boats and ships is one among the threats facing coastal resources including coral reefs in recent decades. This study reports the current contamination status of diuron and its behaviour in the coastal waters of Malaysia. The maximum concentration of diuron was 285 ng/L detected at Johor port. All samples from Redang and Bidong coral reef islands were contaminated with diuron. Temporal variation showed relatively high concentrations but no significant difference (P > 0.05) during November and January (North-East monsoon) in Klang ports (North, South and West), while higher levels of diuron were detected during April, 2012 (Inter monsoon) in Kemaman, and Johor port. Although no site has shown concentration above maximum permissible concentration (430 ng/L) as restricted by the Dutch Authorities, however, long term exposure studies for environmental relevance levels of diuron around coastal areas should be given a priority in the future.  相似文献   
197.
198.
It is well-versed that transport occurrence is vital for in stream rehabilitation, river restoration and installment of sediment sampler on river beds. Current practice emulates the use of continuous pre-diction using reach-averaged approach. However, prediction of transport occurrence entails the use of binary model through the execution of logistic regression analysis. Bed load and turbulence data were physically measured at mountainous region with divergent surface bedform in its presence. The para-meterization and statistical approaches are treated in the similar fashion with multiple regression except for the test for model fit and model selection criterion. The parameters on near-bed turbulence char-acteristics at the entrainment threshold were assigned as independent variables containing 15 pre-dictors. Almost 80 models were generated by selecting the best possible combination in accordance with the statistical precaution of alleviating multicollinearity issue. It is postulated that the model containing shields stress in the form of turbulent kinetic energy (TKE) at vertical direction and fractional time for second quadrant provides better estimation of potential location for greatest sediment-entrainment;hence a high possibility for transport occurrence.  相似文献   
199.
Lead isotope data of sulfides and host volcanic rocks from the Bukit Botol and Bukit Ketaya deposits, the two representative deposits of the Tasik Chini volcanic‐hosted massive sulfide (VHMS) deposit, Central Belt of Peninsular Malaysia, are reported. Lead isotope compositions of the associated sulfide minerals and volcanic rocks from the Bukit Botol deposit exhibit homogeneous and less radiogenic values (206Pb/204Pb showing a range of composition from 18.14 to 18.20, 207Pb/204Pb between 15.52 and 15.59 and 208Pb/204Pb from 37.96 to 38.35). Similarly, the Pb isotopic compositions of the host volcanic rocks from the Bukit Ketaya deposit yielded a narrow range to those of the sulfide samples (206Pb/204Pb from 18.04 to 18.20, 207Pb/204Pb between 15.43 and 15.57 and 208Pb/204Pb of 37.96 to 38.30). The uniform Pb‐isotope compositions of the sulfides in the ore horizon and the host volcanic rocks from both deposits suggest a derivation from a similar source reservoir and mineralization processes. In the framework of the tectonic model for the Central Belt of Peninsular Malaysia, both deposits display a range of lead isotopic compositions originated from mixing of bulk crust/juvenile arc and minor mantle sources, which are typical for VHMS deposits in an island arc–back arc setting.  相似文献   
200.
Ocean Dynamics - The present work focuses on the measured wave spectrum in the South China Sea (scs) during storms. The measured spectra have been obtained from surface elevation measurements...  相似文献   
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