Colloidal Control on the Distribution of Rare Earth Elements in Shallow Groundwaters     

Olivier Pourret  Gérard Gruau  Aline Dia  Mélanie Davranche  Jérôme Molénat 《Aquatic Geochemistry》2010,16(1):31-59

A 7-year monitoring period of rare earth element (REE) concentrations and REE pattern shapes was carried out in well water samples from a 450 m long transect setup in the Kervidy/Coët-Dan experimental catchment, France. The new dataset confirms systematic, topography-related REE signatures and REE concentrations variability but challenges the validity of a groundwater mixing hypothesis. Most likely, this is due to REE preferential adsorption upon mixing. However, the coupled mixing–adsorption mechanism still fails to explain the strong spatial variation in negative Ce anomaly amplitude. A third mechanism—namely, the input into the aquifer of REE-rich, Ce anomaly free, organic colloids—is required to account for this variation. Ultrafiltration results and speciation calculations made using Model VI agree with this interpretation. Indeed, the data reveal that Ce anomaly amplitude downslope decrease corresponds to REE speciation change, downhill groundwaters REE being mainly bound to organic colloids. Water table depth monitoring shows that the colloid source is located in the uppermost, organic-rich soil horizons, and that the colloid input occurs mainly when water table rises in response to rainfall events. It appears that the colloids amount that reaches groundwater increases downhill as the distance between soil organic-rich horizons and water table decreases. Topography is, therefore, the ultimate key factor that controls Ce anomaly spatial variability in these shallow groundwaters. Finally, the <0.2 μm REE fraction ultimately comes from two solid sources in these groundwaters: one located in the deep basement schist; another located in the upper, organic-rich soil horizon.  相似文献   

Landslide influence on turbidity and total solids in Cubat?o do Norte River, Santa Catarina, Brazil     

Masato Kobiyama  Aline de Almeida Mota  Fernando Grison  Joana Nery Giglio 《Natural Hazards》2011,59(2):1077-1086

The rainfall events that occurred in the Cubat?o do Norte River watershed, Santa Catarina State, Brazil, in 2008, were characterized by both high intensities and amounts and triggered landslides in this watershed. The objective of the present study was to analyze the influence of landslides on the turbidity and the total solid concentration (TS) in this river using turbidity, TS, and river discharge data obtained from March 23, 2008, to June 11, 2010. The comparison between turbidity and discharge patterns implies that the landslide process was not continuous and increased the turbidity intermittently and irregularly. The sediment yield during the landslide occurrence was approximately five times higher than without the landslide, even though the discharges were similar. The turbidity/discharge relationship during the landslide occurrence was markedly different from that before and after the occurrence. The correlation coefficients between turbidity and TS showed that the landslide significantly changed the sediment yield in this watershed. The result indicates that sediment yield estimations at the watershed level should be treated more carefully when landslides occur.  相似文献   

Adaptation of the antioxidant defence system in hydrothermal-vent mussels (Bathymodiolus azoricus) transplanted between two Mid-Atlantic Ridge sites     

Rui Company  Angela Serafim  Richard Cosson  Aline Fiala-Médioni  David R. Dixon  & Maria João Bebianno 《Marine Ecology》2007,28(1):93-99

The vent mussel Bathymodiolus azoricus is the dominant member of the Northern Mid‐Atlantic Ridge (MAR) hydrothermal megafauna, and lives in an environment characterized by temporal and spatial variations in the levels of heavy metals, methane and hydrogen sulphide, substances which are known to increase reactive oxygen species levels in the tissues of exposed organisms. To evaluate the effects of two contrasting hydrothermal environments on the antioxidant defence system of this vent mussel species, a 2‐week transplant experiment was carried out involving mussels collected from the relatively deep (2300 m), and chemical rich, Rainbow vent field. These were transplanted to the shallower (1700 m), and relatively less toxic, Lucky Strike vent field. To achieve this objective, levels of superoxide dismutase, catalase (CAT), total glutathione peroxidase (GPx), selenium‐dependent glutathione peroxidase and lipid peroxidation (LPO) were measured in the gills and mantle tissues of resident and transplant mussels before and after the transplant experiment. With the exception of CAT, the gills of the transplanted mussels had significantly higher antioxidant enzyme activity compared with the basal levels in the donor (Rainbow) and recipient (Lucky Strike) populations; whereas the antioxidant enzyme levels in the mantle tissues of the transplants reflected the baseline levels of activity in the native Lucky Strike mussels after 2 weeks. In contrast, LPO levels were significantly higher in both tissue types in the transplants than in either the source or the recipient populations, which suggested a response to hydrostatic pressure change (note, the transplant animals were brought to the surface for transportation between the two vent fields). The fact that the Rainbow mussels survived the transplant experience indicates that B. azoricus has a very robust constitution, which enables it to cope behaviourally, physiologically and genetically with the extreme conditions found in its naturally contaminated deep‐sea environment.  相似文献   

An improved description of the interactions between rare earth elements and humic acids by modeling: PHREEQC-Model VI coupling     

Rémi Marsac  Mélanie Davranche  Gérard Gruau  Martine Bouhnik-Le Coz  Aline Dia 《Geochimica et cosmochimica acta》2011,75(19):5625-5637

The Humic Ion Binding Model VI (Model VI) - previously used to model the equilibrium binding of rare earth elements (REE) by humic acid (HA) - was modified to account for differences in the REE constant patterns of the HA carboxylic and phenolic groups, and introduced into PHREEQC to calculate the REE speciation on the HA binding sites. The modifications were shown to greatly improve the modeling. They allow for the first time to both satisfactorily and simultaneously model a large set of multi-REE experimental data with the same set of equations and parameters. The use of PHREEQC shows that the light rare earth elements (LREE) and heavy rare earth elements (HREE) do not bind to HA by the same functional groups. The LREE are preferentially bound to carboxylic groups, whereas the HREE are preferentially bound to carboxy-phenolic and phenolic groups. This binding differentiation might lead to a fractionation of REE-HA patterns when competition between REE and other metals occur during complexation. A survey of the available data shows that competition with Al³⁺ could lead to the development of HREE-depleted HA patterns. This new model should improve the hydrochemical modeling of the REE since PHREEQC takes into account chemical reactions such as mineral dissolution/precipitation equilibrium and redox reactions, but also models kinetically controlled reactions and one-dimensional transport.  相似文献   

Coupling the terrestrial hydrology model with biogeochemistry to the integrated LAND surface model: Amazon Basin applications     

Aline Anderson de Castro  Luz Adriana Cuartas  Michael T. Coe  Celso Von Randow  Andrea Castanho  Alex Ovando 《水文科学杂志》2013,58(13-14):1954-1966

ABSTRACT

We coupled the hydrologic routing and flood dynamics model Terrestrial Hydrology Model with Biogeochemistry (THMB) to the Integrated LAND Surface Model (INLAND) and compared simulations of the discharge and flood extent area against gauge station and satellite-based information in the Amazon Basin. The coupled model represents well the seasonality of the flooding and discharge, but underestimates both of them. This can be related to an already discussed underestimate of the precipitation in the east of the Andes Mountains. A photosynthesis limitation on the flooded area was also included, showing changes in plant productivity and reduction in vegetation carbon stocks. Despite its limitations, the model proves to be a valuable tool for studies of the hydrological cycle and flood dynamics response to climate change projections, allowing it to be used to represent the feedbacks between continental surface water cycle and vegetation.  相似文献   

How do management alternatives of fast-growing forests affect water quantity and quality in southeastern Brazil? Insights from a paired catchment experiment     

Silvio F. B. Ferraz  Carolina B. Rodrigues  Lara G. Garcia  Diana Peña-Sierra  Aline Fransozi  Matheus E. K. Ogasawara  Katherine Vasquez  Rildo M. Moreira  Carla C. Cassiano 《水文研究》2021,35(9):e14317

Fast-growing forest plantations have been expanding in Brazil in the last 50 years, which reach productivities by over 40 m³ ha⁻¹ year⁻¹ in reduced rotation between 5 and 15 years. In the 1990s, environmental warnings about these plantations guided research projects seeking to understand their effects on water and propose forest management actions to minimize them. The assessment of forest management effects on water resources is conducted by long-term experiments in paired catchments. In this paper we present results of some studies conducted at the hydrological monitoring centre of Itatinga Experimental Forest Station, of the University of São Paulo, where hydrological monitoring began in 1987, and currently include three catchments (83–98 ha) under different forest management regimes: short-rotation Eucalyptus plantation, long-term forest plantation mosaic and native forest restoration. Results show that at similar conditions observed at study area including deep soils and good natural water regulation, hydrological effects vary according to the forest management regime adopted, increasing water consumption and making the flow regime vulnerable to intra- and inter-annual seasonality. Regarding water quality, weekly sampling results showed suspended sediments and nitrate concentrations below water quality thresholds criteria by silvicultural operations, and the effects were transient but higher concentrations of nutrients were observed in intensive management regime. In the study area, reducing the management intensity of forest plantation by increasing the rotation time, adopting forest age mosaic and avoiding the coppice technique are alternative choices that reduced water use and increased flow regulation. Different adopted forest management schemes directly affected water use, showing that in water-deficit tropical regions, management regime of fast-growing forest plantations controls water availability.  相似文献   

Near‐bed shear stress,turbulence production and dissipation in a shallow and narrow tidal channel          下载免费PDF全文

Aline Pieterse  Jack A. Puleo  Thomas E. McKenna  Rebecca A. Aiken 《地球表面变化过程与地形》2015,40(15):2059-2070

Near‐bed, highly resolved velocity profiles were measured in the lower 0.03 m of the water column using acoustic Doppler profiling velocimeters in narrow tidal channels in a salt marsh. The bed shear stress was estimated from the velocity profiles using three methods: the log‐law, Reynolds stress, and shear stress derived from the turbulent kinetic energy (TKE). Bed shear stresses were largest during ebbing tide, while near‐bed velocities were larger during flooding tide. The Reynolds stress and TKE method gave similar results, while the log‐law method resulted in smaller bed shear stress values during ebbing tide. Shear stresses and turbulent kinetic energy followed a similar trend with the largest peaks during ebbing tide. The maximum turbulent kinetic energy was on the order of 1 × 10^{? 2} m²/s². The fluid shear stress during flooding tide was approximately 30% of the fluid shear stress during ebbing tide. The maximum TKE‐derived shear stress was 0.7 N/m² and 2.7 N/m² during flooding and ebbing tide, respectively, and occurred around 0.02 m above the bed. Turbulence dissipation was estimated using the frequency spectrum and structure function methods. Turbulence dissipation estimates from both methods were maximum near the bed (~0.01 m). Both the structure function and the frequency spectrum methods resulted in maximum dissipation estimates on the order of 4 × 10^{? 3} m²/s³. Turbulence production exceeded turbulence dissipation at every phase of the tide, suggesting that advection and vertical diffusion are not negligible. However, turbulence production and dissipation were within a factor of 2 for 77% of the estimates. The turbulence production and dissipation decreased quickly away from the bed, suggesting that measurements higher in the water column cannot be translated directly to turbulence production and dissipation estimates near the bed. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Improving the determination of reservoir capacities for drought control   总被引：2，自引：2，他引：0  

Aline de Araújo Nunes  Fernando Falco Pruski 《Stochastic Environmental Research and Risk Assessment (SERRA)》2015,29(1):183-191

Reliable methods of determining reservoir capacities are becoming more and more necessary to improve the planning and management of water resources. Due to its easy use and solid technical and scientific basis, the Reservoir Operation Study has been widely utilized by engineers. However, this method is limited by its strong dependence on the available database. This study was undertaken to propose potential modifications to the Reservoir Operation Study to overcome its problems, namely the strong dependence upon the first year of the time series and inability of associating the reservoir storage capacity with a frequency (return period). To make the reservoir capacity independent from the first year of the time series, we created (N ? 1) synthetic series of streamflows (N = the number of years in the time series) and applied the Reservoir Operation Study method to each one. To associate the reservoir capacity with a frequency factor (return period), we applied a Gumbel distribution to the reservoir capacity estimated from each one of the synthetic series. For β-values (proportion of the average streamflow to be regulated) greater than or equal to 0.75, the proposed method efficiently overcame the aforementioned limitation regarding the method’s dependence on the database. The association of storage capacities with return periods greater than the length of the time series, which is presented in this work, also considerably improves the Reservoir Operation Study method.  相似文献   

A new model for flow in shale-gas reservoirs including natural and hydraulic fractures   总被引：1，自引：0，他引：1  

Aline C. Rocha  Marcio A. Murad  Tien D. Le 《Computational Geosciences》2017,21(5-6):1095-1117

In this work, we construct a new coupled Multiscale/Discrete Fracture Model for compressible flow in a multiporosity shale gas reservoir containing networks of natural and hydraulic fractures. The geological formation is characterized by four distinct length scales and levels of porosity. The window of observation of the finest (nanoscale) portraits the nanopores within organic matter containing adsorbed gas. At the microscale, the medium is formed by two solid phases: organic, composed by kerogen aggregates, and inorganic (clay, quartz, calcite). Such phases are separated by the network of partially-saturated interparticle pores where microscopic free gas flow influenced by Knudsen effects along with gas diffusion in the immobile water phase occur simultaneously. The upscaling of the local flow to the mesoscale gives rise to a nonlinear homogenized pressure equation in the shale matrix which lies adjacent to the system of natural fractures. Homogenization of the coupled matrix/preexisting fractures to the macroscale leads to a microstructural model of dual porosity type. Such homogenized model is subsequently coupled with the hydrodynamics in the network of induced fractures which, in the context of the discrete fracture modeling, are treated as (n ? 1), (n = 2, 3) lower dimensional objects. In order to handle numerically the nonlinear interaction between the different flow equations, we adopt a superposition argument, firstly proposed by Arbogast (1996), in each iteration of a fixed-point algorithm. The resultant governing equations are discretized by the finite element method and numerical simulations of gas production in stratified arrangements of the fracture networks are presented to illustrate the potential of the multiscale approach.  相似文献   

Structures associated with inversion of the Donbas Foldbelt (Ukraine and Russia)     

Aline Saintot  Randell Stephenson  Sergiy Stovba  Yuriy Maystrenko   《Tectonophysics》2003,373(1-4):181

The Donbas Foldbelt is part of the Prypiat–Dnieper–Donets intracratonic rift basin (Belarus–Ukraine–southern Russia) that developed in Late Devonian times and was reactivated in Early Carboniferous. To the southeast, the Donbas Foldbelt joins the contiguous, deformed Karpinsky Swell. Basin “inversions” led first to the uplift of the Palaeozoic series (mainly Carboniferous but also syn-rift Devonian strata in the southwesternmost part of the Donbas Foldbelt, which are deeply buried in the other parts of the rift system), and later to the formation of the fold-and-thrust belt. The general structural trend of the Donbas Foldbelt, formed mainly during rifting, is WNW–ESE. This is the strike of the main rift-related fault zones and also of the close to tight “Main Anticline” of the Donbas Foldbelt that developed along the previous rift axis. The Main Anticline is structurally unique in the Donbas Foldbelt and its formation was initiated in Permian times, during a period of (trans) tensional reactivation, during which active salt movements occurred. A relief inversion of the basin also took place at this time with a pronounced uplift of the southern margin of the basin and the adjacent Ukrainian Shield. Subsequently, Cimmerian and Alpine phases of tectonic inversion of the Donbas Foldbelt led to the development of flat and shallow thrusts commonly associated with folds into the basin. A fan-shaped deformation pattern is recognised in the field, with south-to southeast-vergent compressive structures, south of the Main Anticline, and north- to northwest-vergent ones, north of it. These compressive structures are clearly superimposed onto the WNW–ESE structural grain of the initial rift basin. Shortening structures that characterise the tectonic inversion of the basin are (regionally) orientated NW–SE and N–S. Because of the obliquity of the compressive trends relative to the WNW–ESE strike of inherited structures (major preexisting normal faults and the Main Anticline), in addition to reverse displacements, right lateral movements occurred along the main boundary fault zones and along the faulted hinge of the Main Anticline. The existence of preexisting structures is also thought to be responsible for local deviations in contractional trends (that are E–W in the southwesternmost part of the basin).  相似文献